A {Ru(CH)}-Containing Isopolymolybdate with Good Photocatalytic Activity for Oxidative Coupling of Amines, and Proton Conduction Properties.

We present a nonclassical {Ru(CH)}-containing isopolymolybdate CsKNaH{[(CH)Ru]MoO}·35HO () via one-pot reaction. The crystallographic characterization of compound revealed that it contains an unusual {MoO} cluster together with six {Ru(CH)} groups, having the largest number of {Ru(CH)} groups within the field of {Ru(CH)}-containing polyoxometalates. Results showed that compound displayed excellent proton conductivity (9.

Photocatalytic Reduction of Nitrobenzene to Aniline by an Intriguing {Ru(CH)}-Based Heteropolytungstate.

In this paper, we have successfully synthesized a structurally novel heteropolytungstate via coordination of four {Ru(CH)} and trivacant {TeWO} clusters, formulated as CsNaH[TeWO(HO){(CH)Ru}]·12HO (). Compound inherited the strong absorption of [Ru(CH)Cl] in the visible region and {TeWO} in the UV region, providing a good basis for photocatalysis. As expected, compound showed good photocatalytic activity in the visible-light-driven reduction of nitrobenzene using NH·HO as a reductant with a yield of 99.

{Ru(C H )}-Decorating Heteropolymolybdate for Highly Activity Photocatalytic Oxidation of Benzyl Alcohol to Benzaldehyde.

An unclassical structure of {Ru(C H )}-based polyoxometalate, Cs H [Te Mo O {Ru(C H )}] ⋅ 16.5H O (1), has been successfully constructed from {Te Mo O }-type heteropolymolybdate and {Ru(C H )} group, which structure type was discovered for the first time. Compound 1 not only possesses strong light-harvesting ability, but also exhibits high carrier separation efficiency and lower charge transfer resistance.