Enhanced phosphate recovery in R-MCDI systems: Synergistic effects of modified electrodes and membrane-electrode-current collector assembly.

Efficient phosphorus (P) recovery is critical for sustainable wastewater management and resource reuse. This study optimized a reservoir of membrane capacitive deionization (R-MCDI) system by integrating acid-modified activated carbon cloth (ACC) electrodes and a membrane-electrode-current collector assembly (MECA) configuration. Acid modification enhanced the electrode's specific surface area, microporosity, and carboxyl group content, while reducing charge transfer resistance, significantly improving P recovery and selectivity.