Purification of Waste-Generated Biogas Mixtures Using Covalent Organic Framework's High CO Selectivity.

Development of crystalline porous materials for selective CO adsorption and storage is in high demand to boost the carbon capture and storage (CCS) technology. In this regard, we have developed a β-keto enamine-based covalent organic framework () via the Schiff base polycondensation technique. The as-synthesized exhibited excellent thermal and chemical stability along with a very high surface area (1258 m g) and a high CO adsorption capacity (3.

Modulating cultivation regimes of Messastrum gracile SVMIICT7 for biomass productivity integrated with resource recovery via hydrothermal liquefaction.

The present study was designed to assess Messastrum gracile SVMIICT7 potential in treating dairy wastewater (autoclaved (ADWW) and raw (DWW)) with relation to nutrient removal, in-vivo Chl-a-based biomass, and bio-oil synthesis. Chlorophyll a fluorescence kinetics revealed improved photochemical efficiency (0.639, Fv/Fm) in M.

Biorefinery-centric ethanol and oleochemical production employing Yarrowia lipolytica and Pichia farinosa.

The research examined the capabilities of Yarrowia lipolytica (YL) and Pichia farinosa (PF) in converting sugars to ethanol and oleochemicals. Lipid, ethanol, protein yield and gene-expressions were analysed at different substrate concentrations (3 to 30 g/L) with glucose, food waste, and fermentation-effluent. Optimal results were obtained at 20 g/L using both synthetic carbon with 4.

Hexavalent chromium waste removal bioelectrochemical systems - a life cycle assessment perspective.

Bioelectrochemical systems (BESs) such as microbial fuel cells (MFCs) present numerous benefits for the removal and recovery of heavy metals from industrial and municipal wastewater. This study evaluated the life cycle environmental impact of simultaneous hexavalent chromium (Cr(vi)) removal and bioelectricity generation in a dual chamber MFC. Results indicate a global warming potential (GWP) of -0.

In situ self-induced electrical stimulation to plants: Modulates morphogenesis, photosynthesis and gene expression in Vigna radiata and Cicer arietinum.

Specific stimuli to plants influence intracellular and intercellular communications, activation of ion channels, gene expression, growth and development. The functional role of self-induced in situ electrical stimuli at the rhizosphere of the plant by placing electrode assembly in a defined circuit mode was studied on the growth and development of Vigna radiata and Cicer arietinum plants. Experiments were designed with three-circuit mode configurational variations (CC-P, OC-P and SC-P) and compared with the relative performance of control system (non-potential).

Electrogenic engineered flow through tri-phasic wetland system for azo dye treatment: Microbial dynamics and functional metagenomics.

Electrogenic engineered flow through tri-phasic wetland (EEFW) system based on nature-based ecological principles was studied by integrating successive biological microenvironments. The potential mechanism of the plant root-based microbial community and its functional diversity with the influence of plant-microbe-electrode synergism towards dye degradation was evaluated. The EEFW system was operated at three varied dye loads of 10, 25 and 50 mg L, where the results from the cumulative outlets revealed a maximum dye removal efficiency of 96%, 96.

Light-dependent biohydrogen production: Progress and perspectives.

The fourth industrial revolution anticipates energy to be sustainable, renewable and green. Hydrogen (H) is one of the green forms of energy and is deemed a possible solution to climate change. Light-dependent H production is a promising method derived from nature's most copious resources: solar energy, water and biomass.

Catalytic hydrothermal deoxygenation of sugarcane bagasse for energy dense bio-oil and aqueous fraction acidogenesis for biohydrogen production.

The study focuses on the effective conversion of sugarcane bagasse (SCB) by catalytic deoxygenation using various alkali and metal-based catalysts under N pressure employing water as solvent. The specific influence of catalyst over bio-crude yields (bio-oil and aqueous fraction) including energy recovery ratio was explored. The optimum catalytic condition (Ru/C) resulted in ∼ 70% of bio-crude and 28% of bio-oil with an improved HHV (31.

