Triboelectric Bending Sensors for AI-Enabled Sign Language Recognition.

Human-machine interfaces and wearable electronics, as fundamentals to achieve human-machine interactions, are becoming increasingly essential in the era of the Internet of Things. However, contemporary wearable sensors based on resistive and capacitive mechanisms demand an external power, impeding them from extensive and diverse deployment. Herein, a smart wearable system is developed encompassing five arch-structured self-powered triboelectric sensors, a five-channel data acquisition unit to collect finger bending signals, and an artificial intelligence (AI) methodology, specifically a long short-term memory (LSTM) network, to recognize signal patterns.

Biometric-Tuned E-Skin Sensor with Real Fingerprints Provides Insights on Tactile Perception: Rosa Parks Had Better Surface Vibrational Sensation than Richard Nixon.

The dense mechanoreceptors in human fingertips enable texture discrimination. Recent advances in flexible electronics have created tactile sensors that effectively replicate slowly adapting (SA) and rapidly adapting (RA) mechanoreceptors. However, the influence of dermatoglyphic structures on tactile signal transmission, such as the effect of fingerprint ridge filtering on friction-induced vibration frequencies, remains unexplored.

Natural Antioxidant Vitamin C Improves Photovoltaic Performance of Tin-Lead Mixed Perovskite Solar Cells.

The oxidation of Sn can occur even after the completion of the perovskite crystallization in a low oxygen environment. Concerning this, the natural antioxidant vitamin C (VC) is introduced to the surface of Sn-Pb mixed perovskite using a postprocessing method to achieve the purpose of inhibiting Sn oxidation and enhancing perovskite solar cells performance. The results indicate that the VC could effectively inhibit Sn oxidation and heal the vacancy defects of the annealed perovskite film.

N-P covalent bond regulation of mesoporous carbon-based catalyst for lowered oxygen reduction overpotential and enhanced zinc-air battery performance.

Developing sustainable metal-free carbon-based electrocatalysts is essential for the deployment of metal-air batteries such as zinc-air batteries (ZABs), among which doping of heteroatoms has attracted tremendous interest over the past decade. However, the effect of the heteroatom covalent bonds in carbon matrix on catalysis was neglected in most studies. Here, an efficient metal-free oxygen reduction reaction (ORR) catalyst is demonstrated by the N-P bonds anchored carbon (termed N,P-C-1000).

Surfactant Self-Assembly Enhances Tribopositivity of Stretchable Ionic Conductors for Wearable Energy Harvesting and Motion Sensing.

Boosting stretchability and electric output is critical for high-performance wearable triboelectric nanogenerators (TENG). Herein, for the first time, a new approach for tuning the composition of surface functional groups through surfactant self-assembly to improve the tribopositivity, where the assembly increases the transferred charge density and the relative permittivity of water polyurethane (WPU). Incorporating bis(trifluoromethanesulfonyl)imide (TFSI) and alkali metal ions into a mixture of WPU and the surfactant forms a stretchable film that simultaneously functions as positive tribolayer and electrode, preventing the conventional detachment of tribolayer and electrode in long term usage.

Effect of the Photoreduction Process on the Self-Cleaning and Antibacterial Activity of Au-Doped TiO Colloids on Cotton Fabric.

This study aims at understanding the effect of the photoreduction process during the synthesis of gold (Au)-doped TiO colloids on the conferred functionalities on cotton fabrics. TiO/Au and TiO/Au/SiO colloids were synthesized through the sol-gel method with and without undergoing the photoreduction step based on different molar ratios of Au:Ti (0.001 and 0.

AI-Enabled Soft Sensing Array for Simultaneous Detection of Muscle Deformation and Mechanomyography for Metaverse Somatosensory Interaction.

Motion recognition (MR)-based somatosensory interaction technology, which interprets user movements as input instructions, presents a natural approach for promoting human-computer interaction, a critical element for advancing metaverse applications. Herein, this work introduces a non-intrusive muscle-sensing wearable device, that in conjunction with machine learning, enables motion-control-based somatosensory interaction with metaverse avatars. To facilitate MR, the proposed device simultaneously detects muscle mechanical activities, including dynamic muscle shape changes and vibrational mechanomyogram signals, utilizing a flexible 16-channel pressure sensor array (weighing ≈0.

Asymmetric Chemical Potential Activated Nanointerfacial Electric Field for Efficient Vanadium Redox Flow Batteries.

Constructing active sites with enhanced intrinsic activity and accessibility in a confined microenvironment is critical for simultaneously upgrading the round-trip efficiency and lifespan of all-vanadium redox flow battery (VRFB) yet remains under-explored. Here, we present nanointerfacial electric fields (-fields) featuring outstanding intrinsic activity embodied by binary MoC-MoN sublattice. The asymmetric chemical potential on both sides of the reconstructed heterogeneous interface imposes the charge movement and accumulation near the atomic-scale N-Mo-C binding region, eliciting the configuration of an accelerator-like -field from MoN to MoC sublattice.

