CCl(4) dissociation on the ice I(h) surface: an excess electron mediated process.

Dissociation of chlorofluorocarbons in the atmosphere is a heterogeneous process that takes place mainly on the surface of ice particles. Recently an enhancement of the dissociation rate due to excess electrons has been shown theoretically and correspondingly measured experimentally. Our density functional theory calculations show that CCl(4) dissociates due to an excess electron with an energy gain of 0.