Naturally dissolved arsenic concentrations in the Alpine/Mediterranean Var River watershed (France).

A detailed study on arsenic (As) in rocks and water from the Var River watershed was undertaken aiming at identifying (i) the origin and the distribution of As in this typical Alpine/Mediterranean basin, and (ii) As input into the Mediterranean Sea. Dissolved As concentrations in the Var River range from 0.1 to 4.

Formation of MSeO(4)(aq) complexes (M(2+) = Mg(2+), Co(2+), Ni(2+), Cu(2+), Cd(2+)) studied as a function of temperature by affinity capillary electrophoresis.

Complexation of divalent cations (Mg(2+), Co(2+), Ni(2+), Cu(2+), Cd(2+)) by selenate ligand was studied by ACE (UV indirect detection) in 0.1 mol/L NaNO(3) ionic strength solutions at various temperatures (15, 25, 35, 45 and 55°C). For each solution, a unique peak was observed as a result of a fast equilibrium between the free ion and the complex (labile systems).

Formation of CaSO4(aq) and CaSeO4(aq) studied as a function of ionic strength and temperature by CE.

Ca(2+) complexation by both sulfate and selenate ligands was studied by CE. The species were observed to give a unique retention peak as a result of a fast equilibrium between the free ions and the complexes. The change in the corresponding retention time was interpreted with respect to the equilibrium constant of the complexation reaction.

Evidence of different stoichiometries for the limiting carbonate complexes across the lanthanide(III) series: a capillary electrophoresis-mass spectrometry study.

The electrophoretic mobilities (mu ep,Ln) of twelve lanthanides (not Ce, Pr and Yb) were measured by CE-ICP-MS in 0.15 and 0.5 mol L(-1) Alk2 CO3 aqueous solutions for Alk+ = Li+, Na+, K+ and Cs+.