Nanoimprinting Solution-Derived Barium Titanate for Electro-Optic Metasurfaces.

Electro-optic metasurfaces have demonstrated significant potential in enhancing the modulation speed and efficiency for fast and large-scale free-space optical devices. Barium titanate has a strong electro-optic Pockels coefficient, but its availability in thin-film form is restricted due to costly growth processes or low thickness. Here, we fabricated active metasurfaces using an etch-free bottom-up process with sol-gel-based polycrystalline barium titanate with a large electro-optic coefficient similar to bulk lithium niobate.

Photonic Assemblies of Randomly Oriented Nanocrystals for Engineered Nonlinear and Electro-Optic Effects.

Nonlinear crystals that have a noncentrosymmetric crystalline structure, such as lithium niobate (LiNbO) and barium titanate (BaTiO) exhibit nonzero second-order tensor susceptibilities (χ) and linear electro-optic coefficients ( ). The constraints associated with top-down nanofabrication methods have led to bottom up approaches to harness the strong nonlinearities and electro-optical properties. Here, we present an overview of photonic assemblies made of randomly oriented noncentrosymmetric nanocrystals via bottom-up fabrication methods.

Second-harmonic generation tuning by stretching arrays of GaAs nanowires.

We present a wearable device with III-V nanowires in a flexible polymer, which is used for active mechanical tuning of the second-harmonic generation intensity. An array of vertical GaAs nanowires was grown with metalorganic vapour-phase epitaxy, then embedded in polydimethylsiloxane and detached from the rigid substrate with mechanical peel off. Experimental results show a tunability of the second-harmonic generation intensity by a factor of two for 30% stretching which matches the simulations including the distribution of sizes.