Study on the Structure and Properties of Silk Fibers Obtained from Factory All-Age Artificial Diets.

The traditional production mode of the sericulture industry is no longer suitable for the development requirements of modern agriculture; to facilitate the sustainable development of the sericulture industry, factory all-age artificial diet feeding came into being. Understanding the structural characteristics and properties of silk fibers obtained from factory all-age artificial diet feeding is an important prerequisite for application in the fields of textiles, clothing, biomedicine, and others. However, there have been no reports so far.

Interfacially Ordered NiCoMoS Nanosheets Arrays on Hierarchical TiCT MXene for High-Energy-Density Fiber-Shaped Supercapacitors with Accelerated Pseudocapacitive Kinetics.

Balancing electrochemical activity and structural reversibility of fibrous electrodes with accelerated Faradaic charge transfer kinetics and pseudocapacitive storage are highly crucial for fiber-shaped supercapacitors (FSCs). Herein, we report novel core-shell hierarchical fibers for high-performance FSCs, in which the ordered NiCoMoS nanosheets arrays are chemically anchored on TiCT fibers. Beneficial from architecting stable polymetallic sulfide arrays and conductive networks, the NiCoMoS-TiCT fiber maintains fast charge transfer, low diffusion and OH adsorption barrier, and stabilized multi-electronic reaction kinetics of polymetallic sulfide.

Enhanced ozonation of vanillin catalyzed by highly efficient magnetic MnFeO/ZIF-67 catalysts: Synergistic effects and mechanism insights.

In this study, we synthesized magnetic MnFeO/ZIF-67 composite catalysts using a straightforward method, yielding catalysts that exhibited outstanding performance in catalyzing the ozonation of vanillin. This exceptional catalytic efficiency arose from the synergistic interplay between MnFeO and ZIF-67. Comprehensive characterization via x-ray photoelectron spectroscopy (XPS), x-ray diffraction (XRD), Fourier transform infrared spectrometer (FT-IR), Brunauer-Emmett-Teller (BET), field emission scanning electron microscopy (FE-SEM), and energy dispersive spectroscopy (EDS) confirmed that the incorporation of MnFeO promoted the creation of oxygen vacancies, resulting in an increased presence of l adsorbed oxygen (O) and the generation of additional ·OH groups on the catalyst surface.

Electronic structure modulation of iron sites with fluorine coordination enables ultra-effective HO activation.

Electronic structure modulation of active sites is critical important in Fenton catalysis as it offers a promising strategy for boosting HO activation. However, efficient generation of hydroxyl radicals (•OH) is often limited to the unoptimized coordination environment of active sites. Herein, we report the rational design and synthesis of iron oxyfluoride (FeOF), whose iron sites strongly coordinate with the most electronegative fluorine atoms in a characteristic moiety of F-(Fe(III)O)-F, for effective HO activation with potent •OH generation.

Analysis of photocatalytic degradation of polyamide microplastics in metal salt solution by high resolution mass spectrometry.

Microplastic pollution has become one of the most concerned focuses in the world. Among many treatment methods, photocatalysis is considered to be one of the most environmentally friendly methods. In this work, the photodegradation behavior of polyamide microplastics is studied by using polyamide 6 PA6) as model microplastics and FeCl as catalyst.

Porous organic semiconductor/PET composite fibre for the synergistic removal of hexavalent chromium and organic pollutants under sunlight.

In this study, the porous graphite phase carbon nitride photocatalyst (P-g-CN) is prepared by the CaCO template method, and then P-g-CN/T-polyethylene terephthalate (T-PET) catalytic fibre is prepared by the padding method. P-g-CN can provide more active sites than g-CN as proved by the Brunauer-Emmett-Teller and the UV-Visible diffuse reflectance test. P-g-CN powder catalyst successfully supports PET fibre as proved by scanning electron microscope, Fourier infrared spectroscopy and X-ray diffraction spectroscopy.