Dairy wastewater treatment using Monoraphidium sp. KMC4 and its potential as hydrothermal liquefaction feedstock.

Monoraphidium sp. KMC4 was cultivated mixotrophically for simultaneous treatment of dairy wastewater and biomass production. The KMC4 was cultivated with varying chemical oxygen demand concentrations of simulated synthetic dairy wastewater.

Sustainable consideration for traditional textile handloom cluster/village in pollution abatement - A case study.

Decentralized handlooms are being traditionally practised throughout India. Siripuram village known for traditional Pochampally/Ikat work was considered as a case study for detailed investigation towards providing a sustainable solution. Nearly 65% of village population solely depend on weaving and dyeing works as primary occupation based on the household survey and generated wash water of 127 KLD on an average from the dyeing operations.

Sustainable enzymatic treatment of organic waste in a framework of circular economy.

Enzymatic treatment of food and vegetable waste (FVW) is an eco-friendly approach for producing industrially relevant value-added products. This review describes the sources, activities and potential applications of crucial enzymes in FVW valorization. The specific roles of amylase, cellulase, xylanase, ligninase, protease, pectinase, tannase, lipase and zymase enzymes were explained.

Emerging innovations for sustainable production of bioethanol and other mercantile products from circular economy perspective.

Biogenic municipal solid waste (BMSW) and food waste (FW) with high energy density are ready to tap renewable resources for industrial scale ethanol refinery foreseen for establishing bio-based society. Circular economy has occupied limelight in the domain of renewable energy and sustainable chemicals production. The present review highlights the importance of BMSW/FW as newer feed reserves that can cater as parent molecules for an array of high-visibility industrial products along with bioethanol upon implementing a judicious closed-cascade mass-flow mechanism enabling ultimate feed and waste stream valorisation.

Microbial electrolysis cells for the production of biohydrogen in dark fermentation - A review.

To assess biohydrogen for future green energy, this review revisited dark fermentation and microbial electrolysis cells (MECs). Hydrogen evolution rate in mesophilic dark fermentation is as high as 192 m H/m-d, however hydrogen yield is limited. MECs are ideal for improving hydrogen yield from carboxylate accumulated from dark fermentation, whereas hydrogen production rate is too slow in MECs.

Critical factors influence on acidogenesis towards volatile fatty acid, biohydrogen and methane production from the molasses-spent wash.

The study explored the spent wash valorisation into value added biobased products viz. volatile fatty acids (VFAs), biohydrogen (bio-H), methane (CH) and biohythane (bio-H-CNG) based on eight selected parameters employing design of experiment (DOE) approach. Selectively enriched biocatalyst showed marked influence on the production of acidogenic products (bio-H and VFA) while untreated inoculum resulted in higher CH and bio-H-CNG generation.

Magnetite-Bacillus subtilis synergy on the metabolic selection of products in electrofermentation system.

The study examines the role of magnetite (1-150 mg/L) at the interface of Bacillus subtilis-electrode under poised-condition (-0.2 V) for product-formation and catalytic-conduct with the relative-gene-expression encoding lactate dehydrogenase (lctE), pyruvate dehydrogenase (pdhA), acetate kinase (ackA), pyruvate carboxylase (pycA), and NADH dehydrogenase (ndh). The magnetite load of 25 mg/L showed positive influence on acidogenesis resulting in H production of 264.

Synergy of selective buffering, intermittent pH control and bioreactor configuration on acidogenic volatile fatty acid production from food waste.

The production of volatile fatty acids (VFAs) and biohydrogen (bio-H) from food waste (FW) by acidogenic process is one of the promising strategies. The present study was performed to evaluate the role of initial (phase I) and intermittent pH (phase II) control strategies utilising combination of sodium hydroxide (NaOH) and sodium carbonate (NaCO) as buffering/neutralizing agents on VFAs and bio-H production from FW. The study was carried out in two bioreactor configurations (biofilm (UAFBB) and a suspended mode bioreactor (UASB)).

