Biochar is a carbon-rich, sponge-like material with intricate functionalities, making it suitable for various environmental remediation applications, including water treatment, soil amendment and, additives in construction materials, anaerobic digesters, and electrodes, among others. Its easy adaptability and low cost make it particularly attractive. This review highlights a range of biochar and surface-modified biochar exhibiting high uptake and degradation efficiencies for a broad spectrum of contaminants, including humic acid, disinfection by-products (DBPs), radioactive materials, dyes, heavy metals, antibiotics, microplastics, pathogens, Per- and polyfluoroalkyl substances (PFAS), and cytotoxins.
View Article and Find Full Text PDFSimultaneous biological nutrient removal (SBNR) using an anaerobic-anoxic-oxic phase is the key feature of advanced wastewater treatment plants (WWTPs). Removing ammonia, total nitrogen, and phosphorus concurrently with organic matter and suspended solids from wastewater is essential to meeting stringent effluent discharge standards via SBNR in WWTPs. More insight into the mechanisms of SBNR, i.
View Article and Find Full Text PDFHydrothermal and thermal-alkali pretreatment potential was investigated to enhance agro-wastes' anaerobic co-digestion (AcoD). The techno-economic (TEA) and life cycle assessment (LCA) of biogas upgrading (BioCNG) and energy generation via combined heat and power (CHP) processes for energy utilization were carried out to realize the environmental impacts and cost-effectiveness of the studied processes. Three AcoD conditions of untreated, hydrothermally (150 °C, 60 min) and thermal-alkali pretreated (1% NaOH, 150 °C- 60 min) wheat straw (WS) with food waste and cow manure were studied in semi-continuous mode for 340 days under variable organic loading rates (OLR, 1.
View Article and Find Full Text PDFSeveral nations around the world use rice as their primary food staple because of its tremendous nutritional value. India's expanding population has sparked a proliferation of rice mills as a result of the country's growing rice demand. However, small and medium-scale industries lack adequate facilities for processing effluents and other waste generated.
View Article and Find Full Text PDFAdvanced steam explosion pretreatment, i.e., the Thermal hydrolysis process (THP) is applied mainly to improve the sludge solubilization and subsequent methane yield in the downstream anaerobic digestion (AD) process.
View Article and Find Full Text PDFThe semi-continuous anaerobic co-digestion (AcoD) of thermal and thermal-alkali pretreated organic fraction of municipal solid waste (OFMSW) and sewage sludge (SS) was studied under varying hydraulic retention times (HRT) and organic loading rates (OLR Three semi-continuous digesters were operated under control (non-pre-treated), thermally pretreated (125 °C), and thermal-alkali pretreated (125°C-3g/L NaOH) conditions at variable OLRs at 2.5, 4.0, 5.
View Article and Find Full Text PDFThe COVID-19 (coronavirus disease 2019) pandemic's steady condition coupled with predominance of emerging contaminants in the environment and its synergistic implications in recent times has stoked interest in combating medical emergencies in this dynamic environment. In this context, high concentrations of pharmaceutical and personal care products (PPCPs), microplastics (MPs), antimicrobial resistance (AMR), and soaring coinfecting microbes, tied with potential endocrine disruptive (ED) are critical environmental concerns that requires a detailed documentation and analysis. During the pandemic, the identification, enumeration, and assessment of potential hazards of PPCPs and MPs and (used as anti-COVID-19 agents/applications) in aquatic habitats have been attempted globally.
View Article and Find Full Text PDFLandfills are commonly used to manage solid waste, but they can contribute to microplastic (MPs) pollution. As plastic waste degrades in landfills, MPs are released into the surrounding environment, contaminating soil, groundwater, and surface water. This poses a threat to human health and the environment, as MPs can adsorb toxic substances.
View Article and Find Full Text PDFA significant amount of plastic waste is generated each year on a global scale, in which the maximum quantity of plastic waste is typically dumped in landfills in various parts of the world. Moreover, dumping plastic waste in landfills cannot address the issue of proper disposal; it simply delays the process. Exploiting waste resources entails environmental hazards because plastic wastes buried in landfills gradually break down into Microplastics (MPs) due to physical, chemical, and biological effects.
View Article and Find Full Text PDFThis study aimed to pretreat the waste activated sludge (WAS) by ultrasonication in an energy efficient way by combining sodium citrate with ultrasonic pretreatment at 0.03 g/g suspended solids (SS) of dosage. The ultrasonic pretreatment was done at various (20-200 W) power levels, sludge concentration (7 to 30 g/L), sodium citrate dosages (0.
View Article and Find Full Text PDFThe role of pesticides in enhancing global agricultural production is magnificent. However, their unmanaged use threatens water resources and individual health. A significant pesticide concentration leaches to groundwater or reaches surface waters through runoff.
View Article and Find Full Text PDFThe pinnacle of all the efforts of nutrient removal is practically put-down the moment biological cells are lysed, hydrolyzed or digested causing subsequent reappearance of assimilated nitrogen and phosphorus in any biological process. While sludge reduction requires high SRT, the enhanced phosphorus assimilative uptake demands low SRT. A novel reactor configuration for enhanced sludge and phosphorus removal was put to test by incorporating a side stream anaerobic reactor to an Anaerobic-Anoxic-Aerobic (AO) SBR with a pre-anoxic chamber and an influent receiving inlet anaerobic reactor.
