Environ Technol
November 2024
Dexamethasone (DXM) was the first drug used to treat COVID-19, only a small part is metabolized and has been identified in wastewater and surface water, conventional treatments do not remove these compounds, therefore new technologies must be developed. A commercially injectable solution containing dexamethasone (DXM) was removed by heterogeneous sono/photo-Fenton (SPF) process using clinoptilolite zeolite (CZ) modified with Fe (CZ-Fe) by an electrodeposition method. The effect of initial concentration (1.
View Article and Find Full Text PDFJ Hazard Mater
September 2024
Microbially induced carbonate precipitation (MICP) immobilizes toxic metals and reduces their bioavailability in aqueous systems. However, its application in the treatment of acid mine drainage (AMD) is poorly understood. In this study, the genomes of Sporosarcina sp.
View Article and Find Full Text PDFJ Environ Manage
February 2024
The textile industry is an important economic sector; however, its wastewater generates a great impact on the environment. A heterogeneous solar Fenton (HSF) process was evaluated for denim wastewater treatment. The catalyst was obtained through ultrasonic modification of recycled polyethylene terephthalate (PET) with Fe nanoparticles (PET/NPs- FeO).
View Article and Find Full Text PDFBiological treatments have become insufficient to treat municipal wastewater with greater toxicity and excess nitrogen and phosphate species, thus affecting the organisms that consume the water. In this work, a process was implemented for the removal of nutrients through three stages: stage A, complete aeration (24 h, 43 months); stage B, decreased aeration (12 h, 17 months); and stage C, decreased aeration with biocalcium (12 h, 19 months). The addition of biocalcium from eggshell promoted the formation of flocks, which resulted in the removal of nitrites (61 %), nitrates (84 %), total nitrogen (57 %), total phosphorus (8.
View Article and Find Full Text PDFRainwater Electro-Galvanic Alkalization (EGA) was performed using copper and magnesium (1:1) electrode. Efficiently removal of pollutants without external energy consumption was carried out, in addition essential ions were dosed for alkalization of rainwater. The optimal system conditions were obtained using response surface methodology (RSM) by considering the following operating variables: flow rate and concentration of the supporting electrolyte (NaCl and CaCl).
View Article and Find Full Text PDFHS is a gaseous compound that contributes to air pollution. In this work, the electrochemical oxidation treatment of gaseous streams polluted with HS is evaluated using a jet mixer and electrochemical cell device, in which the performance of electrolytic and electro-Fenton assisted absorption processes are compared. Results demonstrate the feasibility of both processes to remove HS, reaching coulombic efficiencies of nearly 100% in the electrolytic assisted absorption, and 70-80% in the electro-Fenton assisted absorption.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
September 2022
This review summarizes research data on the pharmaceutical drugs used to treat the novel SARS-CoV-2 virus, their characteristics, environmental impacts, and the advanced oxidation processes (AOP) applied to remove them. A literature survey was conducted using the electronic databases Science Direct, Scopus, Taylor & Francis, Google Scholar, PubMed, and Springer. This complete research includes and discusses relevant studies that involve the introduction, pharmaceutical drugs used in the SARS-CoV-2 pandemic: chemical characteristics and environmental impact, advanced oxidation process (AOP), future trends and discussion, and conclusions.
View Article and Find Full Text PDFAcid mine drainage was evaluated using a galvanic (GV) electrochemical system, Al-Cu (anode/cathode), based on a 3 factorial design. The factors analyzed were anodic area/volume ratios (A/V) of 0.037, 0.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
June 2022
Drinking water contaminated with As and [Formula: see text] is increasingly prevalent worldwide. Their coexistence can have negative effects due to antagonistic or synergistic mechanisms, ranging from cosmetic problems, such as skin lesions and teeth staining, to more severe abnormalities, such as cancer and neurotoxicity. Available technologies for concurrent removal include electrocoagulation ~ adsorption > membranes > chemical coagulation > , and among others, all of which have limitations despite their advantages.
View Article and Find Full Text PDFThe goal of this research is to apply an electrocoagulation process in continuous flow for the defluoridation of drinking water. Two sampling sites were studied, Temascalcingo (T), Mexico state and Jerecuaro (J), Guanajuato, with fluoride (F) concentrations above the norms (2.3 mg L and 4.
View Article and Find Full Text PDFOrganochlorine pesticides have generated public concern worldwide because of their toxicity to human health and the environment, even at low concentrations, and their persistence, being mostly nonbiodegradable. The use of 2,4-dichlorophenoxyacetic acid (2,4-D) has increased in recent decades, causing severe water contamination. Several treatments have been developed to degrade 2,4-D.
