We experimentally demonstrated the generation of domain-wall dark pulse in an Erbium-doped fiber laser using the combination of a 10 cm graded index multimode fiber sandwiched by single mode fibers as artificial saturable absorber. The interaction of phase difference in grade index multimode fiber allowed the stable dual-wavelength oscillation in the cavity. The dual-wavelength centered at 1567.
View Article and Find Full Text PDFThe use of chemical insecticides in agriculture has posed several challenges to environment and ecosystem health. Pesticides of biological origin are considered to be suitable for sustainable environment. In the present study bioactive compounds from Penicillium sp.
View Article and Find Full Text PDFThis paper discusses the structural orientations and the physico-chemical properties of a single crystal of 2-amino-4,6-dimethoxypyrimidinium hydrogen (2,3)-tartrate 2-amino-4,6-dimethoxypyrimidine (2ADT). The experimental investigation of the properties of the compound improves the potential for the utilization of the crystalline compound in the fabrication of optical limiting and nonlinear optical devices. For the growth process, an organic nonlinear optical crystal of 2ADT is synthesized conventionally at varying molar concentrations to achieve an excellent yield.
View Article and Find Full Text PDFThis paper reports the photoluminescence and nonlinear optical (NLO) properties of Ce₂O₃-TiO₂ nanocomposites synthesized via sol-gel process with different concentrations of cerium. The physical characterization studies by means of XRD indicated for the successful incorporation of Ce into the lattice of TiO₂, while the UV-visible spectra for an absorption edge shift of TiO₂ to the higher wavelength side following the Ce addition, and FESEM analysis for the morphology and particles sizes of the synthesized materials. On testing of the photoluminescence properties recorded through time-resolved fluorescence (TCSPC) technique, a decrease in the intensity of TiO₂ with that of increased Ce concentration was observed and is due to an escalation in the number of oxygen vacancies.
View Article and Find Full Text PDFBackground: The ongoing COVID 19 pandemic brought about a sudden disruption to the way medical services are rendered in our country. Management of maxillofacial injuries, especially isolated mandibular fractures by surgical methods, became near impossibility because of the restrictions and other concerns related to the pandemic.
Methods: The individuals who suffered isolated mandibular fracture because of trauma were included, to undergo conservative treatment methods with adaptations for the pandemic.
Spectrochim Acta A Mol Biomol Spectrosc
February 2021
The materials of Cyclohexylamine with 1,5-naphthalenedisulfonic acid and 3,5-dinitrosalicylic acid were used to synthesize the bis(cyclohexylammonium)-1,5-naphthalenedisulfonate (CA15NS) and bis(cyclohexylammonium)-3,5-dinitrosalicylate (CA35NS) compounds and single crystals of these compounds were grown successfully by low temperature solution growth technique. Crystal systems of the samples were identified for both the samples of CA15NS and CA35NS by the obtained unit cell parameters of the grown crystals which is determined by single crystal X-ray diffraction (SCXRD) analysis, the crystals of CA15NS and CA35NS are crystallized in monoclinic crystal structures. The powder X-ray diffraction (PXRD) analysis also was carried out for the title samples.
View Article and Find Full Text PDFActa Crystallogr B Struct Sci Cryst Eng Mater
April 2020
Two cocrystals of 18-crown-6 with isophthalic acid derivatives, 5-hydroxyisophthalic acid and trimesic acid, have been successfully grown by the slow evaporation solution growth technique. Crystal structures of (18-crown-6)·6(5-hydroxyisophthalic acid)·10(HO) (I) and (18-crown-6)·2(trimesic acid)·2(HO) (II) elucidated by single crystal X-ray diffraction reveal that both cocrystals pack the centrosymmetric triclinic space group P{\overline 1}. The molecules are associated by strong/weak hydrogen bonds, π.
View Article and Find Full Text PDFAlkali borate glasses activated with trivalent europium ions and rooted with gold (Au) nanoparticles (NPs) were synthesised through a melt quenching process involving a selective thermochemical reduction and their applicability as photonic materials was assessed in detail. Non-linear optical (NLO) measurements were performed using a Z-scan approach in the wavelength range of 700-1000 nm. The open aperture Z-scan signatures for the Eu-containing glasses embedded with and without the Au NPs established a reverse saturable absorption (RSA) at all of the studied wavelengths ascribed to the two-photon absorption (2PA).
View Article and Find Full Text PDFA facile and eco-friendly hydrothermal method was used to prepare carbon quantum dots (CQDs) using orange waste peels. The synthesized CQDs were well dispersed and the average diameter was 2.9 ± 0.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
April 2015
The copper doped lithium tetraborate (LTB:Cu) nanoparticles were synthesized by sol-gel method and characterized by XRD (tetragonal structure) and by FESEM (sphere-like nanoparticle). UV-Vis studies show that there is no strong absorption in the visible region. In the luminescence spectrum, the emission peak at 370 nm reveals the presence of Cu+ in LTB lattice.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
March 2015
Single crystals of ethylenediaminium di(4-nitrophenolate) [EDA4NP] were grown by slow evaporation solution growth technique using ethanol as solvent at constant temperature. It crystallizes in monoclinic centrosymmetric space group C2/c with cell dimension a=11.326Ǻ, b=7.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
February 2015
Manganese doped Li2B4O7 nano crystallites were prepared by chemical method and characterized by XRD, FTIR, UV and fluorescence spectra. FESEM reveals that the particles are coagulated and the particle size is in the range of 50-107 nm. Bands appear at 682-769 cm(-1) corresponds to the bending of B-O linkage in borate network.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
January 2015
The organic material 4-dimethylaminobenzaldehyde single crystals were grown by slow evaporation technique. The grown crystal was confirmed by the single crystal and powder X-ray diffraction analyses. The functional groups of the crystal have been identified from the Fourier Transform Infrared (FTIR) and FT-Raman studies.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
April 2008
Solid-state dye-doped polymers are attractive alternative to the conventional liquid dye solutions. In this paper, nonlinear properties of the dye Acid Fuchsin has been studied. The third-order nonlinear optical properties of Acid Fuchsin dye in 1-butanol and dye-doped polymer film were measured by the Z-scan technique using 532 nm diode pumped Nd:Yag laser.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
September 2007
Solid-state dye-doped polymers are attractive alternative to the conventional liquid dye solutions. In this paper, nonlinear properties of the dye Pararosanilin has been studied. The third-order nonlinear optical properties of Pararosanilin dye in 1-butanol and dye-doped polymer film were measured by the Z-scan technique using 532 nm diode pumped Nd:Yag laser.
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