This report investigates the preparation, characterization, and application of activated carbon derived from Spathodea campanulata flowers (SCAC) to remove Congo Red (CR) dye from aqueous streams. SCAC was synthesized using orthophosphoric acid activation which yielded a mesoporous material with a specific surface area of (986.41 m/g), significantly exceeding values reported for flower-derived activated carbons in the available literature.
View Article and Find Full Text PDFThe widespread use of 2,4-Dichlorophenoxyacetic acid (2,4-D) as a weedkiller has resulted in its persistence in the environment, leading to surface and groundwater pollution. In this study, the fixed bed column experiments were performed to remove 2,4-D from aqueous solutions using magnetic activated carbon derived from Peltophorum pterocarpum tree pods. The evaluation was done on effects of operating parameters such as bed depth (2-4 cm), influent flow rate (4.
View Article and Find Full Text PDFAs wastewater contains a variety of contaminating bacteria and oily residues, there is an urgent need for environmentally safe bactericidal agents and surfactants which can be applied for wastewater treatment. The present study emphasizes on the potential of hydrophobin-like protein (HFB-NJ1) extracted from sporulating mycelia of Aspergillus sp. NJ1 for wastewater treatment.
View Article and Find Full Text PDFThe current investigation reports the usage of adaptive neuro-fuzzy inference system (ANFIS) and artificial neural network (ANN), the two recognized machine learning techniques in modelling tetracycline (TC) adsorption onto Cynometra ramiflora fruit biomass derived activated carbon (AC). Many characterization methods utilized, confirmed the porous structure of synthesized AC. ANN and ANFIS models utilized pH, dose, initial TC concentration, mixing speed, time duration, and temperature as input parameters, whereas TC removal percentage was designated as the output parameter.
View Article and Find Full Text PDFEnviron Res
June 2024
The present study reports the synthesis, characterization, and application of sustainable magnetic biochar composite. The inedible fruits of Vateria indica, a powerful ayurvedic plant were hydrothermally transformed into magnetic biochar (BC-FeO) in a single step and characterized by several sophisticated techniques. FESEM analysis portrayed fibrous irregular mesh-like biochar with surface clustered FeO nanoparticles, while the incidence of carbon, oxygen, and iron in the elemental analysis by EDS established magnetic biochar formation.
View Article and Find Full Text PDFChemosphere
February 2024
The usage of various herbicides in the agricultural field leads to water pollution which is a big threat to the environment. Herein, the pods of the Peltophorum pterocarpum tree were used as a cheap resource to synthesize activated carbon (AC) by low-temperature carbonization to remove 2,4-dichlorophenoxyacetic acid (2,4-D) - an abundantly used herbicide. The exceptional surface area (1078.
View Article and Find Full Text PDFBenzo(a)pyrene, a five-ring polyaromatic hydrocarbon, originating from coal tar, crude oil, tobacco, grilled foods, car exhaust etc, is highly persistent in the environment. It has been classified as a Group I carcinogen, as on its ingestion in human body, diol epoxide metabolites are generated, which bind to DNA causing mutations and eventual cancer. Among various removal methods, bioremediation is most preferred as it is a sustainable approach resulting in complete mineralization of benzo(a)pyrene.
View Article and Find Full Text PDFMicroplastics have been identified in all living forms including human beings, the present need is to restrain its spread and devise measures to remediate microplastics from polluted ecosystems. In this regard, the present review emphasizes on the occurrence, sources detection and toxic effects of microplastics in various ecosystems. The removal of microplastics is prevalent by various physico-chemical and biological methods, although the removal efficiency by biological methods is low.
View Article and Find Full Text PDFThe discovery of zero-dimensional carbonaceous nanostructures called carbon dots (CDs) and their unique properties associated with fluorescence, quantum confinement and size effects have intrigued researchers. There has been a substantial increase in the amount of research conducted on the lines of synthesis, characterization, modification, and enhancement of properties by doping or design of composite materials, and a diversification of their applications in sensing, catalysis, optoelectronics, photovoltaics, and imaging, among many others. CDs fulfill the need for inexpensive, simple, and continuous environmental monitoring, detection, and remediation of various contaminants such as metals, dyes, pesticides, antibiotics, and other chemicals.
View Article and Find Full Text PDFThe present study aimed at the synthesis of cobalt oxide nanoparticles (CONPs) mediated by leaf extract of Muntingia calabura using a rapid and simple method and evaluation of its photocatalytic activity against methylene blue (MB) dye. UV-vis absorption spectrum showed multiple peaks with an optical band gap of 2.05 eV, which was concordant with the literature.
