Nonlinear absorption of metal-halide perovskite nanocrystals (NCs) makes them an ideal candidate for applications which require multiphoton-excited photoluminescence. By doping perovskite NCs with lanthanides, their emission can be extended into the near-infrared (NIR) spectral region. We demonstrate how the combination of Yb doping and bandgap engineering of cesium lead halide perovskite NCs performed by anion exchange (from Cl to Br) leads to efficient and tunable emitters that operate under two-photon excitation in the NIR spectral region.
View Article and Find Full Text PDFHorses were domesticated later than other farm animals. Horse breeds have been selectively developed by humans to satisfy different needs and purposes. The factory and indigenous breeds are of particular interest, having been bred in purity for many centuries without the addition of foreign blood.
View Article and Find Full Text PDFHere we report on the development and investigation of a novel multiplex assay model based on polymer microspheres (PMS) encoded with ternary AIS/ZnS quantum dots (QDs). The system was prepared via layer-by-layer deposition technique. Our studies of Förster resonance energy transfer (FRET) between the QD-encoded microspheres and two different cyanine dyes have demonstrated that the QD photoluminescence (PL) quenching steadily increases with a decrease in the QD-dye distance.
View Article and Find Full Text PDFWe report on the first, to the best of our knowledge, in-band pumped , codoped waveguide (WG) laser. A depressed-index surface channel WG (type III) with a 50 µm half-ring cladding is fabricated in a 5 at. % , 0.
View Article and Find Full Text PDFThermal decomposition of 1,3,5-triazines with azido, trinitroethyl, and nitramino groups, the three important energetic functionalities, has been studied with a range of thermal analysis tools. The involved compounds melt under heating with the following mass loss and heat and gas release in the course of thermal decomposition. Model-fitting kinetic analysis resulted in formal reaction schemes with two general stages.
View Article and Find Full Text PDFSurface channel waveguides (WGs) based on a half-ring (40-60-µm-diameter) depressed-index cladding (type III) geometry are fabricated in monoclinic Tm:MgWO by femtosecond (fs) laser writing at a repetition rate of 1 kHz. The WGs are characterized by confocal laser microscopy and -Raman spectroscopy. A Tm:MgWO WG laser generates 320 mW at ∼2.
View Article and Find Full Text PDFDepressed-index buried and surface channel waveguides (type III) are produced in a bulk 3.5 at.% Tm:CALGO crystal by femtosecond direct-laser-writing at kHz repetition rate.
View Article and Find Full Text PDFWe report the generation of mid-infrared (~2 µm) high repetition rate (MHz) sub-100 ns pulses in buried thulium-doped monoclinic double tungstate crystalline waveguide lasers using two-dimensional saturable absorber materials, graphene and MoS. The waveguide (propagation losses of ~1 dB/cm) was micro-fabricated by means of ultrafast femtosecond laser writing. In the continuous-wave regime, the waveguide laser generated 247 mW at 1849.
View Article and Find Full Text PDFWe report on efficient laser operation of the first holmium monoclinic double tungstate waveguide laser fabricated by femtosecond direct laser writing. A depressed-index buried channel waveguide with a 60 μm diameter circular cladding was inscribed in 5 at.% Ho:KGd(WO).
View Article and Find Full Text PDFWe report on the first erbium (Er) doped double tungstate waveguide laser. As a gain material, we studied a monoclinic Er:KLu(WO) crystal. A depressed-index buried channel waveguide formed by a 60 µm-diameter circular cladding was fabricated by 3D femtosecond direct laser writing.
View Article and Find Full Text PDFTo evaluate the accuracy of estimated continuous cardiac output (esCCO) based on pulse wave transit time in comparison with cardiac output (CO) assessed by transpulmonary thermodilution (TPTD) in off-pump coronary artery bypass grafting (OPCAB). We calibrated the esCCO system with non-invasive (Part 1) and invasive (Part 2) blood pressure and compared with TPTD measurements. We performed parallel measurements of CO with both techniques and assessed the accuracy and precision of individual CO values and agreement of trends of changes perioperatively (Part 1) and postoperatively (Part 2).
View Article and Find Full Text PDFThe optical properties of three-dimensional ordered superstructures formed on glass substrates by self-assembly of cadmium selenide or lead sulfide nanocrystals (NCs) are investigated and compared to the optical properties of the initial NC colloidal solutions. The formation of the superstructures is strongly correlated to the presence of oleic acid molecules on the surface of the NCs. It is found that the absorption band of the NCs in the superstructures is broadened and shifted to shorter wavelengths in comparison with the absorption band of the NCs in solution.
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