Enhancing ionic conductivity and expanding the electrochemical window in polymer electrolytes via ferroelectric-metal-organic-frameworks to manipulate charge spatial distribution.

Poly (ethylene oxide) (PEO)-based polymer electrolytes have promising applications in all-solid-state lithium metal batteries. However, their wide range of practical applications is severely limited by their relatively low room temperature lithium ion conductivity and narrow electrochemical window. In this paper, based on the ability of spontaneous polarization of ferroelectric materials to generate polarization field under applied electric field and the characteristics of Metal-Organic-Frameworks (MOFs) materials with regular adjustable pore structure, a Nano material combining ferroelectric materials and MOF (NUS-6(Hf)-MOF) was first proposed to be added to PEO polymer electrolyte as a filler.

Dual functional coordination interactions enable fast polysulfide conversion and robust interphase for high-loading lithium-sulfur batteries.

The stable operation of high-capacity lithium-sulfur batteries (LSBs) has been hampered by slow conversion kinetics of lithium polysulfides (LiPSs) and instability of the lithium metal anodes. Herein, 6-(dibutylamino)-1,3,5-triazine-2,4-thiol (DTD) is introduced as a functional additive for accelerating the kinetics of cathodic conversion and modulating the anode interface. We proposed that a coordination interaction mechanism drives the polysulfide conversion and modulates the Li solvated structure during the binding of the N-active site of DTD to LiPSs and lithium salts.

Using High-Entropy Configuration Strategy to Design Spinel Lithium Manganate Cathodes with Remarkable Electrochemical Performance.

Owing to its abundant manganese source, high operating voltage, and good ionic diffusivity attributed to its 3D Li-ion diffusion channels. Spinel LiMnO is considered a promising low-cost positive electrode material in the context of reducing scarce elements such as cobalt and nickel from advanced lithium-ion batteries. However, the rapid capacity degradation and inadequate rate capabilities induced by the Jahn-Teller distortion and the manganese dissolution have limited the large-scale adoption of spinel LiMnO for decades.

Double catalysis of CoSe-NiSe heterogeneous dual-chamber core-shell Achieves high conversion of polysulfides.

Achieving efficient catalytic conversion of lithium polysulfides is a key way to improve kinetics in lithium-sulfur (Li-S) batteries. However, due to the limited nature of the catalyst interface, it is difficult to achieve a high conversion rate of LiPSs in one step. A novel heterogeneous dual-chamber core-shell nanocatalyst (CoSe-NiSe@PC) is described here, which efficiently accommodates sulfur and provides a heterogeneous dual catalytic interface like a two-stage "filter".

ZmCCD8 regulates sugar and amino acid accumulation in maize kernels via strigolactone signalling.

How carbon (sucrose) and nitrogen (amino acid) accumulation is coordinatively controlled in cereal grains remains largely enigmatic. We found that overexpression of the strigolactone (SL) biosynthesis gene CAROTENOID CLEAVAGE DIOXYGENASE 8 (CCD8) resulted in greater ear diameter and enhanced sucrose and amino acid accumulation in maize kernels. Loss of ZmCCD8 function reduced kernel growth with lower sugar and amino acid concentrations.

Direct Carbapenem Resistance and Carbapenemases Genotype Prediction by Al-MOF/TiO@Au Cubic Heterostructures-Assisted Intact Bacterial Cells Metabolic Analysis.

Carbapenem-resistant (CRKP) infections pose a significant threat to human health. Fast and accurate prediction of carbapenem resistance and carbapenemase genotype is critical for guiding antibiotic treatment and reducing mortality rates. In this study, we present a novel method using Al-MOF/TiO@Au cubic heterostructures for the metabolic analysis of intact bacterial cells, enabling rapid diagnosis of CRKP and its carbapenemases genotype.

Effect of clearance volume on the internal flow characteristics and output performance of oil-gas multiphase reciprocating pump.

In the production of oil and natural gas, excessive clearance volume is an important factor affecting the normal operation of oil-gas multiphase pump. Currently, little research has been conducted on the effect of clearance volume on the output characteristics of multiphase pump at home and abroad, leading to extremely low efficiency in the field application of multiphase pump. Therefore, this study conducted numerical calculations on the internal flow characteristics and output performance of multiphase pump under different clearance volumes using FLUENT software.