Efficient elimination of carbamazepine using polyacrylonitrile-supported pyridine bridged iron phthalocyanine nanofibers by activating peroxymonosulfate in dark condition.

The monoaminotrinitro iron phthalocyanine (FeMATNPc) is used to connect with isonicotinic acid (INA) for amide bonding and axial coordination to synthetic a unique catalyst FeMATNPc-INA, which is loaded in polyacrylonitrile (PAN) nanofibers by electrospinning. The introduction of INA destroys the π-π conjugated stack structure in phthalocyanine molecules and exposes more active sites. The FeMATNPc-INA structure is characterized by X-ray photoelectron spectroscopy and UV-visible absorption spectrum, and the FeMATNPc-INA/PAN structure is characterized by Fourier transform infrared spectroscopy and X-ray diffraction.

Microfluidic-Assembled Covalent Organic Frameworks@Ti C T MXene Vertical Fibers for High-Performance Electrochemical Supercapacitors.

The delicate design of innovative and sophisticated fibers with vertical porous skeleton and eminent electrochemical activity to generate directional ionic pathways and good faradic charge accessibility is pivotal but challenging for realizing high-performance fiber-shaped supercapacitors (FSCs). Here, hierarchically ordered hybrid fiber combined vertical-aligned and conductive Ti C T MXene (VA-Ti C T ) with interstratified electroactive covalent organic frameworks LZU1 (COF-LZU1) by one-step microfluidic synthesis is developed. Due to the incorporation of vertical channels, abundant redox active sites and large accessible surface area throughout the electrode, the VA-Ti C T @COF-LZU1 fibers express exceptional gravimetric capacitance of 787 F g in a three-electrode system.

Pyridine-bridged cobalt tetra-aminophthalocyanine to active peroxymonosulphate for efficient degrading carbamazepine.

In this study, each cobalt tetra-aminophthalocyanine (CoTAPc) molecule was immobilised with four isonicotinic acid (INA) molecules by amide bonding, a novel and highly efficient catalyst pyridine-bridged cobalt tetra-aminophthalocyanine (CoTAPc-TINA) was synthesised. The introduction of INA molecules promoted CoTAPc to expose more active sites, and increased the electron cloud density of cobalt ions promoting O-O bond homolysis of PMS to generate more active species, which significantly enhanced catalytic activity. With the pharmaceutical of carbamazepine (CBZ) as model pollutant, 0.

Size Dispersion of the Filler Particles and Its Consequences on the Light-Extinction Properties of TiO/PET Nanocomposite Fibers.

Titanium dioxide (TiO) nanoparticles have been extensively used to modify the optical properties of various types of materials. In particular, they have been intensively loaded onto polymer fibers to quench the light reflection. In situ polymerization and online addition are two common strategies for fabricating TiO-loaded polymer nanocomposite fibers.

Interface-Anchored Covalent Organic Frameworks@Amino-Modified Ti C T MXene on Nylon 6 Film for High-Performance Deformable Supercapacitors.

Designing deformable supercapacitors (D-SCs) that have robust skeleton and smoothly active channels for charges kinetic migration and faradic storage are highly crucial for wearable systems. Here, we develop the high-performance D-SCs made of the covalent organic frameworks(COF)@amino-modified Ti C T deposited on decorated nylon 6 (DPA) film (COF@N-Ti C T /DPA) via layer-by-layer fabrication. The hierarchical COF@N-Ti C T /DPA exhibits admirable specific capacitance, rate performance and cycling stability in three-electrode system due to the superior H storage property and large interfacial charge transfer clarified by density functional theory calculations.

Hierarchical 3D Porous Hydrogen-Substituted Graphdiyne for High-Performance Electrochemical Lithium-Ion Storage.

Graphdiyne (GDY) has realized significant achievements in lithium-ion batteries (LIBs) because of its unique π-conjugated skeleton with sp- and sp-hybridized carbon atoms. Enriching the accessible surface areas and diffusion pathways of Li ions can realize more storage sites and rapid transport dynamics. Herein, three-dimensional porous hydrogen-substituted GDY (HsGDY) is developed for high-performance Li-ion storage.

