Modeling nitrous oxide emission from full-scale hybrid membrane aerated biofilm reactors (MABR).

Current published models for nitrous oxide (NO) emission in membrane aerated biofilm reactors (MABR) have several simplifications that are not representative of full-scale systems. This study developed an improved MABR NO model that captured commonly overlooked phenomena such as back diffusion of generated NO into MABR lumen gas and the recirculation of the NO laden lumen gas for tank mixing and biofilm thickness control. The improved model was validated with measured NO concentrations in the lumen gas phase and bulk mixed liquor in a full-scale hybrid MABR facility.

Implementing differential recovery corrections enhances accuracy of mass balances on microplastics in wastewater treatment.

This study examined the impact of using different analytical recovery practices to correct MP concentrations on the performance of count and mass balances of primary wastewater settling. Spiking tests using standard MPs were conducted to evaluate the influence of MP size and sample type on recovery. The derived recovery values were then used to correct MP concentrations and loads in a full-scale primary treatment facility.

Impact of organic matter constituents on phosphorus recovery from CPR sludges.

This study evaluated the influence of organic matter (OM) constituents on the potential for recovery of P from wastewaters when FeCl treatment is employed for P removal. The presence of OM constituents did not influence P release from Fe-P sludges when alkaline and ascorbic acid treatments were employed. However, the overall recovery of P from wastewater was impacted by the presence of selected OM constituents through the reduction of P uptake during coagulation.

Pilot-scale evaluation of cascade anaerobic digestion of mixed municipal wastewater treatment sludges.

This work assessed the performance of a pilot-scale cascade anaerobic digestion (AD) system when treating mixed municipal wastewater treatment sludges. The cascade system was compared with a conventional continuous stirred tank reactor (CSTR) digester (control) in terms of process performance, stability, and digestate quality. The results showed that the cascade system achieved higher volatile solids removal (VSR) efficiencies (28-48%) than that of the reference (25-41%) when operated at the same solids residence time (SRT) in the range of 11-15 days.

Framework to Quantify Uncertainty in Microplastic Concentrations in Wastewaters and Sludges Incorporating Analytical Recovery Information into Data Analysis.

Wastewater treatment plants (WWTPs) serve a pivotal role in transferring microplastics (MPs) from wastewater to sludge streams, thereby exerting a significant influence on their release into the environment and establishing wastewater and biosolids as vectors for MP transport and delivery. Hence, an accurate understanding of the fate and transport of MPs in WWTPs is vital. Enumeration is commonly used to estimate concentrations of MPs in performance evaluations of treatment processes, and risk assessment also typically involves MP enumeration.

A comprehensive floc model for simulating simultaneous nitrification, denitrification, and phosphorus removal.

A comprehensive floc model for simultaneous nitrification, denitrification, and phosphorus removal (SNDPR) was designed, incorporating polyphosphate-accumulating organisms (PAOs), glycogen-accumulating organisms (GAOs), intrinsic half-saturation coefficients, and explicit external mass transfer terms. The calibrated model was able to effectively describe experimental data over a range of operating conditions. The estimated intrinsic half-saturation coefficients of oxygen values for ammonia-oxidizing bacteria, nitrite-oxidizing bacteria, ordinary heterotrophic organisms (OHOs), PAOs, and GAOs were set at 0.

Quantifying the removal of polybrominated diphenyl ethers (PBDEs) in physical, chemical, and biological sludge treatment systems.

Polybrominated diphenyl ethers (PBDE) are priority contaminants historically used as flame retardants. PBDEs are known to occur in wastewater biosolids posing potential concerns with the beneficial land application of the biosolids. This study evaluated the removal of 21 congeners in nine full-scale sludge treatment systems including pelletization (P), alkaline stabilization (AS), and aerobic (AE) and anaerobic (AN) digestion.

Implementing an adaptive, two-tiered SARS-CoV-2 wastewater surveillance program on a university campus using passive sampling.

Building-level wastewater-based surveillance (WBS) has been increasingly applied upstream from wastewater treatment plants to conduct targeted monitoring for SARS-CoV-2. In this study, a two-tiered, trigger-based wastewater surveillance program was developed on a university campus to monitor dormitory wastewater. The objective was to determine if passive sampling with cotton gauze as a sampling medium could be used to support institution-level public health action.

Molecular level investigation of interactions between pharmaceuticals and β-cyclodextrin (β-CD) functionalized adsorption sites for removal of pharmaceutical contaminants from water.

