Nanozymes based on manganese oxide (MnO) are demonstrated to be promising probes in colorimetric sensing applications. In this study, the r-MnO/β-MnO heterophase nanostructure was simply prepared by a calcination process with controllable temperature. The characterization of the nanostructured material was confirmed by SEM, UV-vis spectroscopy, Raman, TGA-DSC, and XRD analysis.
View Article and Find Full Text PDFSilver nanoparticles (AgNPs) have been regarded as a highly promising substrate for surface-enhanced Raman scattering (SERS) sensors. In this study, we focused on the electrochemical synthesis method by developing three kinds of AgNPs using three different electrolytes: citrate (e-Ag-C), oleic acid (e-Ag-O) and fish mint ( Thunb.) extract (e-Ag-bio).
View Article and Find Full Text PDFThe rapid and efficient detection of chloride (Cl) ions is crucial in a variety of fields, making the development of advanced sensing methods such as colorimetric sensors an imperative advancement in analytical chemistry. Herein, a novel, selective, and straightforward paper-based colorimetric sensing platform has been developed utilizing an amorphous photonic array (APA) of magnetoplasmonic Ag@FeO nanoparticles (MagPlas NPs) for the detection of Cl in water. Taking advantage of the highly responsive APA, the key principle of this sensing method is based on the chemical reaction between Ag and Cl, which results in the precipitation of high-refractive index (RI) AgCl.
View Article and Find Full Text PDFA functional ternary substrate was developed for surface-enhanced Raman scattering (SERS) sensing systems. MnO nanosheets were synthesized by a simple and controllable hydrothermal method, followed by the integration of graphene oxide (GO) nanosheets. Subsequently, MnO/GO nanostructures were decorated with plasmonic Ag nanoparticles (e-AgNPs).
View Article and Find Full Text PDFPhys Chem Chem Phys
July 2023
Taking advantage of metal-semiconductor junctions, functional nanocomposites have been designed and developed as active substrates for surface-enhanced Raman scattering (SERS) sensing systems. In this work, we prepared three types of nanocomposites based on manganese oxide (MnO) nanostructures and electrochemically synthesized silver nanoparticles (e-AgNPs), which differed according to the morphologies of MnO. The SERS performance of MnO nanosheet/e-Ag (MnO-s/e-Ag), MnO nanorod/e-Ag (MnO-r/e-Ag), and MnO nanowire/e-Ag (MnO-w/e-Ag) was then evaluated using tricyclazole (TCZ), a commonly used pesticide, as an analyte.
View Article and Find Full Text PDFRSC Adv
March 2023
In this study, bio-Ag/ZnO NCs were synthesized a microwave-assisted biogenic electrochemical method using mangosteen () peel extract as a biogenic reducing agent for the reduction of Zn and Ag ions to form hybrid nanoparticles. The as-synthesized NC samples at three different microwave irradiation temperatures ( , , ) exhibited a remarkable difference in size and crystallinity that directly impacted their electrocatalytic behaviors as well as electrochemical sensing performance. The obtained results indicate that the sample showed the highest electrochemical performance among the investigated samples, which is attributed to the improved particle size distribution and crystal microstructure that enhanced charge transfer and the electroactive surface area.
View Article and Find Full Text PDFUsing electrochemically exfoliated graphene oxide (GO)-modified screen-printed carbon electrodes for the detection of furazolidone (FZD), a nitrofuran antibiotic, was explored. In this study, we designed some GO samples possessing different oxygen functional group content/defect density by using ultrasonic irradiation or microwave techniques as supporting tools. The difference in physical characteristics of GO led to the remarkable change in kinetic parameters (electron transfer rate constant ( ) and transfer coefficient ()) of electron transfer reactions at / probes as well as the FZD analyte.
View Article and Find Full Text PDFThe present work reports efficient electrochemical nanosensors for the sensitive monitoring of 4-nitrophenol (4-NP) in tomato samples using various biosynthesized silver nanoparticles (bio-AgNPs). Three different bio-AgNP types were synthesized using natural plant extracts, including green tea (GT) leaf, grapefruit peel (GP), and mangosteen peel (MP), aiming to investigate their effects on the formation of bio-AgNPs, as well as the analytical performance of 4-NP. Based on the obtained results, it was found that the phytochemical content in various plant extracts directly influenced the physicochemical parameters of the created bio-AgNPs, such as particle size, crystallinity, and distribution.
View Article and Find Full Text PDFMoS-GO composites were fabricated by an ultrasonication method at room temperature. Raman spectra, emission scanning electron microscopy (SEM), and transmission electron microscopy (TEM) images were used to study the structural characteristics, morphologies, and sizes of the synthesized materials. An MoS-GO/SPE (screen-printed electrode) was prepared by a facile dropping method and acted as an effective electrochemical sensor toward clenbuterol (CLB) and 4-nitrophenol (4-NP) detection.
View Article and Find Full Text PDFIntroduction: African swine fever (ASF) was officially reported in Vietnam in February 2019 and spread across the whole country, affecting all 63 provinces and cities.
Material And Methods: In this study, ASF virus (ASFV) VN/Pig/HaNam/2019 (VN/Pig/HN/19) strain was isolated in primary porcine alveolar macrophage (PAM) cells from a sample originating from an outbreak farm in Vietnam's Red River Delta region. The isolate was characterised using the haemadsorption (HAD) test, real-time PCR, and sequencing.