Reducing noble metal dependence: oxygen evolution reaction with a Ru-minimized BiRuO@MOF-801 composite.

Developing efficient and noble metal-minimized electrocatalysts for the oxygen evolution reactions (OER) is critical for energy conversion reactions. Here we present Ru-minimized BiRuO@MOF-801 that synergistically combines the high catalytic activity of the bimetallic oxide with the unique structural and hydrophilic properties of the Zr-MOF. The composite achieves superior OER performance with a low overpotential of 307 mV at 50 mA cm and a Tafel slope of 99.

Association of Obesity, Inflammation, and Hypogonadism: A Cross-Sectional Study in Males Under 60 Years of Age.

Background Obesity is a significant global health issue closely associated with numerous metabolic disorders, including hypogonadism. Male obesity-related secondary hypogonadism (MOSH) is characterized by reduced testosterone levels, leading to various health complications. The bidirectional relationship between obesity and hypogonadism creates a vicious cycle, with obesity exacerbating hypogonadism and hypogonadism contributing to further obesity.

α-BiMoO: A Dual-Functional Material for Electrocatalytic Water Splitting and Supercapacitor Applications.

This study explores the functionality of α-BiMoO (BMO) as an electrocatalyst for water splitting and its suitability for supercapacitor applications. BMO was synthesized by the solvothermal method and characterized in pre-calcination [BMO (BC)], post-calcination [BMO (AC)], and base-etched forms [BMO (BE)]. Structural analysis confirmed the formation of α-BiMoO with well-defined crystallographic planes.

CuNi sulphidation maximizes MOR activity by expanding the accessibility of active sites!

Sulphidation of a CuNi alloy of Cu : Ni ratio 81 : 19 led to an exponential activity enhancement in the alkaline methanol oxidation reaction (MOR) by four fold due to an order of magnitude increase in the number of active Cu and Ni sites and improved charge transfer properties.

A Case of Pyrexia of Unknown Origin Diagnosed as Hemophagocytic Lymphohistiocytosis.

Hemophagocytic lymphohistiocytosis (HLH) is a rare disease that is even rarer in the adult population. It requires a high degree of suspicion from the treating physician, and if diagnosed early, patients might have a survival benefit from this highly fatal condition. HLH is a disorder of immune regulation where the hyperactivity of cytokines attacks different cells, which leads to multiple organ dysfunctions.

Sonophotocatalytic water splitting by BaTiO@SrTiO core shell nanowires.

Sonophotocatalysis has garnered significant attention due to its potential to enhance advanced oxidation processes, particularly water splitting, by employing materials with combined sonocatalytic and photocatalytic properties. In this study, we synthesized and investigated core-shell BaTiO@SrTiO nanowires (BST NWs) with varying Sr/Ba molar ratios (2.5:7.

A novel CoMoO enwrapped ZIF-8 nanocomposite with enhanced visible light photocatalytic activity.

A hybrid nano catalyst, CoMoO anchored zeolitic imidazolate framework-8 (ZIF-8) has been synthesized by simplest in-situ chemical method. The characterization results showed that the CoMoO@ZIF-8 composites had a crystalline structure with a uniform distribution of the Cobalt molybdate particles on the ZIF-8 surface. The FTIR spectra revealed the presence of characteristic peaks for both ZIF-8 and CoMoO, indicating the successful incorporation of the metal molybdate into the ZIF-8 framework.

Resistance Profiles to Second-Line Anti-Tuberculosis Drugs and Their Treatment Outcomes: A Three-Year Retrospective Analysis from South India.

: Patients with first-line drug resistance (DR) to rifampicin (RIF) or isoniazid (INH) as a first-line (FL) line probe assay (LPA) were subjected to genotypic DST using second-line (SL) LPA to identify SL-DR (including pre-XDR) under the National TB Elimination Program (NTEP), India. SL-DR patients were initiated on different DR-TB treatment regimens and monitored for their outcomes. The objective of this retrospective analysis was to understand the mutation profile and treatment outcomes of SL-DR patients.

A review on hypo-cholesterolemic activity of seeds and its extracts.

(N. sativa) (Family Ranunculaceae) is a popular therapeutic herb in many parts of the world. It is widely used in traditional medical systems such as Unani, Ayurveda and Siddha.

Rhino Orbital Cerebral Mucormycosis in Covid-19 Crisis.

Rhino-Orbital cerebral Mucormycosis (ROCM) an angioinvasive fungal infection commonly seen in diabetic and immunocompromised patients. In recent days, due to COVID 19 pandemic mucormycosis has been significantly increased (Smith et al. in Radiol Cardiothorac Imaging 2(5):e200280, 2020).

Comparative Study of Pain Scale Assessment Between Cold Verses Hot Tonsillectomy Method.

Tonsillectomy is an age old surgery especially in pediatric population. Over the last few years, various techniques have been proposed in performing tonsillectomy in an attempt to lower the morbidity and mortality. This study compares the post-operative pain scale of cold dissection method and newer methods like coblation, radiofrequency and bipolar cautery assisted tonsillectomy.

