The development of an efficient noble-metal-free cocatalyst is the key to photocatalytic hydrogen production technology. In this study, hierarchical Co(OH) nanosheet array-graphene (GR) composite cocatalysts are developed. With Eosin Y (EY) as a photosensitizer, the optimal Co(OH)-10%GR hybrid cocatalyst presents excellent photocatalytic activity with an H production rate of 17 539 μmol g h, and the apparent quantum yield for hydrogen production can reach 12.
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