PAMAM dendrimers as anchors for the preparation of electrocatalytically active ultrathin metallic films.

This paper describes the formation of catalytically active thin films of Pt, Pt/Au, and Pt/Ru on gold substrates stabilized by amine-terminated polyamidoamine (PAMAM) dendrimers. A monolayer of dendrimer is initially self-assembled on the gold substrate, which serves as a template for the growth of catalytically active thin films. As dendrimers contain tens to hundreds of functional groups at the periphery, the aggregate strength of the multidentate interactions with the gold substrate leads to the formation of robust films.