This study describes a novel application of the use of molecular modeling tools for investigating the adsorption of organic micropollutants (OMPs) from water by nanocomposites. The partitioning of pharmaceuticals onto β-Cyclodextrin (β-CD) functionalized adsorbents was investigated at the molecular level to explore the atomistic interactions of pharmaceutical contaminants in water systems with β-CD and to provide insight into possible approaches for removal of pharmaceuticals from water. Molecular electrostatic surface potential mapping of β-CD derivatives was employed to examine the impact of substitution degree of β-CD and type of grafting agent on host-guest complexation.

Phosphorus release and recovery by reductive dissolution of chemically precipitated phosphorus from simulated wastewater.

Chemically mediated recovery of phosphorous (P) as vivianite from the sludges generated by chemical phosphorus removal (CPR) is a potential means of enhancing sustainability of wastewater treatment. This study marks an initial attempt to explore direct P release and recovery from lab synthetic Fe-P sludge via reductive dissolution using ascorbic acid (AA) under acidic conditions. The effects of AA/Fe molar ratio, age of Fe-P sludge and pH were examined to find the optimum conditions for Fe-P reductive solubilization and vivianite precipitation.

Leveraging deep learning for automatic recognition of microplastics (MPs) via focal plane array (FPA) micro-FT-IR imaging.

The fast and accurate identification of MPs in environmental samples is essential for the understanding of the fate and transport of MPs in ecosystems. The recognition of MPs in environmental samples by spectral classification using conventional library search routines can be challenging due to the presence of additives, surface modification, and adsorbed contaminants. Further, the thickness of MPs also impacts the shape of spectra when FTIR spectra are collected in transmission mode.

β-Cyclodextrin functionalized adsorbents for removal of organic micropollutants from water.

The presence of organic micropollutants in water is an ongoing concern due to the potential risks to living organisms. β-Cyclodextrin-based adsorbents have been developed to remove organic micropollutants from water as they are deemed to be efficient, selective and reusable. This literature review establishes the current state of the knowledge on the application of β-Cyclodextrin adsorbents for the removal of organic micropollutants from water and determines knowledge gaps and recommendations for future studies.

Interaction of operating HRT and temperature on fouling of tertiary membranes treating municipal wastewater.

This paper presents the first study to quantify and demonstrate the interactions between SBR operating conditions (hydraulic retention time (HRT) and temperature) and soluble microbial product (SMP) generation, as well as the impact of SBR operating conditions and filtration temperature on fouling of membranes used in tertiary treatment. Reducing SBR operating HRT from 20 to 10 h resulted in an increase in SMP concentrations, however, the extent of the increase in high and low molecular weight (MW) organics was different for the effluents from SBRs operated at 8 and 20 °C. Results of SMP modelling demonstrated that a reduction in SBR operating HRT induced decreased utilization associated product (UAP) yields and the influence was greater at the SBR operating temperature of 8 °C.

A probabilistic approach to the quantification of methane generation in sewer networks.

Quantifying greenhouse gas (GHG) emissions from the conveyance of wastewater is an essential part of emissions reduction as it can identify areas of high emissions that can be targeted for mitigative action. In this study, a Monte Carlo algorithm that employs a reach-based methane generation sub-model was developed and applied to a full-scale municipal sewer system in Ontario, Canada. The algorithm employed eight categories of random variables including sewage temperature, slope, and coefficients described in the sewer reach model.

Nitrogen removal pathways during simultaneous nitrification, denitrification, and phosphorus removal under low temperature and dissolved oxygen conditions.

Nitrogen removal pathways of simultaneous nitrification, denitrification, and phosphorus removal (SNDPR) at low dissolved oxygen (0.3 mg/L) and temperature (10℃) were explored to understand nitrogen removal mechanisms. Biological nitrogen and phosphorus removal was sustained with total inorganic nitrogen removal, phosphorus removal, and simultaneous nitrification and denitrification (SND) efficiencies of 62.

Characterization and modelling of soluble microbial products in activated sludge systems treating municipal wastewater with special emphasis on temperature effect.

Soluble microbial products (SMP) classified as utilization-associated products (UAP) and biomass-associated products (BAP) are the predominant foulants determining fouling in tertiary filtration. However, the exact mechanisms of BAP and UAP generation when treating real wastewaters under cold temperatures remain unrevealed. This paper presents the first study linking biological processes and SMP formation when treating real wastewaters through a combination of bioprocess modelling and advanced SMP characterization.

Developing understanding of the fate and behaviour of silver in fresh waters and waste waters.

