CoZr nanocomposites in a ceramic-metal AlO(OH)/Al matrix with a different Co/Zr ratio and its potential for syngas processing.

We investigated the possibility of synthesizing Co nanoparticles in CoZrH/AlO(OH)/Al ceramic-metal catalysts and controlling the catalytic properties of these nanoparticles in syngas conversion by changing the Co/Zr ratio. The CoZr nanocomposites were obtained from metal powders by mechanochemical activation in a high-energy mill under an argon atmosphere, followed by treatment with hydrogen at high pressure and room temperature. Ceramic-metal catalysts were prepared by mixing the corresponding CoZrH powder nanocomposite (30 wt%) with powdered aluminum (70 wt%), hydrothermal treatment of the mixture and subsequent calcination.

Co and CoO in the Hydrolysis of Boron-Containing Hydrides: HO Activation on the Metal and Oxide Active Centers.

This work focuses on the comparison of H evolution in the hydrolysis of boron-containing hydrides (NaBH, NHBH, and (CHNHBH)) over the Co metal catalyst and the CoO-based catalysts. The CoO catalysts were activated in the reaction medium, and a small amount of CuO was added to activate CoO under the action of weaker reducers (NHBH, (CHNHBH)). The high activity of CoO has been previously associated with its reduced states (nanosized CoB).

Approaches to the design of efficient and stable catalysts for biofuel reforming into syngas: doping the mesoporous MgAlO support with transition metal cations.

The mesoporous MgAlO support is promising for the design of efficient and stable to coking catalysts for natural gas and biofuel reforming into syngas. This work aims at doping this support with transition metal cations (Fe, Cr, Ti) to prevent the incorporation of Ni and rare-earth cations (Pr, Ce, Zr), loaded by impregnation, into its lattice along with providing additional sites for CO activation required to prevent coking. Doped MgAlMeO (Me = Fe, Ti, Cr) mesoporous supports prepared by the one-pot evaporation-induced self-assembly method with Pluronic P123 triblock copolymers were single-phase spinels.

Effect of Ce/Zr Composition on Structure and Properties of CeZrO Oxides and Related Ni/CeZrO Catalysts for CO Methanation.

CeZrO oxides (x = 0.1, 0.25, 0.

Mechanism studies of the conversion of 13C-labeled n-butane on zeolite H-ZSM-5 by using 13C magic angle spinning NMR spectroscopy and GC-MS analysis.

By using 13C MAS NMR spectroscopy (MAS = magic angle spinning), the conversion of selectively 13C-labeled n-butane on zeolite H-ZSM-5 at 430-470 K has been demonstrated to proceed through two pathways: 1) scrambling of the selective 13C-label in the n-butane molecule, and 2) oligomerization-cracking and conjunct polymerization. The latter processes (2) produce isobutane and propane simultaneously with alkyl-substituted cyclopentenyl cations and condensed aromatic compounds. In situ 13C MAS NMR and complementary ex situ GC-MS data provided evidence for a monomolecular mechanism of the 13C-label scrambling, whereas both isobutane and propane are formed through intermolecular pathways.