One-component, switchable ionic liquids derived from siloxylated amines.

A new class of one-component, thermally reversible, neutral to ionic liquid solvents derived from siloxylated amines is presented and characterized.

[BMIM][PF(6)] promotes the synthesis of halohydrin esters from diols using potassium halides.

Haloesterification of diverse diols with various carboxylic acids was achieved using potassium halides (KX) as the only halide source in ionic liquids. The best yield was obtained in [BMIM][PF(6)] when 1,2-octanediol, palmitic acid and KBr were used. This yield was 85% and the regioisomer with the bromine in primary position was present in a 75:25 ratio.

Using Kamlet-Taft solvent descriptors to explain the reactivity of anionic nucleophiles in ionic liquids.

In this paper, we report the effect of ionic liquids on substitution reactions using a variety of anionic nucleophiles. We have combined new studies of the reactivity of polyatomic anions, acetate, trifuoroacetate, cyanide, and thiocyanide, with our previous studies of the halides in [C4C1py][Tf2N], [C4C1py][TfO], and [C4C1im][Tf2N] (where [C4C1im]+ is 1-butyl-3-methylimidazolium and [C4C1py]+ is 1-butyl-1-methylpyrrolidinium) and compared their reactivities, k2, to the same reactions in the molecular solvents dichloromethane, dimethylsulfoxide, and methanol. The Kamlet-Taft solvent descriptors (alpha, beta, pi) have been used to analyze the rates of the reactions, which were found to have a strong inverse dependency on the alpha value of the solvent.

Aromatic nitrations in ionic liquids: the importance of cation choice.

Aromatic substrates can be nitrated in high yields and with efficient use of the nitrating agent in ionic liquids, although a suitably inert ionic liquid cation must be used.