Anisotropic membrane with high proton conductivity sustaining upon dehydration.

In fuel cells and electrolyzers, suboptimal proton conductivity and its dramatic drop at low humidity remain major drawbacks in proton exchange membranes (PEMs), including current benchmark Nafion. Sustained through-plane (TP) alignment of nanochannels was proposed as a remedy but proved challenging. We report an anisotropic composite PEM, mimicking the water-conductive composite structure of bamboo that meets this challenge.

Ion Coupling, Bonding, and Transfer in Narrow Carbon Nanotubes.

Narrow carbon nanotubes (nCNT) are unique mimics of biological channels with water-ion selectivity attractive for applications such as water purification and osmotic energy harvesting, yet their understanding is still incomplete. Here, an ab initio computation is employed to develop the full picture of ion transfer in nCNT including specificity and coupling between ions. The thermodynamic costs of ion transfer are computed for single ions and ion pairs and used to evaluate different local coupling scenarios including strong (pairing) and weak (free-ion) coupling as well as "electroneutrality breakdown" (EB), possible for cations only due to their chemisorption-like interaction with nCNT.

Pseudo-bottle-brush decorated thin-film composite desalination membranes with ultrahigh mineral scale resistance.

High water recovery is crucial to inland desalination but is impeded by mineral scaling of the membrane. This work presents a two-step modification approach for grafting high-density zwitterionic pseudo-bottle-brushes to polyamide reverse osmosis membranes to prevent scaling during high-recovery desalination of brackish water. Increasing brush density, induced by increasing reaction time, correlated with reduced scaling.

Dynamics of underwater microparticle adhesion to soft hydrated surfaces: Modeling and analysis by time-dependent AFM force spectroscopy.

Hypothesis: Understanding the attachment and detachment of microparticles and living cells to surfaces is crucial for developing antifouling strategies. Hydrogel coatings have shown promise in reducing fouling and particle adhesion due to their softness and high water content, yet the mechanisms involved are dynamic and complex, and relevant parameters are not easily accessible. AFM-based force spectroscopy (FS) experiments with colloidal probe particles is a direct way of evaluating adhesive and mechanical relaxational dynamics, yet their interpretation and modeling has been challenging.

Dielectric exclusion, an éminence grise.

Dielectric exclusion has long been well-established as the key mechanism in membrane desalination, critical for delivering the required levels of salt rejection, also playing important role in electro-membrane processes, nanofluidics, and biomimetics. Unfortunately, its elusive nature and many features, such as dependence on the pore size, membrane hydration, and ion size and charge, make it deceivingly similar to the other ion exclusions mechanisms, steric and Donnan, which has led to much controversy and misconceptions. Starting from the Born model and the concept of self-energy, the present paper reviews and highlights the physical basis of dielectric exclusion, its main features and the ways it may be looked at.

Polystyrene Sulfonate Particles as Building Blocks for Nanofiltration Membranes.

Today the standard treatment for wastewater is secondary treatment. This procedure cannot remove salinity or some organic micropollutants from water. In the future, a tertiary cleaning step may be required.

Ambipolar blend-based organic electrochemical transistors and inverters.

CMOS-like circuits in bioelectronics translate biological to electronic signals using organic electrochemical transistors (OECTs) based on organic mixed ionic-electronic conductors (OMIECs). Ambipolar OECTs can reduce the complexity of circuit fabrication, and in bioelectronics have the major advantage of detecting both cations and anions in one device, which further expands the prospects for diagnosis and sensing. Ambipolar OMIECs however, are scarce, limited by intricate materials design and complex synthesis.

Putting together the puzzle of ion transfer in single-digit carbon nanotubes: mean-field meets .

Nature employs channel proteins to selectively pass water across cell membranes, which inspires the search for bio-mimetic analogues. Carbon nanotube porins (CNTPs) are intriguing mimics of water channels, yet ion transport in CNTPs still poses questions. As an alternative to continuum models, here we present a molecular mean-field model that transparently describes ion coupling, yet unlike continuum models, computes all required thermodynamic quantities for the KCl salt and H and OH ions present in water.

Elucidating the Effect of Aliphatic Molecular Plugs on Ion-Rejecting Properties of Polyamide Membranes.

Polyamide RO membranes are widely used for seawater desalination owing to their high salt rejection and water permeability; however, improved selectivity-permeability trade-off is still desired. "Molecular plugs," small molecules immobilized within the polyamide structure, offer an attractive approach; however, their overall effect on polyamide physicochemical properties poses many questions. Here, we analyze the effect of decylamine, a promising plug, and a few charged and uncharged mimics on polyamide films using several in situ techniques.

Electrospun Ion-Conducting Composite Membrane with Buckling-Induced Anisotropic Through-Plane Conductivity.

Fuel cell (FC) is an attractive green alternative for today's fuel combustion systems. In common FCs, a polymer electrolyte membrane selectively conducts protons but blocks the passage of electrons and fuel. Nafion, the current benchmark membrane material, has a superior conductivity owing to unique morphology comprising randomly oriented elongated ionic nanochannels within its Teflon-like matrix.

Water and Ion Transfer to Narrow Carbon Nanotubes: Roles of Exterior and Interior.

