Effect of Processing Methods on Antinutritional Factors (Oxalate, Phytate, and Tannin) and Their Interaction with Minerals (Calcium, Iron, and Zinc) in Red, White, and Black Kidney Beans.

The purpose of this study was to assess how different processing techniques affected mineral compositions, antinutritional factors, and their interactions in red, white, and black kidney beans consumed in Ethiopia. Mineral contents were found to be 41-44, 58-78, and 112-126 mg Ca/100 g in the raw, soaked, and cooked samples, respectively. Iron content in the raw, soaked and cooked samples were found to be 2.

A Highly Selective Analytical Method Based on Salt-Assisted Liquid-Liquid Extraction for Trace-Level Enrichment of Multiclass Pesticide Residues in Cow Milk for Quantitative Liquid Chromatographic Analysis.

In this study, a simple, inexpensive, selective, and fast salting-out assisted liquid-liquid extraction (SALLE) technique coupled with high-pressure liquid chromatography-diode array detection (HPLC-DAD) was developed for the extraction, preconcentration, and analysis of trace level seven multiclass pesticide residues in pasteurized and raw cow milk samples. The significant factors that affect the extent to which the target analytes are extracted, such as the type of extraction solvent and its volume, the type and concentration of salting-out salts, the pH of the solution, and the extraction time, have been investigated. Under optimum conditions, the correlation coefficient () was obtained within a range of 0.

Pyridinic-Type N-Doped Graphene on Cobalt Substrate as Efficient Electrocatalyst for Oxygen Reduction Reaction in Acidic Solution in Fuel Cell.

In this study, we use density functional theory to investigate the catalytic activity of graphene (G), single vacancy defective graphene (G), quaternary N-doped graphene (NG), and pyridinic N-doped graphene (NG, 3NG, and 4NG) on Co(0001) substrate for an oxygen reduction reaction (ORR) in proton exchange membrane fuel cells (PEMFCs). The results show pyridinic N-doped graphene on a Co support exhibited better performance than the NG on a Co support and free-standing systems. According to the results, ORR intermediates (*OOH, *O, and *OH) become more stable due to the presence of a Co substrate.

Oxygen reduction reaction on Pt-skin PtV(111) fuel cell cathode: a density functional theory study.

Pt-non-precious transition metals (Pt-NPTMs) alloy electrocatalysts have gained considerable attention to develop cheaper and efficient electrocatalysts for oxygen reduction reaction (ORR) in proton exchange membrane fuel cells (PEMFCs). In this report, density functional theory (DFT) has been applied to study the catalytic activity of Pt-skin PtV(111) electrocatalyst for ORR in PEMFCs. The results revealed that the ORR intermediates (O, OH and OOH) have lower binding energies on Pt-skin PtV(111) compared to pure Pt(111) surface.

Iron-/Nitrogen-Doped Electrocatalytically Active Carbons for the Oxygen Reduction Reaction with Low Amounts of Cobalt.

Transition-metal-doped carbon catalysts are promising Pt-free alternatives for low-temperature fuel cells. They are frequently obtained from sacrificial N-rich zeolitic imidazolate frameworks (ZIFs) doped with Co and Fe. The optimal low loading of metals has to be achieved to guarantee the competitive efficiency and facilitate an inquiry into the mechanism of their catalytic activity.