This work investigates the structure, optical and electrical conductivity properties of BaTi Co O (0≤ ≤0.1) ceramics prepared by the hydrothermal method. The X-ray diffraction and Raman scattering analysis demonstrates that the prepared samples have a single-phase tetragonal structure with 4 symmetry.
View Article and Find Full Text PDFThis paper describes a rapid bottom-up approach to selectively functionalize gold nanoparticles (AuNPs) on an indium tin oxide (ITO) substrate using the plasmon confinement effect. The plasmonic substrates based on a AuNP-free surfactant were fabricated by electrochemical deposition. Using this bottom-up technique, many sub-30 nm spatial gaps between the deposited AuNPs were randomly generated on the ITO substrate, which is difficult to obtain with a top-down approach (i.
View Article and Find Full Text PDFBull Environ Contam Toxicol
June 2021
In this work, reduced graphene oxide/double-walled carbon nanotubes/octahedral-FeO/chitosan composite material modified screen-printed gold electrodes (rGO/DWCNTs/Oct-FeO/Cs/SPAuE) under inhibition of urease enzyme was developed for the determination of glyphosate (GLY). The electrochemical behaviors of GLY on these electrodes were evaluated by square wave voltammetry (SWV). With the electroactive surface area is 1.
View Article and Find Full Text PDFIn this work, we have combined nanosphere lithography with electrochemical reduction of aryldiazonium salts to elaborate nanostructured mixed layers of organic materials. The strategy consists first in the deposition of a close-packed hexagonal monolayer of microbeads used as a mask for the electroreduction of a first aryldiazonium salt. After removing the beads, an ultrathin organic layer with holes remains.
View Article and Find Full Text PDFA plasmonic molecular electronic device, consisting of poly(3,4-ethylenedioxythiophene) (PEDOT) nanowires bridging an ultramicroelectrode and an indium tin oxide (ITO) substrate covered by gold nanoparticles (Au NPs), has been developed. Light irradiation of this device has a dramatic impact on its conductance. Polymer strands, maintained electrochemically in their oxidized, conducting state, reversibly switch to their insulating state upon irradiation by visible-wavelength light, resulting in a sharp decrease in the conductance.
View Article and Find Full Text PDFSurface grafting from diazonium solutions triggered by localized surface plasmon has been investigated. An organic layer that is 20-30 nm thick is easily grafted onto gold nanoparticles (AuNPs) by visible-light illumination in a few minutes without any reducing agent or molecular photocatalyst. Grafting depends on the wavelength and polarization of the incident light.
View Article and Find Full Text PDFA new heteroleptic polypyridyle Ru(II) complex was synthesized and deposited on surface by the diazonium electroreduction process. It yields to the covalent grafting of a monolayer. The functionalized surface was characterized by XPS, electrochemistry, AFM, and STM.
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