Decoupling Activation and Transport by Electron-Regulated Atomic-Bi Harnessed Surface-to-Pore Interface for Vanadium Redox Flow Battery.

Vanadium redox flow battery (VRFB) promises a route to low-cost and grid-scale electricity storage using renewable energy resources. However, the interplay of mass transport and activation processes of high-loading catalysts makes it challenging to drive high-performance density VRFB. Herein, a surface-to-pore interface design that unlocks the potential of atomic-Bi-exposed catalytic surface via decoupling activation and transport is reported.

A Stretchable Solid Ionic Electrode-Based Triboelectric Nanogenerator for Biomechanical Energy Harvesting and Self-Powered Sensors.

Stretchable power devices and self-powered sensors have become increasingly desired for wearable electronics and artificial intelligence. In this study, an all-solid-state triboelectric nanogenerator (TENG) is reported, whose one solid-state structure prevents delamination during stretch and release cycles and increasing the patch adhesive force (3.5 N) and strain (586% elongation at break).

Nano-sphere RuO embedded in MOF-derived carbon arrays as a dual-matrix anode for cost-effective electrochemical wastewater treatment.

The electrodes' activity, surface area and cost hinder the deployment of electrochemical wastewater treatment. Using an economical microfiber-based carbon felt (CF) substrate, we design RuO nanospheres confined by CoO cooperated carbon nanoarrays (RuO-CoO@TCF) to augment noble metal utilization and thus reduce the catalyst cost. RuO-CoO@TCF anode with vertical diffusion channels exhibits rapid generation ability of oxidizing species particularity in the presence of Cl ions, which play a crucial role in azo bond cleavage and benzene ring chlorination of methyl orange.

Wide-Bandwidth Nanocomposite-Sensor Integrated Smart Mask for Tracking Multiphase Respiratory Activities.

Wearing masks has been a recommended protective measure due to the risks of coronavirus disease 2019 (COVID-19) even in its coming endemic phase. Therefore, deploying a "smart mask" to monitor human physiological signals is highly beneficial for personal and public health. This work presents a smart mask integrating an ultrathin nanocomposite sponge structure-based soundwave sensor (≈400 µm), which allows the high sensitivity in a wide-bandwidth dynamic pressure range, i.

Biotechnology of Plastic Waste Degradation, Recycling, and Valorization: Current Advances and Future Perspectives.

Invited for this month's cover is the collaborative group of Dr. Carol Sze Ki Lin and Dr. Xiang Wang.

Tribo-charge enhanced hybrid air filter masks for efficient particulate matter capture with greatly extended service life.

Face masks have been an effective and indispensable personal protective measure against particulate matter pollutants and respiratory diseases, especially the novel Coronavirus disease recently. However, disposable surgical face masks suffer from low filtration efficiency for particles ranging from nano- to micro-size, and the limited service life of ~ 4 h. Here, a nano/micro fibrous hybrid air filter mask composing of electrospun nanofibrous network and poly(3,4-ethylenedioxythiophene:poly(styrenesulfonate) coated polypropylene (PP) is proposed.

Biotechnology of Plastic Waste Degradation, Recycling, and Valorization: Current Advances and Future Perspectives.

Although fossil-based plastic products have many attractive characteristics, their production has led to severe environmental burdens that require immediate solutions. Despite these plastics being non-natural chemical compounds, they can be degraded and metabolized by some microorganisms, which suggests the potential application of biotechnologies based on the mechanism of plastic biodegradation. In this context, microbe-based strategies for the degradation, recycling, and valorization of plastic waste offer a feasible approach for alleviating environmental challenges created by the accumulation of plastic waste.

Carboxymethyl cellulose-chitosan composite hydrogel: Modelling and experimental study of the effect of composition on microstructure and swelling response.

Molecular recognition is essential for the advancement of functional supramolecular natural polymer-based hydrogels. First, a series of carboxymethyl cellulose (CMC)-chitosan (CSN) hydrogels crosslinked with fumaric acid are studied, where the influence of composition on microstructure and swelling is investigated using mathematical modelling and experiment and the hydrolytic properties, microstructure parameters and physicochemical properties are examined. Second, best fit values for the responses are obtained using multiple linear regression and MATLAB R2020a curve fitting and predictive models are generated.

Nanogap and Environmentally Stable Triboelectric Nanogenerators Based on Surface Self-Modified Sustainable Films.

The advancement of wearable electronics and environmental awareness requires a wearable triboelectric nanogenerator (TENG) to feature the concepts of sustainability and environmental suitability. While most wearable TENGs are developed based on complex surface modification approaches to avoid the necessity of a physical spacer, herein a nanogap TENG is fabricated based on surface self-modified sustainable polymer films. Compared with poly(lactic acid) (PLA)-based and polycaprolactone (PCL)-based TENGs, the polybutylene succinate (PBS)-based TENG shows the highest output performance, representing up to 3.

Carbon Dot-Based Composite Films for Simultaneously Harvesting Raindrop Energy and Boosting Solar Energy Conversion Efficiency in Hybrid Cells.

