Dataset linking women's maternity care experiences with hospital environment and governance in Ireland.

Many scholars argue that there is a deepening crisis of trust in healthcare systems. What is not contested is the centrality of public trust in building reputational value in healthcare organisations. However, there is a dearth of research focused on better understanding how trust in healthcare institutions, and the healthcare workforce, can be sustainably cultivated.

Crystal structures of eight- and ten-membered cyclic bis-anisyl-phosphono-thioyl disulfanes and comparison with their -ferrocenyl analogues.

Two new crystal structures of eight- and ten-membered cyclic bis-anisyl-phosphono-thioyl disulfanes, namely 2,5-bis-(4-meth-oxy-phen-yl)-1,6,3,4,2λ,5λ-dioxadi-thiadi-phospho-cane-2,5-di-thione, CHOPS, and 2,5-bis-(4-meth-oxy-phen-yl)-1,6,3,4,2λ,5λ-dioxadi-thia-diphosphecane-2,5-di-thione, CHOPS, have been determined and compared to structures of the ferrocenyl analogues. The eight-membered rings have similar conformations (TBC) but the ten-membered macrocycles are differently puckered. Structural parameters of the relevant SPSSPS motif have been analysed and are discussed in detail.

Simultaneous determination of individual isothiocyanates in plant samples by HPLC-DAD-MS following SPE and derivatization with N-acetyl-l-cysteine.

The procedure for the isothiocyanates (ITCs) determination that involves derivatization with N-acetyl-l-cysteine (NAC) and separation by HPLC was developed. Prior to derivatization, plant ITCs were isolated and purified using solid-phase extraction (SPE). The optimum conditions of derivatization are: 500μL of isopropanolic eluate obtained by SPE combined with 500μL of derivatizing reagent (0.

Isothiocyanates may chemically detoxify mutagenic amines formed in heat processed meat.

Meat consumption represents a dietary risk factor increasing the incidence of common cancers, probably due to carcinogenic amines (HAAs) formed upon meat heating. Interestingly, cancers whose incidence is increased by meat consumption, are decreased in populations consuming brassica vegetables regularly. This inverse correlation is attributed to brassica anticarcinogenic components, especially isothiocyanates (ITCs) that stimulate detoxification of food carcinogens.