The increasing concern over the negative impact of electromagnetic radiation and interference on humans has led to a growing interest in microwave-absorbing materials that are cost-effective, have a wide frequency range, and have high efficiency. In this paper, an FeO nanoparticle/carbonized hemp fiber composite was successfully prepared using hemp fibers as the primary material and template. By carefully regulating the concentration of the iron nitrate impregnation solution, accurate loading of FeO nanoparticles onto the carbonized hemp fiber was achieved.
View Article and Find Full Text PDFJ Colloid Interface Sci
July 2024
Zinc-iodine batteries (ZIBs) have been recognized as a promising energy storage device due to their high energy density, low cost and environmental friendliness. However, the development of ZIBs is hindered by the shuttle effect of polyiodides which results in capacity degradation and poor cycling performance. Inspired by the ability of starch to form inclusion compounds with iodine, we propose to use a starch gel on the cathode to suppress the shuttle of polyiodides.
View Article and Find Full Text PDFEthnopharmacological Relevance: Coronavirus Disease 2019 (COVID-19) is a grave and pervasive global infectious malady brought about by Severe Acute Respiratory Syndrome Coronavirus 2 (SARS-CoV-2), posing a significant menace to human well-being. Qingfei Paidu decoction (QFPD) represents a pioneering formulation derived from four classical Chinese medicine prescriptions. Substantiated evidence attests to its efficacy in alleviating clinical manifestations, mitigating the incidence of severe and critical conditions, and reducing mortality rates among COVID-19 patients.
View Article and Find Full Text PDFJ Colloid Interface Sci
September 2023
Component regulation and microstructure design are two effective strategies to adjust electromagnetic parameters and improve the microwave absorption performance of materials. In this study, a facile synthesis strategy consisting of ultrasonic dispersion, blast drying, and roasting is proposed to build a sandwich-like graphene-based absorbent, in which FeO nanoparticles with adjustable content are sandwiched uniformly between reduced graphene oxide nanosheets. The sandwich structure can form multiple interfaces, prevent the aggregation of nanoparticles, facilitate interface polarization, and endow the material with multiple electromagnetic loss mechanisms, which is very beneficial for impedance matching and microwave attenuation.
View Article and Find Full Text PDFBiomass-derived hard carbon materials are considered as the most promising anode materials for sodium-ion batteries (SIBs) due to their abundant sources, environmental friendliness, and excellent electrochemical performance. Although much research exists on the effect of pyrolysis temperature on the microstructure of hard carbon materials, there are few reports that focus on the development of pore structure during the pyrolysis process. In this study, corncob is used as the raw material to synthesize hard carbon at a pyrolysis temperature of 1000~1600 °C, and their interrelationationship between pyrolysis temperature, microstructure and sodium storage properties are systematically studied.
View Article and Find Full Text PDFCarbon-based microwave-absorbing materials with a low cost, simple preparation process, and excellent microwave absorption performance have important application value. In this paper, biomass-based carbon fibers were prepared using cotton fiber, hemp fiber, and bamboo fiber as carbon sources. Then, the precise loading of NiFeO nanoparticles on biomass-based carbon fibers with the loading amount in a wide range was successfully realized through a sustainable and low-cost route.
View Article and Find Full Text PDFAiming at the disadvantages of high cost, complex processes, low yield, and narrow bandwidth of carbon-based microwave absorbing materials, this paper provides a novel and efficient method for synthesizing metal oxide/carbonized bamboo fibers using renewable natural bamboo fibers as a carbon source. The results suggested that the metal oxides such as NiO and FeO were uniformly dispersed on the carbonized bamboo fibers and proved that the dielectric component NiO and magnetic component FeO can significantly improve the microwave absorption performance of the carbonized bamboo fibers. As expected, the NiO/carbonized bamboo fibers showed excellent microwave absorption performance due to the appropriate complex permittivity, high impedance matching, and attenuation coefficient.
View Article and Find Full Text PDFCOVID-19 pandemic poses a severe threat to public health. However, so far, there are no effective drugs for COVID-19. Transcriptomic changes and key genes related to Th2 cells in COVID-19 have not been reported.
