Coordination Chemistry and Reactivity of a Lewis Acidic Di-Zinc Framework Supported by Bisphenoxymethanone Ligands.

We present the synthesis, structural characterization, and reactivity studies of a tetra-zinc complex supported by the bisphenoxymethanone ligands and its transformation into various di-zinc architectures. Our findings highlight the potential of these complexes in molecular recognition, supramolecular chemistry, and catalysis.

Organocatalytic Ring-Opening Polymerization of -Caprolactone Using (-('-butylimidazolium)alkane Dicationic Ionic Liquids as the Metal-Free Catalysts: Polymer Synthesis, Kinetics and DFT Mechanistic Study.

In this work, we successfully synthesized high thermal stable 1,n-(-('-butylimidazolium)alkane hexafluorophosphates (1,n-[Bim][PF], n = 4, 6, 8, and 10) catalysts in 55-70% yields from imidazole which were applied as non-toxic DILs catalysts with 1-butanol as initiator for the bulk ROP of -caprolactone (CL) in the varied ratio of CL/BuOH/1,4-[Bim][PF] from 200/1.0/0.25-4.

Organo-Cobalt Complexes in Reversible-Deactivation Radical Polymerization.

Cobalt complexes have played an essential role in different chemical reactions. One of them that has attracted substantial attention in polymer science is cobalt mediated radical polymerization (CMRP), which is famous for its remarkable efficiency in controlling the radical polymerization of vinyl acetate (VAc) and other less active monomers (LAMs). Two pathways, reversible termination (RT) and degenerative transfer (DT), were recognized to control the polymerization in CMRP and could be further used to rationalize the mechanism of other RDRP methods.