Room temperature synthesis of CdSe/CdS triangular nanoemitters and their stabilization in colloidal state and sol-gel glass.

Heterostructured cadmium-based core-shell nanoparticles (NPs) are the subject of research because of not only fundamental scientific advances but also a range of technological applications. To increase the range of applications of nanoparticles, it is possible to immobilise them in sol-gel glass that can be easily manufactured and shaped, keeping the properties of the dispersed particles. This allows the creation of new bulk optical materials with tailored properties, opening up opportunities for various technological applications such as lighting or sensing.

Luminescence Dynamics of Single Self-Assembled Chains of Förster (FRET)-Coupled CdSe Nanoplatelets.

Self-assembled linear chains of CdSe nanoplatelets are known to exhibit highly efficient Förster resonant energy transfer (FRET) leading to fast exciton diffusion between platelets. Here, we compare the luminescence decay dynamics of single nanoplatelets, clusters of a few platelets, and self-assembled chains. As the number of stacked platelets is increased, we show that the luminescence decay becomes faster, which can be interpreted as the FRET-mediated effect of quenchers: excitons may diffuse to nearby quenchers so that their decay rate is increased.

Curvature and self-assembly of semi-conducting nanoplatelets.

Semi-conducting nanoplatelets are two-dimensional nanoparticles whose thickness is in the nanometer range and controlled at the atomic level. They have come up as a new category of nanomaterial with promising optical properties due to the efficient confinement of the exciton in the thickness direction. In this perspective, we first describe the various conformations of these 2D nanoparticles which display a variety of bent and curved geometries and present experimental evidences linking their curvature to the ligand-induced surface stress.