View Article and Find Full Text PDFDewatered sludges from twenty-two sewage treatment facilities were characterized to develop the quality control indices in India. This study used fertilizer index (FI) and clean index (CI) as a tool for categorizing sludge utilization into different classes (A, B, C and limited use classes LU-1, LU-2, LU-3) by their fertilizing potential, toxicity level, pathogen presence, and vector attraction reduction criteria. The findings revealed that total P (as PO), total N, and K (as KO) in the sludge samples ranged from 0.
View Article and Find Full Text PDFAgro-waste having lignocellulosic biomass is considered most effective (heating value 16 MJ/kg) for energy production through anaerobic digestion (AD). However, recalcitrant lignocellulosic fraction in agro-waste obstructs its biotransformation and is a rate-limiting step of the process. This study investigated the effects of hydrothermal and thermal-alkaline pretreatment on anaerobic co-digestion of wheat straw (WS).
View Article and Find Full Text PDFSewage sludge is rich source of carbon, nutrients, and trace elements and can be subjected to proper treatment before disposal to fulfill government legislation and protect receiving environments. Anaerobic digestion (AD) is a well-adopted technology for stabilizing sewage sludge and recovering energy-rich biogas and nutrient-rich digestate. However, a slow hydrolysis rate limits the biodegradability of sludge.
View Article and Find Full Text PDFSuccinic acid (SA) is used as a commodity chemical and as a precursor in chemical industry to produce other derivatives such as 1,4-butaneidol, tetrahydrofuran, fumaric acid, and bio-polyesters. The production of bio-based SA from renewable feedstocks has always been in the limelight owing to the advantages of renewability, abundance and reducing climate change by CO capture. Considering this, the current review focuses on various 2G feedstocks such as lignocellulosic biomass, crude glycerol, and food waste for cost-effective SA production.
View Article and Find Full Text PDFEnergy sustainability is one of the critical parameters to be studied for the successful application of pretreatment processes. This study critically analyzes the energy efficiency of different energy-demanding sludge pretreatment techniques. Conventional thermal pretreatment of sludge (∼5% total solids, TS) produced 244 mL CH/gTS, which could result in a positive energy balance of 2.
View Article and Find Full Text PDFIn this study, four batch assays were performed to ensure the synergic effects of co-digestion and find out the best inoculums to substrate ratio (ISR), carbon to nitrogen ratio (C:N), and total solid (TS) percentage in sequence. The co-digestion of three feedstocks had a 20% higher biogas yield (416 mL/gVS added) than mono-digestion with 21% volatile solids (VS) degradation. The ISR of 2 leads to the highest biogas yield (431 mL/gVS added) and VS removal (30.
View Article and Find Full Text PDFGeneration of excess sludge in large quantities from wastewater treatment plant face huge problem in terms of handling and management, whereas it possess higher organic and inorganic constituents and thus it can be used as a feedstock for the generation of biofuel with proper disintegration techniques.In this regard, an effort has been made in this study to combine thermo-chemo-disperser pretreatment for the disintegration of paper mill waste activated sludge for the production of biohydrogen in an energy efficient way. These combinations of thermo-chemo-disperser (TCD) tend to be effective in disintegration and possess 24.
View Article and Find Full Text PDFThermal-chemical pre-treatment has proven to facilitate the solubilization of organics and improvement in biogas generation from the organic fraction of municipal solid waste (OFMSW). However, the production of recalcitrant is inevitable when OFMSW is pretreated at high temperatures and alkali dosage. This study develops a strategy to use Fe to reduce the formation of recalcitrant compounds, i.
View Article and Find Full Text PDFWorldwide demand for antibiotics and pharmaceutical products is continuously increasing for the control of disease and improvement of human health. Poor management and partial metabolism of these compounds result in the pollution of aquatic systems, leading to hazardous effects on flora, fauna, and ecosystems. In the past decade, the importance of microalgae in micropollutant removal has been widely reported.
View Article and Find Full Text PDFAnaerobic digestion (AD) is the most comprehended process to stabilise the waste biomass efficiently and to obtain bioenergy. The AD starts with the hydrolysis process, where the major liability is the action of inhibitors during the hydrolysis process. The biomass pretreatment preceding anaerobic digestion is obligatory to improve feedstock biodegradability for enhanced biogas generation.
View Article and Find Full Text PDFIncreasing energy demands and environmental issues have stressed the importance of sustainable methods of energy production. Anaerobic digestion (AD) of the biodegradable waste, i.e.
View Article and Find Full Text PDFInt J Biol Macromol
December 2021
Polyhydroxyalkanoates (PHA) are natural polyesters synthesized by microbes which consume excess amount of carbon and less amount of nutrients. It is biodegradable in nature, and it synthesized from renewable resources. It is considered as a future polymer, which act as an attractive replacement to petrochemical based polymers.
View Article and Find Full Text PDFHigh-temperature thermal pretreatment alone or in conjugation with chemical pretreatment (highly acidic or alkaline) produced recalcitrant compounds, which inhibits the anaerobic digestion (AD) process performance. This study aims to develop a strategy to use carbon-based conductive materials to mitigate the recalcitrant toxicity and enhance the methane generation in the downstream AD. The formation of recalcitrant compounds, mainly the furan derivatives, i.
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