Publications by Vanessa G Pelayo-Gonzalez

Publications by authors named "Vanessa G Pelayo-Gonzalez"

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Hypervalent-iodine induced quasi-Favorskii C-ring contraction of 12-oxosteroids: a shortcut to C-norsteroids.

Jacqueline Sánchez-Flores Vanessa G Pelayo-González Margarita Romero-Ávila Blas Flores-Pérez Marcos Flores-Álamo

Steroids

February 2013

Treatment of 12-oxosteroids with PhI(OAc)(2) and KOH in refluxing methanol triggers a quasi-Favorskii C-ring contraction leading to the corresponding 11α-alcoxycarbonyl-C-norsteroids in moderate yields. This constitutes the first one-step synthetic alternative to C-norsteroids starting from 12-oxosteroids.

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