2D Electrodes From Functionalized Graphene for Rapid Electrochemical Gold Extraction and Reduction From Electronic Waste.

Electronic waste (e-waste) contains substantial quantities of valuable precious metals, particularly gold (Au). However, inefficient metal recovery leads to these precious metals being discarded in landfills, causing significant water and environmental contamination. This study introduces a two-dimensional (2D) electrode with a layered graphene oxide membrane functionalized by chitosan (GO/CS).

Photocatalytic Seawater Splitting by Earth-Abundant Catalysts: Metal-Semiconductor Metamaterials Made of Plasmonic Magnesium Diboride and Transitional Metal Dichalcogenides.

Metal-semiconductor metamaterials hold great promise for photocatalytic water splitting due to their excellent light harvesting in a broad spectral range as well as efficient charge carrier generation and transfer. In the majority of such metamaterials, semiconductors are used to initiate the water splitting reaction, while their metal counterparts are employed to improve light harvesting through plasmonic effects. Here, we describe for the first time an exceptional reversed case of metal-semiconductor photocatalysts in which metals are used to initiate the water splitting reaction and semiconductors are employed to improve light harvesting through the blackbody effect and serve as co-catalysts.

Graphene/chitosan nanoreactors for ultrafast and precise recovery and catalytic conversion of gold from electronic waste.

The extraction of gold (Au) from electronic waste (e-waste) has both environmental impact and inherent value. Improper e-waste disposal poses environmental and health risks, entailing substantial remediation and healthcare costs. Large efforts are applied for the recovery of Au from e-waste using complex processes which include the dissolution of Au, its adsorption in an ionic state and succeeding reduction to metallic Au.

Versatile Method for Preparing Two-Dimensional Metal Dihalides.

Ever since the ground-breaking isolation of graphene, numerous two-dimensional (2D) materials have emerged with 2D metal dihalides gaining significant attention due to their intriguing electrical and magnetic properties. In this study, we introduce an innovative approach anhydrous solvent-induced recrystallization of bulk powders to obtain crystals of metal dihalides (MX, with M = Cu, Ni, Co and X = Br, Cl, I), which can be exfoliated to 2D flakes. We demonstrate the effectiveness of our method using CuBr as an example, which forms large layered crystals.

Highly oriented single-crystalline gold quantum-dot metamaterials as prospective materials for photonics.

Miniaturization of optical devices is a modern trend essential for optoelectronics, optical sensing, optical computing and other branches of science and technology. To satisfy this trend, optical materials with a small footprint are required. Here we show that extremely thin, flat, nanostructured gold films made of highly oriented single-crystalline gold quantum-dots can provide elements of topological photonics in visible light and be used as high-index dielectric materials in the infrared part of the spectra.

Non-Polaritonic Effects in Cavity-Modified Photochemistry.

Strong coupling of molecules to vacuum fields is widely reported to lead to modified chemical properties such as reaction rates. However, some recent attempts to reproduce infrared strong coupling results have not been successful, suggesting that factors other than strong coupling may sometimes be involved. In the first vacuum-modified chemistry experiment, changes to a molecular photoisomerization process in the ultraviolet-visible spectral range are attributed to strong coupling of the molecules to visible light.

Topological Darkness in Optical Heterostructures: Prediction and Confirmation.

Topological darkness is a new phenomenon that guarantees zero reflection/transmission of light from an optical sample and hence provides topologically nontrivial phase singularities. Here we consider topological darkness in an optical heterostructure that consists of an (unknown) layer placed on a composite substrate and suggest an algorithm that can be used to predict and confirm the presence of topological darkness. The algorithm is based on a combination of optical measurements and the Fresnel equations.

Label-free optical biosensing: going beyond the limits.

Label-free optical biosensing holds great promise for a variety of applications in biomedical diagnostics, environmental and food safety, and security. It is already used as a key tool in the investigation of biomolecular binding events and reaction constants in real time and offers further potential additional functionalities and low-cost designs. However, the sensitivity of this technology does not match the routinely used but expensive and slow labelling methods.

"Dead" Exciton Layer and Exciton Anisotropy of Bulk MoS Extracted from Optical Measurements.

Excitons (electron-hole pairs bound by the Coulomb potential) play an important role in optical and electronic properties of layered materials. They can be used to modulate light with high frequencies due to the optical Pauli blocking. The properties of excitons in 2D materials are extremely anisotropic.

Two-Dimensional Covalent Crystals by Chemical Conversion of Thin van der Waals Materials.

Most of the studied two-dimensional (2D) materials have been obtained by exfoliation of van der Waals crystals. Recently, there has been growing interest in fabricating synthetic 2D crystals which have no layered bulk analogues. These efforts have been focused mainly on the surface growth of molecules in high vacuum.

Self-Limiting Growth of Two-Dimensional Palladium between Graphene Oxide Layers.

The ability of different materials to display self-limiting growth has recently attracted an enormous amount of attention because of the importance of nanoscale materials in applications for catalysis, energy conversion, (opto)electronics, and so forth. Here, we show that the electrochemical deposition of palladium (Pd) between graphene oxide (GO) sheets result in the self-limiting growth of 5-nm-thick Pd nanosheets. The self-limiting growth is found to be a consequence of the strong interaction of Pd with the confining GO sheets, which results in the bulk growth of Pd being energetically unfavorable for larger thicknesses.

