Spin-polarization transfer in colloidal magnetic-plasmonic Au/iron oxide hetero-nanocrystals.

We report on the unprecedented direct observation of spin-polarization transfer across colloidal magneto-plasmonic Au@Fe-oxide core@shell nanocrystal heterostructures. A magnetic moment is induced into the Au domain when the magnetic shell contains a reduced Fe-oxide phase in direct contact with the noble metal. An increased hole density in the Au states suggested occurrence of a charge-transfer process concomitant to the magnetization transfer.

Synthesis of (E,Z)-1-alkoxy-3-acyloxy-2-methylpenta-1,3-dienes via Danishefsky-type dienes or O-acylation of enones.

1-Alkoxy-2-methyl-3-acyloxy-(E,E)-penta-1,3-dienes have been prepared applying among others a modified Danishefsky's general method, including chiral, racemic, and achiral derivatives.