This paper presents the results of an evaluation of corrosion properties of PEO pretreated AlMg3 aluminum alloy samples with polymer coatings obtained by dip-coating in a suspension of superdispersed polytetrafluoroethylene (SPTFE) in a solution of polyvinylidene fluoride (PVDF) in N-methyl-2-pyrrolidone at different PVDF:SPTFE ratios (1:1, 1:3, 1:5, and 1:10). The electrochemical tests showed that samples with a coating formed at a ratio of PVDF to SPTFE of 1:5 possessed the best corrosion properties. The corrosion current density of these samples was more than five orders of magnitude lower than this parameter for bare aluminum alloy.
View Article and Find Full Text PDFIn this work, the micro-arc oxidation method is used to fabricate surface-modified complex-structured titanium implant coatings to improve biocompatibility. Depending on the utilized electrolyte solution and micro-arc oxidation process parameters, three different types of coatings (one of them-oxide, another two-calcium phosphates) were obtained, differing in their coating thickness, crystallite phase composition and, thus, with a significantly different biocompatibility. An analytical approach based on X-ray computed tomography utilizing software-aided coating recognition is employed in this work to reveal their structural uniformity.
View Article and Find Full Text PDFThis paper presents the results of an evaluation of anti-icing properties of samples obtained by plasma electrolytic oxidation (PEO) with a subsequent application of superdispersed polytetrafluoroethylene (SPTFE) and polyvinylidenefluoride (PVDF). A combined treatment of the samples with SPTFE and PVDF is also presented. It is revealed that impregnation of a PEO layer with fluoropolymer materials leads to a significant increase in surface relief uniformity.
View Article and Find Full Text PDFWrought Al-Cu-Mg aluminum alloy (D16) was treated by bipolar plasma electrolytic oxidation to create a base plasma electrolytic oxidation (PEO)-coating with corrosion protection and mechanical properties superior to bare alloy's natural oxide layer. Additional protection was provided by the application of polymer, thus creating a composite coating. Electrochemical and scratch tests, scanning electron microscopy, energy-dispersive X-ray spectroscopy, X-ray diffraction studies were performed.
View Article and Find Full Text PDFA comparative analysis of the structure, properties and the corrosion behavior of the micro-arc coatings based on Sr-substituted hydroxyapatite (Sr-HA) and Sr-substituted tricalcium phosphate (Sr-TCP) deposited on Mg0.8Ca alloy substrates was performed. The current density during the formation of the Sr-HA coatings was higher than that for the Sr-TCP coatings.
View Article and Find Full Text PDFThe high electrochemical activity of the aircraft 1579 aluminium alloy with a welded joint and the necessity of the coating formation to protect this material against corrosion as well as to increase the stability of the weld interface in the corrosive medium has been previously established. In this work, two suggested methods of protective coating formation based on plasma electrolytic oxidation (PEO) in tartrate-fluoride electrolyte significantly increased the protective properties of the welded joint area of the 1579 Al alloy. The electrochemical properties of the formed surface layers have been investigated using SVET (scanning vibrating electrode technique) and SIET (scanning ion-selective electrode technique), EIS (electrochemical impedance spectroscopy), OCP (open circuit potential), and PDP (potentiodynamic polarization) in 0.
View Article and Find Full Text PDFThis work consists of two parts. In the first part, the kinetics and mechanism of corrosion on the surface of the welded joint area of the aircraft 1579 aluminium alloy have been studied using SVET (scanning vibrating electrode technique) and SIET (scanning ion-selective electrode technique) in 0.5 M NaCl.
View Article and Find Full Text PDFThe method of formation of bioactive calcium-phosphate coating on medical titanium alloy Ti-6Al-4V (3.5-5.3% V; 5.
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