Multiscale Dot-Wire-Sheet Heterostructured Nitrogen-Doped Carbon Dots-Ti C T /Silk Nanofibers for High-Performance Fiber-Shaped Supercapacitors.

Fiber-shaped supercapacitors (FSCs) have become one of the significantly strategical flexible energy-storage materials towards future wearable textile electronics and metaverse technologies. Here, we develop the high-performance FSCs based on multiscale dot-wire-sheet heterostructure microfiber of nitrogen-doped carbon dots-Ti C T /silk nanofibers (NCDs-Ti C T /SNFs) hybrids via microfluidic fabrication. Due to the enlarged interlayer spacing, plentiful porous channels, accelerated H ion transport dynamics, large electrical conductivity and excellent mechanical strength/flexibility, the NCDs-Ti C T /SNFs possesses high volumetric capacitance (2218.

In-situ-reduced synthesis of cyano group modified g-CN/CaCO composite with highly enhanced photocatalytic activity for nicotine elimination.

Graphite carbon nitride has many excellent properties as a two-dimensional semiconductor material so that it has a wide application prospect in the field of photocatalysis. However, the traditional problems such as high recombination rate of photogenerated carriers limit its application. In this work, we introduce nitrogen deficiency into g-CN to solve this problem a simple and safe in-situ reduction method.

Iron (II) phthalocyanine loaded tourmaline efficiently activates PMS to degrade pharmaceutical contaminants under solar light.

Iron (II) phthalocyanine (FePc) is loaded on the surface of the tourmaline (TM) by the reflow method to obtain FePc/TM. This research effectively prevents the π-π stacking of FePc, increased the effective utilization rate of PMS activation under solar light, and further improved the catalytic performance of the catalytic system. The catalytic oxidation efficiency of FePc/TM on carbamazepine (CBZ) and sulfadiazine (SD) can reach 99% under solar light for 15 and 5 min, the total organic carbon (TOC) removal rate can reach 58% and 69% under solar light for 120 min.

Interfacial Polymetallic Oxides and Hierarchical Porous Core-Shell Fibres for High Energy-Density Electrochemical Supercapacitors.

Realizing high energy-density and actual applications of fibre-based electrochemical supercapacitors (FESCs) are pivotal but challenging, as the ability to construct advanced fibres for accelerating charges kinetic diffusion and Faradaic storage remain key bottlenecks. Here, we demonstrate high-performance FESCs based on hetero-structured polymetallic oxides/porous graphene core-sheath fibres, where the large pseudo-active polymetallic oxide (PMO) sheath is uniformly loaded on a hierarchical porous graphene fibre (PGF) core. Due to the abundant micro-/mesoporous pathways, large accessible surface, excellent redox activity and good interface electron conduction, the PMO-PGF possesses high areal capacitance (2959.

Efficient peroxymonosulfate activation by N-rich pyridyl-iron phthalocyanine derivative for the elimination of pharmaceutical contaminants under solar irradiation.

It is of great significance for improving electron transmission performance by changing of the outer ring structure of iron phthalocyanine. Herein, 4 (pyridine-2, 3-yl) iron phthalocyanine (FepyPc), as N-rich pyridyl-iron phthalocyanine derivative, was introduced to degrade pharmaceutical contaminants. The catalytic degradation of organic pollutants with FepyPc was studied by activating peroxymonosulfate (PMS) at room temperature.

Abiotic degradation behavior of polyacrylonitrile-based material filled with a composite of TiO and g-CN under solar illumination.

As some of the most promising alternatives to traditional non-degradable materials, photodegradable materials have advantages of environmental benignity and rapid degradation under simple conditions. In this work, nontoxic TiO and cost-effective g-CN have been compounded in a weight of 9:1 to form a photocatalytic additive with high activity. A 25 wt% loading of this photocatalytic additive has been incorporated into the polyacrylonitrile (PAN) by centrifugal electrospinning to prepare an abiotic degradable PAN material.