Study on an Interpenetrating Artificial SEI for Lithium Metal Anode Modification and Fast Charging Characterization.

Artificial SEI is one of the effective strategies to improve lithium dendrites and suppress side reactions. However, the role of SEI components and distribution on the modification of the lithium metal anode remains unclear. Therefore, in this study, the oxygen-sulfur (O-S) component and its distribution in SEI were modulated by designing experiments, and then the mechanism of its action was deeply investigated.

Light-driven biodegradation of chloramphenicol by photosensitized Shewanella oneidensis MR-1.

Efficient and sustainable degradation of chloramphenicol has piqued the interest of the scientific community. This study constructed a photosensitized biohybrid system using Shewanella oneidensis MR-1 and cadmium sulfide (CdS). This system could efficiently degrade chloramphenicol with robust stability.

The deubiquitinase USP15 drives malignant progression of gastric cancer through glucose metabolism remodeling.

Background: Ubiquitin-specific protease 15 (USP15) exhibits amplifications in various tumors, including gastric cancer (GC), yet its biological function and mechanisms in GC progression remain elusive.

Methods: Here, we established stable USP15 knockdown or overexpression GC cell lines and explored the potential mechanism of USP15 in GC. Besides, we also identified interacting targets of USP15.

Receptor-like cytoplasmic kinase 58 reduces tolerance of maize seedlings to low magnesium via promoting HO over-accumulation.

ZmRLCK58, a negative growth regulator, reduces tolerance of maize seedlings to low Mg via enhancing HO accumulation in the shoot. Magnesium (Mg) deficiency is one of critical limiting factors for crop production in widespread acidic soils worldwide. However, the molecular mechanism of crop response to Mg deficiency is still largely unclear.

NIN-LIKE PROTEIN3.2 inhibits repressor Aux/IAA14 expression and enhances root biomass in maize seedlings under low nitrogen.

Plants generally enhance their root growth in the form of greater biomass and/or root length to boost nutrient uptake in response to short-term low nitrogen (LN). However, the underlying mechanisms of short-term LN-mediated root growth remain largely elusive. Our genome-wide association study, haplotype analysis, and phenotyping of transgenic plants showed that the crucial nitrate signaling component NIN-LIKE PROTEIN3.

Adhesion and Transparency Enhancement between Flexible Polyimide-PDMS Copolymerized Film and Copper Foil for LED Transparent Screen.

With the increasing demand for innovative electronic products, LED transparent screens are gradually entering the public eye. Polyimide (PI) materials combine high temperature resistance and high transparency, which can be used to prepare flexible copper-clad laminate substrates. The physical and chemical properties of PI materials differ from copper, such as their thermal expansion coefficients (CTEs), surface energy, etc.

Crown Ether Copolymerized Polyimide Film: Enhanced Mechanical, Thermal Properties and Low Dielectric Constant under High Frequency.

Polymer materials with a low dielectric constant and low dielectric loss have the potential to be applied to high-frequency signal transmissions, such as mobile phone antennas and millimeter wave radars. Two types of diamines, 4,4'-diamino-p-tetraphenyl (DPT) and crown ether diamine (CED), were prepared for ternary copolymerization with BPDA in this study. Cross-links with molecular chains were formed, increasing molecular chain distance by utilizing rings of CED.

Association of residential greenness with obstructive sleep apnea among Chinese old adults and the mediation role of PM and leisure-time physical activity.

Few studies have investigated the association of residential greenness with obstructive sleep apnea (OSA). This study was to comprehensively examine the association of residential greenness exposure with OSA and explore the mediating effect of leisure-time physical activity (LTPA) and PM on the association among Chinese old adults. A prospective cohort study that enrolled 2027 adults aged ≥65 was conducted between 1st July 2015 and 30th September 2019 in Southern China.

Data-driven method for estimating emission factors of multiple pollutants from excavators based on portable emission measurement system and online driving characteristic identification.

This study aims to explore the factors that influence the emission characteristics of multiple pollutants from non-road mobile machinery (NRMM) under real-world conditions and to establish a data-driven method for calculating accurate emission factors. This research focused on NRMM excavators meeting the third-stage emission standards and identified the actual work characteristics of 108 excavators in different scenarios based on a self-developed testing system for 368,000 h. Additionally, a portable emission testing system (PEMS) was used to study the instantaneous emission characteristics under different driving styles and modes for 10 EC210 excavators with the largest engineering construction inventory.

