Publications by authors named "Vasiliy N Yudin"
Article Synopsis
- This research introduces the first heterometallic octahedral cluster complexes made from both 5d (tungsten) and 3d (iron) metals.
- The main focus is on a compound called (TBA)[FeWBr], which shows selective reactions at the iron site when different solvents are applied.
- The study also reveals various anions related to {FeW}, characterizes them through X-ray diffraction, examines their redox properties, and contrasts the bonding between Fe and W with bonds in other metal clusters using theoretical calculations.
Resolving old problems with layered polytungstates related to hexagonal tungsten bronze: phase formation, structures, crystal chemistry and some properties.
Dalton Trans
February 2023
A 60-year-old problem with the atomic arrangements and exact compositions of alkali polytungstates related to hexagonal tungsten bronze (HTB) was solved. The systems WO-WO ( = K, Rb) were restudied and the average monoclinic layered structures of stoichiometric polytungstates WO ( = K, Rb, Cs, Tl) and WO ( = K, Rb, Cs) were first successfully determined. The structures resemble those of "MoWO" and "MoWO" (J.
View Article and Find Full Text PDFRbAgSc(WO): a new glaserite-related structure type, rubidium disorder, ionic conductivity.
Acta Crystallogr B Struct Sci Cryst Eng Mater
February 2020
A new triple tungstate RbAgSc(WO) (0 ≤ x ≤ 0.15) synthesized by solid state reactions and spontaneous crystallization from melts presents a new structure type related to those of CsNaYb(MoO) and NaSrTa(PO). The title compound in centrosymmetric space group Cmcm contains dimers of two ScO octahedra sharing corners with three bridging WO tetrahedra.
View Article and Find Full Text PDFArticle Synopsis
- A new triple molybdate compound, RbAgIn(MoO), was synthesized and characterized, exhibiting a unique crystal structure that supports two-dimensional ionic conductivity.
- The compound's structure features interconnected octahedra and trigonal prisms, forming a 3D framework and incorporating Rubidium atoms in its cavities.
- Notably, RbAgIn(MoO) shows a first-order phase transition at 535 K, accompanied by a significant increase in electrical conductivity, making it a promising candidate for high-temperature ionic conductivity applications.