A comparative total cost of ownership analysis of heavy duty on-road and off-road vehicles powered by hydrogen, electricity, and diesel.

This study investigated the cost competitiveness, using total cost of ownership (TCO) analysis, of hydrogen fuel cell electric vehicles (FCEVs) in heavy duty on and off-road fleet applications as a key enabler in the decarbonisation of the transport sector and compares results to battery electric vehicles (BEVs) and diesel internal combustion engine vehicles (ICEVs). Assessments were carried out for a present day (2021) scenario, and a sensitivity analysis assesses the impact of changing input parameters on FCEV TCO. This identified conditions under which FCEVs become competitive.

Thermogravimetric and kinetic analysis to discern synergy during the co-pyrolysis of microalgae and swine manure digestate.

Background: Co-pyrolysis of wastes with other feedstock can synergistically improve the rate of biomass decomposition and also help to resolve the issues related to limited availability feedstock. In this regards, synergistic interaction between feedstock during co-pyrolysis is an important aspect of research. As the constituents of aquatic and lignocellulosic biomass are different, and the decomposition pattern of aquatic biomass is dissimilar when compared to lignocellulosic biomass, it is important to understand whether these two biomasses interact during co-pyrolysis.

Spray-Dried Sodium Zirconate: A Rapid Absorption Powder for CO Capture with Enhanced Cyclic Stability.

Improved powders for capturing CO at high temperatures are required for H production using sorption-enhanced steam reforming. Here, we examine the relationship between particle structure and carbonation rate for two types of Na ZrO powders. Hollow spray-dried microgranules with a wall thickness of 100-300 nm corresponding to the dimensions of the primary acetate-derived particles gave about 75 wt % theoretical CO conversion after a process-relevant 5 min exposure to 15 vol % CO .

Steam reforming of crude glycerol with in situ CO(2) sorption.

Steam reforming of the crude glycerol by-product of a biodiesel production plant has been evaluated experimentally at atmospheric pressure, with and without in situ CO(2) sorption, in a continuous flow fixed-bed reactor between 400 degrees C and 700 degrees C. The process outputs were compared to those using pure glycerol. Thermodynamic equilibrium calculations were used to assess the effect on the steam reforming process of the main crude impurities (methanol and four fatty acid methyl esters).

Hydrogen production by sorption-enhanced steam reforming of glycerol.

Catalytic steam reforming of glycerol for H(2) production has been evaluated experimentally in a continuous flow fixed-bed reactor. The experiments were carried out under atmospheric pressure within a temperature range of 400-700 degrees C. A commercial Ni-based catalyst and a dolomite sorbent were used for the steam reforming reactions and in situ CO(2) removal.

Thermogravimetric kinetics of crude glycerol.

The pyrolysis of the crude glycerol from a biodiesel production plant was investigated by thermogravimetry coupled with Fourier transform infrared spectroscopy. The main gaseous products are discussed, and the thermogravimetric kinetics derived. There were four distinct phases in the pyrolysis process of the crude glycerol.