Benzopyrano-Fused Phenanthridine-Based Columnar Mesogens: Synthesis, Self-organization and Charge-Transport Properties.

Columnar mesogens constitute a fascinating class of supramolecular nano-architectures owing to the exceptional properties induced by their self-assembling behavior. Extending the π-conjugated core in such systems by incorporating heteroatoms extensively influences their mesomorphic, photophysical properties, etc., presenting them as potential candidates for optoelectronic applications.

New luminescent ordered liquid crystalline molecules with a 3-cyano-2-pyridone core unit.

The self-organized states of liquid crystals (LCs) have recently received a lot of attention because of their various applications, especially in the fields of electron transport materials and optoelectronic devices. In most of these applications, molecules containing a donor-acceptor skeleton have been widely employed and generally these molecular frameworks have been designed mainly on the basis of the donor-acceptor concept. Inspired from this concept, we synthesized a series of new donor-acceptor based luminescent molecules, 4,6-bis(4-alkyloxyphenyl)-2-oxo-1,2-dihydropyridine-3-carbonitrile (Pn-series), carrying variable alkoxy chains [ = 8, 10, 12, 14, 16].