Unraveling timescale-dependent Fe-MOFs crystal evolution for catalytic ozonation reactivity modulation.

Iron-based metal-organic frameworks (Fe-MOFs) have been considered competitive catalyst candidates for the effective degradation of organic pollutants via advanced oxidation processes (AOPs) due to their unique porous architecture and tunable active site structure. However, little is known about the role of synergetic relationship between porous architecture and active site exposure of Fe-MOFs on catalysis for AOPs yet. Here, we demonstrated an overlooked compromise over these two features on modulating the catalytic ozonation reactivity of MIL-53(Fe) through a timescale-dependent crystal evolution.

Atomic-Scale Tailoring and Molecular-Level Tracking of Oxygen-Containing Tungsten Single-Atom Catalysts with Enhanced Singlet Oxygen Generation.

The local coordination structure of metal atoms in single-atom catalysts (SACs) greatly influences their catalytic performance. And for most SACs, single metal atoms were anchored on carbon materials with N or C coordination. However, the rational design of oxygen-containing SACs and analyzing its structure-performance relationship remain challenging.

Supported Palladium-Catalyzed Carbonylative Synthesis of Diaryl Ketones from Aryl Bromides and Arylboronic Acids.

A palladium supported on graphitic carbon nitride (Pd/g-C N ) catalyzed carbonylative reaction of aryl bromides and arylboronic acids by has been developed for the construction of diaryl ketones. Using benzene-1,3,5-triyl triformate (TFBen) as the CO source, the reaction proceeded well to give various diaryl ketones in moderate to good yields.

Ligand-Controlled Regiodivergent Thiocarbonylation of Alkynes toward Linear and Branched α,β-Unsaturated Thioesters.

Thiocarbonylation of alkynes offers an ideal procedure for the synthesis of unsaturated thioesters. A robust ligand-controlled regioselective thiocarbonylation of alkynes is developed. Utilizing boronic acid and 5-chlorosalicylic acid as the acid additive to in situ form 5-chloroborosalicylic acid (5-Cl-BSA), and bis(2-diphenylphosphinophenyl)ether (DPEphos) as the ligand, linear α,β-unsaturated thioesters were produced in a straightforward manner.

Solar-driven zinc-doped graphitic carbon nitride photocatalytic fibre for simultaneous removal of hexavalent chromium and pharmaceuticals.

The current environmental problems urgently require researchers to seek an environmentally friendly, effective and easy to operate sewage treatment method. Graphite carbon nitride (g-CN), which has the advantages of simple preparation, safety, non-toxicity and chemical resistance, was expected to become a photocatalyst for solving environmental pollution. However, the performances of g-CN still have some limitations that the electron hole recombination is fast and the powder is not easy to recover.

High-valent iron-oxo species on pyridine-containing MWCNTs generated in a solar-induced HO activation system for the removal of antimicrobials.

The overuse of antimicrobials has resulted in serious damage to the ecosystem and human health. Therefore, the development of an efficient, stable, and reusable catalyst to eliminate antimicrobials under mild conditions is highly desired. Drawing inspiration from the metabolism of drugs by the enzymes in the human body, such as heme catalase, we developed a simulated enzyme catalyst, perchloride iron phthalocyanine (FePcCl), immobilized on pyridine-modified multiwalled carbon nanotubes (FePcCl-Py-MWCNTs).

Degradation of carbamazepine by MWCNTs-promoted generation of high-valent iron-oxo species in a mild system with O-bridged iron perfluorophthalocyanine dimers.

Metal phthalocyanine has been extensively studied as a catalyst for degradation of carbamazepine (CBZ). However, metal phthalocyanine tends to undergo their own dimerization or polymerization, thereby reducing their activity points and affecting their catalytic properties. In this study, a catalytic system consisting of O-bridged iron perfluorophthalocyanine dimers (FePcF-O-FePcF), multi-walled carbon nanotubes (MWCNTs) and HO was proposed.