Dual-stage biorefinery to convert spentwash hydrolysate into oleochemicals using Trichosporon cutaneum and Yarrowia lipolytica.

Yeast lipids from low-cost renewable feedstock are valuable resources for oleochemicals thus enabling circular chemistry. Current study focuses on lipid and volatile fatty acid (VFA) production through dual-stage fermentation of spentwash in a biorefinery framework with Trichosporon cutaneum (Tc) and Yarrowia lipolytica (Yl). During cell proliferation phase, Tc and Yl accumulated 2.

Polyhydroxybutyrate production by Chlorella sorokiniana SVMIICT8 under Nutrient-deprived mixotrophy.

Polyhydroxybutyrates (PHBs) are naturally occurring biopolymeric compounds that accumulate in a variety of microorganisms, including microalgae as energy and carbon storage sources. The present study was designed to evaluate nature-based PHB production using microalgae (Chlorella sorokiniana SVMIICT8) in biphasic (growth (GP) and stress phase (SP)) nutritional mode of cultivation. Microalgal PHB accumulation was driven by nutrient constraint, with a maximal production of 29.

Design and evaluation of gas fermentation systems for CO reduction to C2 and C4 fatty acids: Non-genetic metabolic regulation with pressure, pH and reaction time.

Addressing the carbon emissions through microbial mediated fermentation is an emerging interest. Custom designed and fabricated gas fermentation (GF) systems were evaluated to optimize the headspace pressure, pH (6.5, 7.

Micro/nano-plastics occurrence, identification, risk analysis and mitigation: challenges and perspectives.

Micro/nanoplastics (MP/NPs) are emerging global pollutants that garnered enormous attention due to their potential threat to the ecosystem in virtue of their persistence and accumulation. Notably, United Nations Environment Programme (UNEP) yearbook in 2014 proposed MPs as one among ten emergent issues that the Earth is facing today. MP/NPs can be found in most regularly used products (primary microplastics) or formed by the fragmentation of bigger plastics (secondary microplastics) and are inextricably discharged into the environment by terrestrial and land-based sources, particularly runoff.

Mixotrophic cultivation of Monoraphidium sp. In dairy wastewater using Flat-Panel photobioreactor and photosynthetic performance.

Monoraphidium sp. SVMIICT6 was isolated and mixotrophically cultivated in a flat-panel photobioreactor (8 days) to treat synthetic dairy wastewater. COD, nitrates, and phosphates removal efficiencies were 75%, 85%, and 60% respectively.

Duckweed biorefinery - Potential to remediate dairy wastewater in integration with microbial protein production.

The phytoremediation potential of Duckweed in treating dairy wastewater (DWW) was studied, focusing on its utilization as nutritional biomass. The process resulted in good treatment efficiency with removal of organic carbon of 74% (COD), nitrates of 66% and phosphates of 80%. The increase in duckweed fronds with time was observed (doubling time (DT) - 0.

Phycoremediation potential ofTetradesmus sp.SVMIICT4in treating dairy wastewaterusingFlat-Panel photobioreactor.

Tetradesmus sp. SVMIICT4 was isolated and cultivated mixotrophically in a flat-panel photobioreactor (FP-PBR) for concurrent dairy wastewater treatment, carbon fixation, and biomass production. Integrated wastewater treatment showed good COD and nutrients removal efficiency accounting for biomass with an accumulation of carbohydrate (21.

Fungal biorefinery for sustainable resource recovery from waste.

Depletion of natural resources and negative impact of fossil fuels on environment are becoming a global concern. The concept of biorefinery is one of the alternative platforms for the production of biofuels and chemicals. Valorisation of biological resources through complete utilization of waste, reusing secondary products and generating energy to power the process are the key principles of biorefinery.