Herein, we report the nonlinear optical (NLO) refraction and absorption features of azo dye namely, methyl orange (MO) dissolved in ethanol, methanol, acetone, 1-propanol, DMF and DMSO. The UV-Visible absorption study reveals that the maximum absorption spectrum of MO dye appeared towards longer wavelength by increasing the solvent polarizability is the result of red shift or bathochromic shift. The Z-scan method is utilized to measure the third-order NLO features of MO dye in different polar solvents.
View Article and Find Full Text PDFThis study emphasis the solvent effect on third-order nonlinear optical (NLO) features of methyl red (MR) dye dissolved in polar solvents including ethanol, methanol, acetone, 1-propanol, DMF and DMSO using low power diode laser. Z-scan technique operating at 405 nm wavelength, is used to estimate the third-order NLO features of MR dye in various solvents. The dye discloses self-defocusing nonlinear index of refraction (n), which is determined to be the order of 10 cm/W.
View Article and Find Full Text PDFSolvent environment on third-order nonlinear optical (TNLO) features of triarylmethane dye namely, basic blue 7 in different solvents is reported herein using 650 nm diode laser with continuous wave mode. The basic blue 7 dye is dissolved in different solvent media including ethanol, methanol, dimethyl formamide (DMF) and dimethyl sulfoxide (DMSO). The influence of solvent characteristics such as solvent polarizability and dipole moment on solute molecule is discussed.
View Article and Find Full Text PDFOrganic dyes have shown a remarkable nonlinear optical (NLO) characteristics under low power laser regime because of chemical stability, large nonlinearity and high susceptibility. With this view in mind, herein we report the third-order NLO features of lissamine green dye using 5 mW power laser with operating wavelength of 650 nm. The lissamine green dye is dissolved into various polar solvents such as ethanol, methanol, acetone and DMSO.
View Article and Find Full Text PDFIn new research growth long after glow material is a potential candidate due to its physical properties, chemical stability and wide application in modern solid-state lightning (LED), display devices, dosimetry and sensors. A cerium doped strontium aluminate phosphor (SrAlO:Ce) was synthesized by conventional solid-state reaction method. The crystal structure and morphology of phosphors, while doping rare earth metal and lithium metal ion was investigated by using X-ray diffraction, Raman spectroscopy and field emission scanning electron microscopy.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
October 2013
An efficient amino acid family nonlinear optical single crystal L-phenylalanine-benzoic acid (LPB) was conveniently grown by slow evaporation technique at room temperature. The crystal system and the lattice parameters were analyzed by single crystal X-ray diffraction studies. The grown crystal has excellent transmission in the entire visible region and its lower cut-off wavelength was found to be 248 nm.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
September 2012
Single crystals of novel organic nonlinear optical material, L-phenylalaninium maleate (LPM) having dimensions up to 10 × 6 × 6 mm(3) were grown by slow evaporation solution growth technique at room temperature. The grown crystals were confirmed by single crystal X-ray diffraction studies and the various functional groups were identified by FT-IR spectroscopic analysis. The optical properties were studied by optical absorption, second harmonic generation (SHG), photoconductivity and photoluminescence (PL) studies and reported for the first time.
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