The Windermere Humic Aqueous Model (WHAM) is often used for risk assessment of metals; WHAM can be used to estimate the potential bioavailability of dissolved metals, where metals complexed to dissolved organic matter (DOM) are expected to be less toxic than ionic forms. Silver is a potential metal of concern but WHAM has not been rigorously tested against experimental measurements. This study compares WHAM predictions to measured ionic silver during fixed pH (4, 8 or 10) argentometric titrations of DOM from diverse origins.

Removal and formation of perfluoroalkyl substances in Canadian sludge treatment systems - A mass balance approach.

Poly- and per-fluoroalkyl substances (PFAS) are an emerging class of anthropogenic contaminants whose occurrence has raised concerns with the beneficial reuse of biosolids from wastewater treatment. This study evaluated the behavior of thirteen PFAS in nine Canadian sludge treatment systems including pelletization, alkaline stabilization, aerobic and anaerobic digestion processes. The composition of the overall PFAS-fluorine (ΣPFAS-F) loading in a system fed with only primary sludge was dominated by perfluorodecanoate (PFDA), whereas systems with blended primary and waste activated sludge feeds had a mix of short and long chain PFAS in raw sludges and treated biosolids.

Organic phosphorus removal using an integrated advanced oxidation-ultrafiltration process.

Non-reactive phosphorus (nRP) contains condensed phosphates and organic phosphorus (OP) species that are recalcitrant in secondary wastewater treatment and tend to remain in final effluents. To meet ultra-low effluent P discharge limits, persistent nRP must be removed. The objective of this study was to evaluate the use of an advanced oxidation process (AOP) which couples TiO/UV photolysis with ultrafiltration to oxidize and remove nRP species.

Impact of AnMBR operating conditions on anaerobic digestion of waste activated sludge.

The impact of solids retention time (SRT) and hydraulic retention time (HRT) on anaerobic digestion of thickened waste activated sludge (TWAS) in a pilot-scale anaerobic membrane bioreactor (AnMBR) was compared with that achieved in conventional anaerobic digestions (CD). The AnMBR was able to successfully digest municipal TWAS at HRTs ranging from 7 to 15 days and SRTs ranging from 15 to 30 days. Increasing SRT in the AnMBR resulted in a significant improvement in COD and VS removal efficiency when compared against CD operating at the same HRT.

Characterization of performance of full-scale tertiary membranes under stressed operating conditions.

This study sought to identify factors responsible for enhanced fouling of ultrafiltration membranes used in tertiary wastewater treatment under challenging conditions of high flow and low temperature. A detailed analysis of full-scale membrane operating data was conducted, and this was supported by data gathered through a field sampling campaign. Higher average fouling rates and average recoveries were observed during periods of highest flows and lowest temperatures.

High functional diversity among Nitrospira populations that dominate rotating biological contactor microbial communities in a municipal wastewater treatment plant.

Nitrification, the oxidation of ammonia to nitrate via nitrite, is an important process in municipal wastewater treatment plants (WWTPs). Members of the Nitrospira genus that contribute to complete ammonia oxidation (comammox) have only recently been discovered and their relevance to engineered water treatment systems is poorly understood. This study investigated distributions of Nitrospira, ammonia-oxidizing archaea (AOA), and ammonia-oxidizing bacteria (AOB) in biofilm samples collected from tertiary rotating biological contactors (RBCs) of a municipal WWTP in Guelph, Ontario, Canada.

Treatment of municipal wastewater in AnMBRs with powdered activated carbon addition under psychrophilic temperatures.

The performance of anaerobic membrane bioreactors (AnMBRs) at psychrophilic temperatures commonly observed in temperate climates (10-24°C) was assessed. A unique aspect of the research was operation at controlled SRT with regular membrane cleaning. COD removal and permeate VFA concentrations were similar at 15 and 24°C and deteriorated at 10°C.

Benchmarking the sustainability of sludge handling systems in small wastewater treatment plants.

A benchmarking strategy was developed to assess all aspects of sludge handling in small wastewater treatment plants and tested on a cross-section of Ontario facilities. Using operational data and on-site measurements, sustainability metrics that addressed energy consumption, chemical use, biosolids quality and disposition, and greenhouse gas (GHG) emissions were estimated. Electricity consumption for sludge handling ranged from 0.

Impact of anaerobically digested biosolids characteristics and handling conditions on dewatering performance at multiple facilities.

Anaerobically digested biosolids (ABD) characteristics that affect dewatering were assessed at three water resource recovery facilities (WRRF) with different handling practices. Dewatering performance at the three sites corresponded to different levels of soluble chemical oxygen demand (COD), ammonia (NH -N), and mono- and divalent cation concentrations in ADB. Capillary suction time (CST) and a modified centrifugal technique were used to determine optimum polymer doses and to assess the impact of handling conditions on dewatering performance.