Sorption of CO, CH and Their Mixtures in Amorphous Poly(2,6-dimethyl-1,4-phenylene)oxide (PPO).

Sorption of pure CO and CH and CO/CH binary gas mixtures in amorphous glassy Poly(2,6-dimethyl-1,4-phenylene) oxide (PPO) at 35 °C up to 1000 Torr was investigated. Sorption experiments were carried out using an approach that combines barometry with FTIR spectroscopy in the transmission mode to quantify the sorption of pure and mixed gases in polymers. The pressure range was chosen to prevent any variation of the glassy polymer density.

Modelling changes in glass transition temperature in polymer matrices exposed to low molecular weight penetrants.

Polymer matrices, when placed in contact with a fluid phase made of low molecular weight compounds, undergo a depression of their glass transition temperature () determined by the absorption of these compounds and the associated plasticization phenomena. Frequently, this effect is coupled with the mechanical action of the compressive stress exerted by the pressure of the fluid phase that, in contrast, promotes an increase in the . This issue is relevant for technological and structural applications of composites with high-performance glassy polymer matrices, due to their significant impact on mechanical properties.

A Molecular Interpretation of the Dynamics of Diffusive Mass Transport of Water within a Glassy Polyetherimide.

The diffusion process of water molecules within a polyetherimide (PEI) glassy matrix has been analyzed by combining the experimental analysis of water sorption kinetics performed by FTIR spectroscopy with theoretical information gathered from Molecular Dynamics simulations and with the expression of water chemical potential provided by a non-equilibrium lattice fluid model able to describe the thermodynamics of glassy polymers. This approach allowed us to construct a convincing description of the diffusion mechanism of water in PEI providing molecular details of the process related to the effects of the cross- and self-hydrogen bonding established in the system on the dynamics of water mass transport.

Modeling Retrograde Vitrification in the Polystyrene-Toluene System.

Atactic polystyrene, as reported in a recent contribution by our group, displays a marked change in glass transition when exposed to toluene vapor due to plasticization associated with vapor sorption within the polymer. The dependence of the glass transition temperature of the polymer-penetrant mixture on the pressure of toluene vapor is characterized by the so-called "retrograde vitrification" phenomenon, in that, at a constant pressure, a rubber to glass transition occurs by increasing the temperature. In this contribution, we have used a theoretical approach, based on the nonrandom lattice fluid thermodynamic model for the polymer-toluene mixture, to predict the state of this system, i.

Analysis of a Polystyrene-Toluene System through "Dynamic" Sorption Tests: Glass Transitions and Retrograde Vitrification.

Exposing a glassy polymer to a fluid phase (in gaseous or liquid state) containing a low molecular weight compound results in the sorption of the latter within the polymer, inducing, among other effects, the plasticization of the material which also promotes a change in the glass transition temperature. The amount of sorbed penetrant is often related in a complex fashion to the temperature and pressure of the fluid, thus determining that the locus of glass transition, when represented in pressure-temperature coordinates, may display as well rather complex patterns. This is an issue of particular importance in several applications of glassy polymers.