Giant photoeffect in proton transport through graphene membranes.

Graphene has recently been shown to be permeable to thermal protons , the nuclei of hydrogen atoms, which sparked interest in its use as a proton-conducting membrane in relevant technologies. However, the influence of light on proton permeation remains unknown. Here we report that proton transport through Pt-nanoparticle-decorated graphene can be enhanced strongly by illuminating it with visible light.

Ultra-narrow surface lattice resonances in plasmonic metamaterial arrays for biosensing applications.

When excited over a periodic metamaterial lattice of gold nanoparticles (~ 100nm), localized plasmon resonances (LPR) can be coupled by a diffraction wave propagating along the array plane, which leads to a drastic narrowing of plasmon resonance lineshapes (down to a few nm full-width-at-half-maximum) and the generation of singularities of phase of reflected light. These phenomena look very promising for the improvement of performance of plasmonic biosensors, but conditions of implementation of such diffractively coupled plasmonic resonances, also referred to as plasmonic surface lattice resonances (PSLR), are not always compatible with biosensing arrangement implying the placement of the nanoparticles between a glass substrate and a sample medium (air, water). Here, we consider conditions of excitation and properties of PSLR over arrays of glass substrate-supported single and double Au nanoparticles (~ 100-200nm), arranged in a periodic metamaterial lattice, in direct and Attenuated Total Reflection (ATR) geometries, and assess their sensitivities to variations of refractive index (RI) of the adjacent sample dielectric medium.

Plasmon-induced nanoscale quantised conductance filaments.

Plasmon-induced phenomena have recently attracted considerable attention. At the same time, relatively little research has been conducted on electrochemistry mediated by plasmon excitations. Here we report plasmon-induced formation of nanoscale quantized conductance filaments within metal-insulator-metal heterostructures.

Strong coupling of diffraction coupled plasmons and optical waveguide modes in gold stripe-dielectric nanostructures at telecom wavelengths.

We propose a hybrid plasmonic device consisting of a planar dielectric waveguide covering a gold nanostripe array fabricated on a gold film and investigate its guiding properties at telecom wavelengths. The fundamental modes of a hybrid device and their dependence on the key geometric parameters are studied. A communication length of 250 μm was achieved for both the TM and TE guided modes at telecom wavelengths.

Solid-State Electrolyte-Gated Graphene in Optical Modulators.

The gate-tunable wide-band absorption of graphene makes it suitable for light modulation from terahertz to visible light. The realization of graphene-based modulators, however, faces challenges connected with graphene's low absorption and the high electric fields necessary to change graphene's optical conductivity. Here, a solid-state supercapacitor effect with the high-k dielectric hafnium oxide is demonstrated that allows modulation from the near-infrared to shorter wavelengths close to the visible spectrum with remarkably low voltages (≈3 V).

Super-narrow, extremely high quality collective plasmon resonances at telecom wavelengths and their application in a hybrid graphene-plasmonic modulator.

We present extremely narrow collective plasmon resonances observed in gold nanostripe arrays fabricated on a thin gold film, with the spectral line full width at half-maximum (fwhm) as low as 5 nm and quality factors Q reaching 300, at important fiber-optic telecommunication wavelengths around 1.5 μm. Using these resonances, we demonstrate a hybrid graphene-plasmonic modulator with the modulation depth of 20% in reflection operated by gating of a single layer graphene, the largest measured so far.

Topological darkness in self-assembled plasmonic metamaterials.

Self-assembled plasmonic metamaterials are fabricated from silver nanoparticles covered with a silica shell. These metamaterials demonstrate topological darkness or selective suppression of reflection connected to global properties of the Fresnel coefficients. The optical properties of the studied structures are in good agreement with effective medium theory.

Fluorographene: a two-dimensional counterpart of Teflon.

A stoichiometric derivative of graphene with a fluorine atom attached to each carbon is reported. Raman, optical, structural, micromechanical, and transport studies show that the material is qualitatively different from the known graphene-based nonstoichiometric derivatives. Fluorographene is a high-quality insulator (resistivity >10(12) Ω) with an optical gap of 3 eV.

Surface-enhanced Raman spectroscopy of graphene.

Surface-enhanced Raman scattering (SERS) exploits surface plasmons induced by the incident field in metallic nanostructures to significantly increase the Raman intensity. Graphene provides the ideal prototype two-dimensional (2d) test material to investigate SERS. Its Raman spectrum is well-known, graphene samples are entirely reproducible, height controllable down to the atomic scale, and can be made virtually defect-free.

Enhancement of magneto-optical effects in magnetic nanoparticles near gold-dielectric surfaces.

We report enhanced magneto-optical Kerr rotation in the layer systems of a magnetic granular film coated by uniform gold and dielectric films. The Kerr rotation spectra measured from 1.2 to 5 eV show a peak at about 2.

Plasmonic resonances in optomagnetic metamaterials based on double dot arrays.

We study optical properties of optomagnetic metamaterials produced by regular arrays of double gold dots (nanopillars). Using combined data of spectroscopic ellipsometry, transmission and reflection measurements, we identify localized plasmon resonances of a nanopillar pair and measure their dependences on dot sizes. We formulate the necessary condition at which an effective field theory can be applied to describe optical properties of a composite medium and employ interferometry to measure phase shifts for our samples.