Rev Sci Instrum
March 2025
This paper introduces a novel high-performance millimeter-wave diplexer, engineered using a suspended microstrip line and rectangular waveguide, achieving operational bandwidths spanning DC to 40 and 70-110 GHz. The low-pass filter section features a tunable compact microstrip resonant cell based on elliptic filter technology, significantly enhancing transition band suppression. The ability to adjust transition bandwidth and suppression performance through modifications of open-circuit stubs exemplifies the filter's tunability.
View Article and Find Full Text PDFIntelligent polymer nanocomposites are multicomponent and multifunctional materials that show immense potential across diverse applications. However, to exhibit intelligent traits such as adaptability, reconfigurability and dynamic properties, these materials often require a solvent or heating environment to facilitate the mobility of polymer chains and nanoparticles, rendering their applications in everyday settings impractical. Here intelligent azopolymer nanocomposites that function effectively in a solvent-free, room-temperature environment based on photocontrolled reversible solid-fluid transitions via switching flow temperatures (Ts) are shown.
View Article and Find Full Text PDFACS Appl Mater Interfaces
October 2023
The performance of contact resistive pressure sensors heavily relies on the intrinsic characteristics of the active layers, including the mechanical surface structure, conductivity, and elastic properties. However, efficiently and simply regulating the conductivity, morphology, and modulus of the active layers has remained a challenge. In this study, we introduced electro-polymerized polypyrrole (ePPy) to design flexible contact piezoresistive sensors with tailored intrinsic properties.
View Article and Find Full Text PDFPhotoresponsive polymers can be conveniently used to fabricate anti-counterfeiting materials through photopatterning. However, an unsolved problem is that ambient light and heat can damage anti-counterfeiting patterns on photoresponsive polymers. Herein, photo- and thermostable anti-counterfeiting materials are developed by photopatterning and thermal annealing of a photoresponsive conjugated polymer (MC-Azo).
View Article and Find Full Text PDFWe investigate three azo-chromophore-containing photoswitches (1, 2 and 3) for molecular solar thermal storage (MOST) based on reversible - isomerization. 1, 2 and 3 are photoswitchable compounds that contain one, two and three azo chromophores, respectively. In solution, 1, 2 and 3 were charged UV-light-induced -to- isomerization.
View Article and Find Full Text PDFThe fabrication of dual-mode patterns in the same region of a material is a promising approach for high-density information storage, new anti-counterfeiting technologies, and highly secure encryption. However, dual-mode patterns are difficult to achieve because the two patterns in one material may interfere with each other during fabrication and usage. The development of noninterfering dual-mode patterns requires new materials and patterning techniques.
View Article and Find Full Text PDFPiebaldism is a rare, autosomal dominant and congenital pigmentary disorder characterized by stable depigmentation of the skin and white forelock. Mutations in KIT or SNAI2 genes result in piebaldism. Most individuals with piebaldism have a family history of the disorder.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
July 2019
Heating and cooling can induce reversible solid-to-liquid transitions of matter. In contrast, athermal photochemical processes can induce reversible solid-to-liquid transitions of some newly developed azobenzene compounds. Azobenzene is photoswitchable.
View Article and Find Full Text PDFAn unprecedented use of trifluoromethanesulfonyl hydrazides as effective SCF sources has been established in the sulfenylation of indoles. A range of substituted indoles participated in CuCl-catalyzed oxidative sulfenylation reaction with TfNHNHBoc in the presence of dimethyl sulfoxide to furnish structurally diverse 3-indolyl trifluoromethyl thioethers in moderate to good yields with very high regioselectivity.
View Article and Find Full Text PDFChem Commun (Camb)
February 2017