Nickel-Electrocatalyzed Synthesis of Bifuran-Based Monomers.

Bifuran motifs can be accessed with nickel-bipyridine electrocatalyzed homocouplings of bromine-substituted methyl furancarboxylates, which, in turn, can be prepared from hemicellulose-derived furfural. The described protocol uses sustainable carbon-based graphite electrodes in the simplest setup - an undivided cell with constant current electrolysis. The reported method avoids using a sacrificial anode by employing triethanolamine as an electron donor.

A metal-free carbon catalyst for oxidative dehydrogenation of aryl cyclohexenes to produce biaryl compounds.

A metal-free route based on a carbon catalyst to synthesize biphenyls through oxidative dehydrogenation (ODH) of phenyl cyclohexene has been investigated. Among the samples examined, an air-oxidized active carbon exhibits the best activity with a 9.1 × 10 h rate constant, yielding 74% biphenyl in 28 h at 140 °C under five bar O in anisole.