View Article and Find Full Text PDFJ Environ Sci Health A Tox Hazard Subst Environ Eng
June 2021
The physicochemical treatment (PT) of food industry wastewater was investigated. In the first stage, calcium magnesium acetate (CaMgAc) was synthesized using eggshell (biocalcium), magnesium oxide and acetic acid in a 1:1:1 stoichiometric ratio. In the synthesis process, the thermodynamic parameters (ΔH, ΔS and ΔG) indicated that the reaction was endothermic and spontaneous.
View Article and Find Full Text PDFJ Environ Sci Health A Tox Hazard Subst Environ Eng
March 2021
In the present study, the electrocoagulation (EC) performance of a Mg-Mg system was applied for the industrial wastewater treatment, from an industrial park that covers different activities such as: food, automotive, pharmaceutical, chemistry and cosmetics, after primary clarification. The effects of major operating parameters such as pH, reaction time, and current density were investigated for chemical oxygen demand (COD), color, and turbidity removal efficiency. The batch system was found convenient, achieving 63.
View Article and Find Full Text PDFThis work focuses on the development of electro-absorption and photoelectro-absorption technologies to treat gases produced by a synthetic waste containing the highly volatile perchloroethylene (PCE). To do this, a packed absorption column coupled with a UV lamp and an undivided electrooxidation cell was used. Firstly, it was confirmed that the absorption in a packed column is a viable method to achieve retention of PCE into an absorbent-electrolyte liquid.
View Article and Find Full Text PDFIn this study, acetaminophen (ACT) in aqueous solution was treated with electrooxidation and photo-electrooxidation processes (PEO). An electrochemical cell was used for the treatment of different concentrations of ACT (10, 50 and 80 mg L). A 2 factorial design was proposed, and the variables studied were current intensity 0.
View Article and Find Full Text PDFJ Environ Sci Health A Tox Hazard Subst Environ Eng
August 2019
Wastewater from soft drink manufacturing, having a high organic load (chemical oxygen demand (COD) = 4,500 mg L) and high alkalinity (2,653.7 mg L CaCO; pH 12), was pretreated with a calcium-modified zeolite to reduce the alkalinity and improve the electrooxidation of organic matter. The natural zeolite clinoptilolite was modified in various ways with Ca(OH) and CaCl.
View Article and Find Full Text PDFJ Environ Sci Health A Tox Hazard Subst Environ Eng
June 2019
The physicochemical treatment (PT) of slaughterhouse wastewater (SWW) was investigated. In the first stage, calcium acetate (Ca(Ac)) was synthesized in five different ways: (1) acetic acid (HAc) and chicken eggshell (CaAc1), (2) lime (CaAc2), (3) a 1:1 eggshell and lime mixture (CaAc3), (4) a 1:2 eggshell and lime mixture (CaAc4), and (5) calcium oxide via the calcination of eggshell (CaAc5). The synthesized Ca(Ac) samples were characterized by IR, SEM, XRD, and EDS.
View Article and Find Full Text PDFAnthropogenic activities can deteriorate the quality of groundwater destined for human use and consumption due to the fact that human activities cause changes in groundwater chemistry. The changes are induced by chemical species coming from industrial waste, which interacts with rocks and minerals. These trigger agents (phosphorus and nitrogen nutrients) which can incorporate trace elements (As, Fe, Mn, Pb, Cd, Ni, Zn).
View Article and Find Full Text PDFIndigo blue dye is mainly used in dyeing of denim clothes and its presence in water bodies could have adverse effects on the aquatic system; for this reason, the objective of this study was to promote the removal of indigo blue dye from aqueous solutions by iron and copper electrochemically modified clay and activated carbon and the saturated materials were regenerated by a Fenton-like process. Montmorillonite clay was modified at pH 2 and 7; activated carbon at pH 2 and pH of the system. The elemental X-ray dispersive spectroscopy analysis showed that the optimum pH for modification of montmorillonite with iron and copper was 7 and for activated carbon was 2.
View Article and Find Full Text PDFCuitzeo Lake is one of the largest and most important lakes in Mexico. It receives different types of pollutants through its main tributary, the Grande River of Morelia. The aim of this work was to determine if high concentrations of iron, zinc, and arsenic are present in sediments in an area near the river mouth to the lake, as well as to estimate the partitioning of these metals using a sequential extraction procedure in order to obtain information of their potential bioavailability.
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