Energy harvesting has drawn worldwide attention as a sustainable technology, while combining several approaches in a single device to maximize the overall energy output holds great promise to offer valuable technologies able to alleviate the energy crisis. Here, we present a hybrid cell composed of a silicon solar cell and a water-droplet-harvesting triboelectric nanogenerator (WH-TENG) with the capacity of harvesting both solar and raindrop energies. A transparent and solution processable carbon dot-based composite film is introduced as a dual-functional layer, acting as the transmittance enhancement layer of the solar cell as well as an ionic conductor of the WH-TENG.

MOF-Derived Sulfide-Based Electrocatalyst and Scaffold for Boosted Hydrogen Production.

Metal-organic frameworks (MOFs) can act as precursors or templates to a myriad of nanostructured materials that are difficult to prepare. In this study, Co-MOF nanorods (NRs) were prepared at room temperature followed by a calcination and hydrothermal sulfurization strategy to transform the MOF into CoS NRs on carbon cloth (CoS/CC). Intriguingly, the resultant 3D sulfide NRs can serve as scaffolds to electrodeposit layered double hydroxides (LDHs) on the surfaces.

Seed-Assisted Growth for Low-Temperature-Processed All-Inorganic CsPbIBr Solar Cells with Efficiency over 10.

All-inorganic CsPbIBr perovskite has recently received growing attention due to its balanced band gap and excellent environmental stability. However, the requirement of high-temperature processing limits its application in flexible devices. Herein, a low-temperature seed-assisted growth (SAG) method for high-quality CsPbIBr perovskite films through reducing the crystallization temperature by introducing methylammonium halides (MAX, X = I, Br, Cl) is demonstrated.

Mechanism of Water Effect on Enhancing the Photovoltaic Performance of Triple-Cation Hybrid Perovskite Solar Cells.

The water effect on the performance of perovskite solar cells has been intensively studied in recent years. However, the conflicting conclusions derived from different studies make it impossible to fully understand the mechanism involved. Besides, all studies have concentrated on single methylammonium cation perovskites.

In situ inclusion of thiocyanate for highly luminescent and stable CHNHPbBr perovskite nanocrystals.

In this work, an in situ thiocyanate inclusion method for the fabrication of highly luminescent and stable CH3NH3PbBr3 perovskite nanocrystals (NCs) is developed, employing Pb(SCN)2 as the lead precursor to partially or totally replace PbBr2 in the ligand-assisted reprecipitation (LARP) process. The in situ approach not only avoids the introduction of impurity elements, but also more interestingly incorporation of thiocyanate can control the crystallinity, particle size, luminescence and stability of CH3NH3PbBr3 NCs in a simple and effective manner. By adjusting the thiocyanate concentration, the photoluminescence (PL) of the synthesized CH3NH3PbBr3 NCs can be tuned in a range of 473-526 nm, as characterized by narrow emission line widths of 21-28 nm and outstanding photoluminescence quantum yields (PLQYs) of 73% to 96%.

UV-Induced Photocatalytic Cashmere Fibers.

Cashmere with UV-induced photocatalytic properties is developed for the first time by applying nanocrystalline anatase TiO₂ colloid that is free of inorganic acids and organic solvents via a facile low-temperature one-step sol-gel process. The coated cashmere exhibits remarkable UV-induced photodegradation of methyl orange. Furthermore, the photocatalytic nano-coating on cashmere exhibits significant stability after repetitive washing cycles without the need for chemical or physical pretreatment, where the photocatalytic activities remain almost unchanged after three washing cycles while maintaining a water contact angle above 150°.

Thermal Stability-Enhanced and High-Efficiency Planar Perovskite Solar Cells with Interface Passivation.

As the electron transport layer (ETL) of perovskite solar cells, oxide semiconductor zinc oxide (ZnO) has been attracting great attention due to its relatively high mobility, optical transparency, low-temperature fabrication, and good environment stability. However, the nature of ZnO will react with the patron on methylamine, which would deteriorate the performance of cells. Although many methods, including high-temperature annealing, doping, and surface modification, have been studied to improve the efficiency and stability of perovskite solar cells with ZnO ETL, devices remain relatively low in efficiency and stability.

Investigation on the mechanism of non-photocatalytically TiO2 -induced reactive oxygen species and its significance on cell cycle and morphology.

Titanium dioxide (TiO2 ) nanoparticles are widely used in daily human life, and were reported to elicit biological effects such as oxidative stress either generating reactive oxygen species (ROS) or causing cell necrosis without generating ROS, whose underlying molecular mechanisms are not yet known. In this study, the role of dissolved oxygen in TiO2 catalytic activity in dark environment, and long-term cytotoxic effects of TiO2 exposure were investigated. To determine the effect of dissolved oxygen, the anatase-TiO2 nanoparticle suspension was prepared both in deoxygenated and regular MilliQ water, and a ~ 9-fold higher ROS in regular MilliQ samples was observed compared to deoxygenated samples while in the dark, which suggested dissolved oxygen as the driving agent behind the TiO2 catalytic reaction.