Silicon-Cantilever-Enhanced Single-Fiber Photoacoustic Acetylene Gas Sensor.

A single-fiber photoacoustic (PA) sensor with a silicon cantilever beam for trace acetylene (CH) gas analysis was proposed. The miniature gas sensor mainly consisted of a microcantilever and a non-resonant PA cell for the real-time detection of acetylene gas. The gas diffused into the photoacoustic cell through the silicon cantilever beam gap.

Specific detection of fungicide thiophanate-methyl: A smartphone colorimetric sensor based on target-regulated oxidase-like activity of copper-doped carbon nanozyme.

Nanozyme-based colorimetric assays have shown great potential in the rapid and sensitive determination of pesticide residue in environment. However, the non-specific enzyme inhibition makes the assays generally lack of selectivity. In this study, we proposed a colorimetric sensing platform for the specific detection of the agricultural fungicide thiophanate-methyl (TM) based on its distinctive inhibitory effect on the nanozyme activity.

"Blue-free" orange ZnO-related light-emitting diode based on a natural interface layer of GaO and ZnGaO.

To fabricate a ZnO-related light-emitting diode (LED) with zero emission at blue wavelengths ("blue-free"), an ingenious strategy is employed. Specifically, for the first time to the best of our knowledge, a natural oxide interface layer, possessing remarkable visible emission potential, is introduced into the Au/i-ZnO/n-GaN metal-insulator-semiconductor (MIS) structure. The unique Au/i-ZnO/interface layer/n-GaN structure successfully eliminated the harmful blue emissions (400-500 nm) from the ZnO film, and the remarkable orange electroluminescence is mainly attributed to the impact ionization process of the natural interface layer at high electric field.

Visual evaluation of acetylcholinesterase inhibition by an easy-to-operate assay based on N-doped carbon nanozyme with high stability and oxidase-like activity.

Acetylcholinesterase (AChE) is the key enzyme associated with neurotransmission, and thus many drugs have been explored for their inhibitory effect on AChE, such as donepezil for Alzheimer's disease and organophosphorus pesticides (OPs). Compared with clinical trials, screening bioassays for AChE inhibitors are preferable in terms of operability and cost. Herein, we developed an easy-to-operate nanozyme-based colorimetric assay for the evaluation of AChE inhibitory strength with excellent anti-interference ability and low dependence on professional equipment.

Impact of Individual Cell Parameter Difference on the Performance of Series-Parallel Battery Packs.

Lithium-ion power batteries are used in groups of series-parallel configurations. There are Ohmic resistance discrepancies, capacity disparities, and polarization differences between individual cells during discharge, preventing a single cell from reaching the lower limit of the terminal voltage simultaneously, resulting in low capacity and energy utilization. The effect of the parameter difference (difference in parameters) of individual cells on the performance of the series-parallel battery pack is simulated and analyzed by grouping cells with different parameters.

A retrotransposon insertion in the promoter results in erect pubescence and higher yield in soybean.

Adaptive changes in crops contribute to the diversity of agronomic traits, which directly or indirectly affect yield. The change of pubescence form from appressed to erect is a notable feature during soybean domestication. However, the biological significance and regulatory mechanism underlying this transformation remain largely unknown.

Clinical observation on the safety and efficacy of umbilical cord mesenchymal stem cells in the treatment of bronchiolitis obliterans after allogeneic haematopoietic stem cell transplantation.

Graft-versus-host disease (GVHD) is caused by a pathologic and destructive response of the organism as a result of the interaction between donor immunocompetent T lymphocytes and the recipient tisular antigens1. Graft-versus-host disease is considered a serious complication of hematopoietic stem cell transplantation. The skin, oral cavity and lungs are commonly affected organs.

Bad apples spoiling the metaphor? How and why self-serving leaders stir up counterproductive behaviors at work.

Self-serving leaders satisfy their self-interests at the cost of both employees and organizations, leading to declining organizational competitive advantage and performance. Drawing upon the affective events theory (AET), we constructed and examined a theoretical model of self-serving leadership influencing counterproductive work behavior (CWB), where traditionality plays a significant moderating role through the lens of anger as a mediator. Data were collected in three waves using a survey questionnaire distributed in three industries located in the Southwest district of China.