View Article and Find Full Text PDFComposites obtained by incorporating magnetic nanoparticles into porous carbon materials are promising in serving as microwave absorbing materials. In this study, Ni/C porous fibers were successfully synthesized through a simple template method by using low-cost jute fibers as carbon source and template. The results showed that the Ni nanoparticles were uniformly loaded on the surface and hollow porous structure of the Ni/C porous fibers.
View Article and Find Full Text PDFIn this study, TiO/AgPO composites based on anatase TiO nanocrystals with co-exposed {101}, {010}/{100}, {001} and [111]-facets and AgPO microcrystals with irregular and cubic-like polyhedron morphologies were successfully synthesized by combining hydrothermal and ion-exchange methods. The anatase TiO nanocrystals with different high-energy facets were controllably prepared hydrothermal treatment of the exfoliated [TiO]/[TiO] nanosheet solutions at desired pH values. The AgPO microcrystal with different morphologies was prepared the ion-exchange method in the presence of AgNO and NHHPO at room temperature, which was used as a substrate to load the as-prepared anatase TiO nanocrystals on its surface and to form TiO/AgPO heterostructures.
View Article and Find Full Text PDFA facile one-pot microwave-assisted hydrothermal synthesis of rutile TiO quadrangular prisms with dominant {110} facets, anatase TiO nanorods and square nanoprisms with co-exposed {101}/[111] facets, anatase TiO nanorhombuses with co-exposed {101}/{010} facets, and anatase TiO nanospindles with dominant {010} facets were reported through the use of exfoliated porous metatitanic acid nanosheets as a precursor. The nanostructures and the formation reaction mechanism of the obtained rutile and anatase TiO nanocrystals from the delaminated nanosheets were investigated. The transformation from the exfoliated metatitanic nanosheets with distorted hexagonal cavities to TiO nanocrystals involved a dissolution reaction of the nanosheets, nucleation of the primary [TiO] monomers, and the growth of rutile-type and anatase-type TiO nuclei during the microwave-assisted hydrothermal reaction.
View Article and Find Full Text PDFIn this work, NiFeO nanoparticles were successfully supported on cotton-based carbon fibers through a flexible two-step approach consisting of calcination of cotton in a N atmosphere and subsequent hydrothermal reaction. The incorporation of the NiFeO nanoparticles into cotton-based carbon fibers resulted in better impedance matching, leading to better microwave absorption performance than cotton-based carbon fibers and NiFeO nanoparticles. For NiFeO/carbon fibers, reflection loss (RL) values less than -10 dB were obtained in the frequency range of 11.
View Article and Find Full Text PDFEcotoxicol Environ Saf
October 2019
To assess the human cancer risk exposed to soil contaminated by polycyclic aromatic hydrocarbons (PAHs) in Shanxi province, China, the total 33 samples in the surface soil were collected from 11 cities, and the priority 15 PAHs were analyzed using gas chromatography-mass spectrometry after the soxhlet extraction and silica-alumina column purification. As a result, the levels of ∑PAH in soil varied from 66.2 to 2633 ng/g dry weight (dw) with a mean of 732 ng/g dw, and seven carcinogenic PAHs made up 42-69% of the total priority PAHs and had an average value of 367 (in the range of 33.
View Article and Find Full Text PDFPorous activated carbon ball (PACB) composites impregnated with iron, cobalt, nickel and/or their oxides were synthesized through a wet chemistry method involving PACBs as the carrier to load Fe(3+), Co(2+), and Ni(2+) ions and a subsequent carbothermal reduction at different annealing temperatures. The results show that the pyrolysis products of nitrates and/or the products from the carbothermal reduction are embedded in the pores of the PACBs, with different distributions, resulting in different crystalline phases. The as-prepared PACB composites possessed high specific surface areas of 791.
View Article and Find Full Text PDFIn order to prepare a lightweight and efficient microwave absorbent, porous activated carbon balls (PACB) were used to load Fe(3+) and Co(2+) ions, because the PACB carrier has a high specific surface area of 800 m(2) g(-1) and abundant pores, including micropores and macropores. The loaded Fe(3+) and Co(2+) ions in the PACB composite were transformed into magnetic CoFe2O4 and/or Co3Fe7 particles during subsequent heat-treatment under an Ar atmosphere. According to the XRD and SEM results, the magnetic particles were embedded in the PACB macropores and showed different crystalline phases and morphologies after heat-treatment.
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