Designing hybrid transition metal phosphosulfide electrocatalysts is critical for the hydrogen evolution reaction (HER). We propose a novel approach by designing a hierarchical structure of cobalt phosphide (CoP) and nickel phosphide (NiP) nanoparticles topotactically developed on nickel sulfide (NiS) nanorods (CoNiP/NiS) a sulfuration-phosphorization strategy using conductive 3D nickel foam. Hierarchical heterostructured nanorods were achieved without the need for template removal steps or the assistance of surfactants.
View Article and Find Full Text PDFBackground: Entrustable Professional Activities (EPA)-based assessment is easily and intuitively used in evaluating the learning outcomes of competency-based medical education (CBME). This study aimed to develop an EPA for occupational therapy focused on providing health education and consultation (TP-EPA3) and examine its validity.
Methods: Nineteen occupational therapists who had completed online training on the EQual rubric evaluation participated in this study.
ACS Appl Mater Interfaces
February 2024
Due to its good mechanical properties and high ionic conductivity, the sulfide-type solid electrolyte (SE) can potentially realize all-solid-state batteries (ASSBs). Nevertheless, challenges, including limited electrochemical stability, insufficient solid-solid contact with the electrode, and reactivity with lithium, must be addressed. These challenges contribute to dendrite growth and electrolyte reduction.
View Article and Find Full Text PDFBackground: Acute coronary syndrome (ACS) is major cause of ventricular arrhythmias (VAs) and sudden death. neuECG is a noninvasive method to simultaneously record skin sympathetic nerve activity (SKNA) and electrocardiogram.
Objective: The purpose of this study was to test the hypotheses that (1) ACS increases average SKNA (aSKNA), (2) the magnitude of aSKNA elevation is associated with VAs during ACS, and (3) there is a gender difference in aSKNA between patients without and with ACS.
Pulmonary damage and function impairment were frequently noted in patients with diabetes mellitus (DM). However, the relationship between lung function and glycemic status in non-DM subjects was not well-known. Here, we evaluated the association of longitudinal changes of lung function parameters with longitudinal changes of glycated hemoglobin (HbA1c) in non-DM participants.
View Article and Find Full Text PDFDeveloping strategies for producing hydrogen economically and in greener ways is still an unaccomplished goal. Photoelectrochemical (PEC) water splitting using photoelectrodes under neutral electrolyte conditions provides possibly one of the greenest routes to produce hydrogen. Here, we demonstrate that chlorophyll extracts can be used as an efficient exfoliant to exfoliate bulk MoS and WS to form a thin layer of a MoS/WS heterostructure.
View Article and Find Full Text PDFSunlight energy is potentially excellent for small drones, which can often operate during daylight hours and fly high enough to avoid cloud blockade. However, the best solar cells provide limited power, compared to conventional power sources, making their use for aerial vehicles difficult to realize, especially in rotorcraft where significant lift ordinarily generated by a wing is already sacrificed for the ability to hover. In recent years, advances in materials (use of carbon-fiber components, improvement in specific solar cells and motors) have finally brought solar rotorcraft within reach.
View Article and Find Full Text PDFHighly hydroxylated barium titanate (BaTiO(3)) nanoparticles have been prepared via an easy and gentle approach which oxidizes BaTiO(3) nanoparticles using an aqueous solution of hydrogen peroxide (H(2)O(2)). The hydroxylated BaTiO(3) surface reacts with sodium oleate (SOA) to form oleophilic layers that greatly enhance the dispersion of BaTiO(3) nanoparticles in organic solvents such as tetrahydrofuran, toluene, and n-octane. The results of Fourier transform infrared spectroscopy confirmed that the major functional groups on the surface of H(2)O(2)-treated BaTiO(3) nanoparticles are hydroxyl groups which are chemically active, favoring chemical bonding with SOA.
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