Narrow carbon nanotubes (CNTs) desalinate water, mimicking water channels of biological membranes, yet the physics behind selectivity, especially the effect of the membrane embedding CNTs on water and ion transfer, is still unclear. Here, we report analysis of the energies involved in transfer of water and K and Cl ions from solution to empty and water-filled 0.68 nm CNTs for different dielectric constants (ϵ) of the surrounding matrix.

Spatial pattern and surface-specificity of particle and microorganism deposition and attachment: Modeling, analytic solution and experimental test.

Hypothesis: Understanding microparticle and living cell deposition and attachment on surfaces from a flow is a long-standing surface-science problem, pivotal to developing antifouling strategies. Recent studies indicate a complex non-conservative and surface-specific nature of adhesion and mechanical contact forces that determine attachment kinetics. This requires new models and kinetic data, however, observed deposition rates (e.

Ion partitioning and permeation in charged low-T* membranes.

Understanding ion transport in membrane materials is key to engineering and development of desalination and water purification technologies as well as electro-membrane applications. To date, modeling of ion transport has mainly relied on mean-field approaches, originally intended for weak inter-ionic interactions, i.e.

Effect of the membrane exclusion mechanism on phosphate scaling during synthetic effluent desalination.

Calcium phosphate scaling is one of the main limitations in effluent desalination using membranes. This may be overcome by tailoring membranes with lower rejection of the scalant ions. In this study, we systematically examined the use of negatively and positively charged membranes, rejecting ions mainly based on Donnan exclusion, as a low-scaling alternative to dielectric-exclusion-dominated polyamide NF membranes for effluent desalination.

In Situ Modification of Reverse Osmosis Membrane Elements for Enhanced Removal of Multiple Micropollutants.

Reverse osmosis (RO) membranes are widely used for desalination and water treatment. However, they insufficiently reject some small uncharged micropollutants, such as certain endocrine-disrupting, pharmaceutically active compounds and boric acid, increasingly present in water sources and wastewater. This study examines the feasibility of improving rejection of multiple micropollutants in commercial low-pressure RO membrane elements using concentration polarization- and surfactant-enhanced surface polymerization.

Degradation of Polyamide Membranes Exposed to Chlorine: An Impedance Spectroscopy Study.

Polyamide is the key material in modern membrane desalination; however, its well-known and incompletely understood drawback is its low tolerance to chlorine, the most efficient in-line disinfectant. Here we report a first investigation of the mechanism and kinetics of chlorine attack using electrochemical impedance spectroscopy (EIS) that directly probes changes in ion permeation upon chlorination at different pH values, focusing on its early stages and low chlorine concentrations (15-197 ppm). EIS results partly conform to an established two-stage mechanism that proceeds as N-chlorination followed by either C-chlorination in acidic conditions or amide bond scission in alkaline conditions.

Modeling QCM-D Response to Deposition and Attachment of Microparticles and Living Cells.

Quartz crystal microbalance with dissipation monitoring (QCM-D) is a powerful tool for studying adhesion, yet its use for analyzing the deposition of microparticles and living cells on surfaces has been hampered by difficulties in interpretation. Here we report a new quantitative model of QCM-D response, presented as an equivalent acoustic impedance circuit. As an essential feature, the particle interaction with surrounding fluid is modeled by relations for a freely oscillating rotating and translating sphere in an unbounded fluid, which is a valid approximation for microparticles.

Selectivity and polarization in water channel membranes: lessons learned from polymeric membranes and CNTs.

Water channels are employed by nature to move pure water across cell membranes while selectively rejecting salts. At present, synthetic channels successfully mimic water permeation, yet even the best channels, such as carbon nanotubes (CNTs) and graphene oxide stacks, still fall short of the selectivity target. The present paper analyzes factors that may help to enhance and control salt rejection based on the lessons learned from conventional membranes and CNTs.

Facile Modification of Reverse Osmosis Membranes by Surfactant-Assisted Acrylate Grafting for Enhanced Selectivity.

The top polyamide layer of composite reverse osmosis (RO) membranes has a fascinatingly complex structure, yet nanoscale nonuniformities inherently present in polyamide layer may reduce selectivity, e.g., for boron rejection.

When Salt-Rejecting Polymers Meet Protons: An Electrochemical Impedance Spectroscopy Investigation.

Polymeric membranes are widely used for salt removal, but mechanism of ion permeation is still insufficiently understood. Here we analyze ion transport in polymers relevant to desalination, dense aromatic polyamide Nomex and cellulose acetate (CA), using impedance spectroscopy, focusing on the effects of the salt type, concentration and pH. The results highlight the role of proton uptake in ion permeation.

Molecular Dynamics Investigation of Ion Sorption and Permeation in Desalination Membranes.

With the purpose of gaining insights into the mechanisms of ion uptake and permeation in desalination membranes, MD investigation of a model polyamide membrane was carried out. A relatively large membrane (45K atoms) was assembled, which closely matched real desalination membrane in terms of chemistry and water permeability. Simulations demonstrate that the mechanism of ion uptake distinctly differs from mean-field approaches assuming a smeared excluding Donnan potential.