Molecular Mass Affects the Phase Separation of Aqueous PEG-Polycation Block Copolymer.

Mechanisms of the phase separation and remixing of cationic PEG-containing block copolymers have been investigated in aqueous lithium triflate solutions. The polycation was poly(vinylbenzyl trimethylammonium triflate). We have previously reported on one such block copolymer, which upon cooling of a hot clear solution first underwent phase separation into a turbid colloid and, later, partially cleared again with further cooling.