Comparative Nutritional Profile of Publicly Procured Foods for School Meals in Federal Schools in Northeastern Brazil Pre- and Post-COVID-19 Pandemic.

Unlabelled: School meals play a critical role in supporting students' biopsychosocial growth, development, learning, academic performance, and the establishment of healthy eating habits. In public institutions, food procurement is conducted through formal public procurement processes. However, emphasizing cost-effectiveness in bidding criteria, such as prioritizing the lowest product price, may inadvertently encourage the acquisition of foods high in critical nutrients.

The Elusive Ternary Intermediates of Chiral Phosphoric Acids in Ion Pair Catalysis─Structures, Conformations, and Aggregation.

In ion-pair catalysis, the last intermediate structures prior to the stereoselective transition states are of special importance for predictive models due to the high isomerization barrier between - and -substrate double bonds connecting ground and transition state energies. However, in prior experimental investigations of chiral phosphoric acids (CPA) solely the early intermediates could be investigated while the key intermediate remained elusive. In this study, the first experimental structural and conformational insights into ternary complexes with CPAs are presented using a special combination of low temperature and relaxation optimized N HSQC-NOESY NMR spectroscopy to enhance sensitivity.

Adaptive dynamics of dairy goats in a temperate region.

Physiological and hematological traits and productive performance of Spanish Majorera and Palmera goats reared on the Island of Tenerife-Spain were assessed. 50 adult, clinically healthy, multiparous female goats were studied for 18 months. The data were analyzed in a two (breeds) x four (season) factorial scheme.

Production of benzyl-based esters from used soybean cooking oil as renewable plasticizers for flexible PVC films: Exploring new applications for lipases in emerging technologies.

The objective of this study was to produce new and renewable bio-based plasticizers from used soybean cooking oil (USCO). First, USCO was completely converted into free fatty acids (FFAs) using lipase from Candida rugosa. Next, these FFAs were enzymatically esterified with benzyl alcohol in solvent-free systems.