Insights into emulsion synthesis of self-assembled suprastructures formed by Janus silica particles with -NH/-SH surface groups.

Spherical particles with tunable anisotropic structures enabled by multiple surface functionalities have garnered interest for their potential applications in adsorption technologies. The presence of diverse functional groups in the surface layer, exhibiting varying acidity and hydrophilicity, can lead to unique characteristics in terms of surface structure and behaviour. In this study, the particles were synthesised using a two-step approach involving surface functionalisation of previously synthesised SiO Stöber particles.

Diamine Groups on the Surface of Silica Particles as Complex-Forming Linkers for Metal Cations.

Novel spherically shaped organosilica materials with (propyl)ethylenediamine groups were obtained via a modified one-pot Stöber co-condensation method. The porosity of these materials was tuned with the controlled addition of three silica monomers acting as structuring agents (tetraethoxysilane and bridged silanes with ethylene and phenylene bridges). The morphologies and structures of the synthesized materials were studied by SEM, DRIFT spectroscopy, CHNS elemental analysis, low-temperature nitrogen adsorption-desorption, and electrokinetic potential measurements.

Diverse Pathway to Obtain Antibacterial and Antifungal Agents Based on Silica Particles Functionalized by Amino and Phenyl Groups with Cu(II) Ion Complexes.

Production of environmentally friendly multitasking materials is among the urgent challenges of chemistry and ecotechnology. The current research paper describes the synthesis of amino-/silica and amino-/phenyl-/silica particles using a one-pot sol-gel technique. CHNS analysis and titration demonstrated a high content of functional groups, while scanning electron microscopy revealed their spherical form and ∼200 nm in size.

Tailoring bifunctional hybrid organic-inorganic nanoadsorbents by the choice of functional layer composition probed by adsorption of Cu ions.

Spherical silica particles with bifunctional (≡Si(CH)NH/≡SiCH, ≡Si(CH)NH/≡Si(CH)(CF)CF) surface layers were produced by a one-step approach using a modified Stöber method in three-component alkoxysilane systems, resulting in greatly increased contents of functional components. The content of functional groups and thermal stability of the surface layers were analyzed by diffuse reflectance infrared Fourier transform (DRIFT) spectroscopy, and C and Si solid-state NMR spectroscopy revealing their composition and organization. The fine chemical structure of the surface in the produced hybrid adsorbent particles and the ligand distribution were further investigated by electron paramagnetic resonance (EPR) and electron spectroscopy of diffuse reflectance (ESDR) spectroscopy using Cu ion coordination as a probe.