View Article and Find Full Text PDFThe current study emphasizes the activated carbon fabrication from rubber fig leaves, the establishment of its composite with iron oxide nanoparticles (RFAC@FeO), and its relevance in the adsorptive elimination of tetracycline. The physical and functional properties of RFAC@FeO nanocomposite were uncovered by multiple approaches. Elemental analysis portrayed the existence of carbon, oxygen, and iron, while FESEM analysis revealed that FeO nanoparticle agglomerates were entrenched in the activated carbon matrix rendering it a rough abrasive texture.
View Article and Find Full Text PDFOverexploitation of natural resources to meet human needs has considerably impacted CO emissions, contributing to global warming and severe climatic change. This review furnishes an understanding of the sources, brutality, and effects of CO emissions and compelling requirements for metamorphosis from a linear to a circular bioeconomy. A detailed emphasis on microalgae, its types, properties, and cultivation are explained with significance in attaining a zero-carbon circular bioeconomy.
View Article and Find Full Text PDFHerein, the sustainable fabrication of magnetic iron oxide nanoadsorbent prepared with activated carbon of inedible Cynometra ramiflora fruit has been investigated. Activated carbon was obtained from phosphoric acid-treated C. ramiflora fruit, which was then utilized for the synthesis of magnetic nanocomposite (CRAC@FeO).
View Article and Find Full Text PDFIn the present study, ferric oxide nanoparticles impregnated with activated carbon from Ulva prolifera biomass (UPAC-FeO) were prepared and employed to remove 2,4-Dichlorophenoxyacetic acid (2,4-D) by adsorption. The UPAC-FeO nanocomposite was characterized for its structural and functional properties by a variety of techniques. The nanocomposite had a jagged, irregular surface with pores due to uneven scattering of FeO nanoparticles, whereas elemental analysis portrayed the incidence of carbon, oxygen, and iron.
View Article and Find Full Text PDFGlobal industrialisation and overexploitation of fossil fuels significantly impact greenhouse gas emissions, resulting in global warming and other environmental problems. Hence, investigations on capturing, storing, and utilising atmospheric CO create novel technologies. Few microorganisms, microalgae, and macroalgae utilise atmospheric CO for their growth and reduce atmospheric CO levels.
View Article and Find Full Text PDFNanotechnology is considered the budding discipline in various fields of science and technology. In this review, the various synthesis methods of iron and iron oxide nanoparticles were summarised with more emphasis on green synthesis - a sustainable and eco-friendly method. The mechanism of green synthesis of these nanomaterials was reviewed in recent literature.
View Article and Find Full Text PDFIn this study, magnetite nanoparticles (MNPs) were synthesized using the seaweed - Ulva prolifera, an amply found marine source in the Western coastal regions of India. The surface and other properties of MNPs were characterized by many sophisticated methods. Spherical nanoclusters were observed in the FESEM image and iron and oxygen elements were seen in EDS results.
View Article and Find Full Text PDFThe final sinkers of polyaromatic hydrocarbons are water sources, where they undergo bioaccumulation and biomagnification, leading to adverse mutagenic, carcinogenic, and teratogenic effects on exposure in flora, fauna, and humans. Two indigenous strains, Pseudomonas sp. WDE11 and Pseudomonas sp.
View Article and Find Full Text PDFEnviron Res
November 2022
This study deals with the synthesis of hydroxyapatite nanoparticles (HAPnps) mediated by Acacia falcata leaf extract. Aggregates of needle-shaped crystalline nanostructures were confirmed by FE-SEM and TEM analysis. Well-defined rings in the SAED patterns corroborated the polycrystalline nature of the HAPnps.
View Article and Find Full Text PDFThe conventional synthesis of hematite nanoparticles (HNPs) is expensive and creates secondary contaminants. Therefore, to combat these issues, there is a requirement for a cheap, effective, and eco-friendly technique. Herein, HNPs were prepared using the fruit extract of Spondias pinnata - an abundant source available in Western-coastal India.
View Article and Find Full Text PDFThe homeostasis of extremophiles is one that is a diamond hidden in the rough. The way extremophiles adapt to their extreme environments gives a clue into the true extent of what is possible when it comes to life. The discovery of new extremophiles is ever-expanding and an explosion of knowledge surrounding their successful existence in extreme environments is obviously perceived in scientific literature.
View Article and Find Full Text PDFZirconium oxide nanoparticles (ZrONPs) were prepared using the leaf extract of Muntingia calabura as a reductant. The absorption peak at 232 nm confirmed the signature peak for ZrONPs with band energy at 5.07 eV.
View Article and Find Full Text PDFHeavy metals are dumped into the environment as a result of human activities, posing a serious threat to ecology and human health. Surface water, potable drinking water, potable groundwater, and majority of wastewater include their traces, due to which, their detection by nanoparticles has received a lot of attention in recent years. Although microorganisms are utilized for green nanoparticle production, plant materials have recently been explored because they are more environmentally friendly, easier to scale up, and require fewer specific growth conditions.
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