Nanocubic copper cobaltite for methyl orange degradation through photocatalytic process.

In this study, cubic spinel structured CuCoO (Copper cobaltite) nanospheres were fabricated by thermal decomposition method. The visible light degradation of organic contaminant methyl orange (MO) was focused in this study using the synthesized pure CuO, CoO and CuCoO with different weight ratios of raw materials (90:10, 75:25 and 50:50). It could be well realized that after the characterization techniques, the synthesized CuCoO materials resembled cubic spinel structure as confirmed by X-ray diffraction (XRD) investigation.

Facile synthesis of broom stick like FeOCl/g-CN nanocomposite as novel Z-scheme photocatalysts for rapid degradation of pollutants.

A simple and cost-effective route has been utilized for the preparation of a novel lamellar structured FeOCl/g-CN nanocomposite as Z-scheme photocatalyst. The preparation method was performed under the ambient temperature conditions without any hazardous chemicals. Various characterization techniques, namely XRD, FESEM, TEM, FT-IR, UV-Vis, DRS, and PL were carried out to analyse the nanocomposite for confirmation of FeOCl/g-CN nanocomposite.

Novel S-scheme 2D/2D BiOBr nanoplatelets/g-CN heterojunctions with enhanced photocatalytic activity towards organic pollutants removal.

Removal of organic pollutants and pharma products in waste water using semiconductor photocatalysts has gained huge interest among recent days. However, low visible light absorption, recombination rate of charge carriers and less availability of reaction sites are still major obstacles for the photocatalysis process. Herein, an in situ-forming BiOBr nanosheets decorated on the surface g-CN were prepared via simple hydrothermal method under ambient temperature.

Heavy metal remediation from wastewater using microalgae: Recent advances and future trends.

Microalgae-based wastewater treatment has previously been carried out in huge waste stabilization ponds. Microalgae, which can absorb carbon dioxide while reusing nutrients from sewage, has recently emerged as a new trend in the wastewater treatment business. Microalgae farming is thought to be a potential match for the modern world's energy strategy, which emphasizes low-cost and environmentally benign alternatives.

Removal of harmful algae in natural water by semiconductor photocatalysis- A critical review.

Harmful Algal Blooms (HABs) have turned out to be a global occurrence owing to the detrimental phenomenon like eutrophication and global climate change caused by human activities. This newly emergent threat imposes a severe hazardous to public health, ecosystems and fishery-based economies. Rapid and exponential growth of certain delirious and toxic algal species shall be held causative to the formation of HABs.

Efficient Cr(vi) photoreduction under natural solar irradiation using a novel step-scheme ZnS/SnInS nanoheterostructured photocatalysts.

Removal of heavy metal pollutants from water is a challenge to water security and the environment. Therefore, in this work, multinary chalcogenide based nanoheterostructures such as ZnS/SnInS nanoheterostructure with different loading amounts were prepared. The prepared nanoheterostructures were utilized as photocatalysts for chromium (Cr(vi)) photoreduction.

Highly efficient visible light photocatalysis of Ni Zn FeO (x= 0, 0.3, 0.7) nanoparticles: Diclofenac degradation mechanism and eco-toxicity.

Pharmaceuticals and personal care products occupy a predominant position with respect to both utility and release into the ecosystem, thereby contributing to environmental pollution at alarming rates. Of the several methods identified to minimize the concentration of PPCPs, nanomaterial based photocatalysis seems to be a potential alternative for it being highly economical and eco-friendly. In this study, we synthesized Nickel zinc ferrite (Ni-ZF) [Ni Zn FeO (x = 0, 0.

Advances in preparation, mechanism and applications of various carbon materials in environmental applications: A review.

Carbon-related materials are now widely investigated in a various industrial field due to their excellent and unique qualities. It must be tailored to the application in such a way that it fits the application. At the same time, it needs to be generated in sufficient quantities for commercial use, and the synthesis method is the major sticking point here.

Improved visible-light-driven photocatalytic removal of Bisphenol A using VO/WO decorated over Zeolite: Degradation mechanism and toxicity.

WO/Zeolite/VO (TZV) composite synthesized through co-precipitation was used for the degradation of Bisphenol-A (BpA). XRD and Raman spectra were employed to ascertain the crystallinity of the composite. The pristine nature of the compound without any free particles over the zeolite surface was established through FESEM, thus, substantiating the composite character of the material.

A Novel, Smartphone-Based, Teleophthalmology-Enabled, Widefield Fundus Imaging Device With an Autocapture Algorithm.

Purpose: Widefield imaging can detect signs of retinal pathology extending beyond the posterior pole and is currently moving to the forefront of posterior segment imaging. We report a novel, smartphone-based, telemedicine-enabled, mydriatic, widefield retinal imaging device with autofocus and autocapture capabilities to be used by non-specialist operators.

Methods: The Remidio Vistaro uses an annular illumination design without cross-polarizers to eliminate Purkinje reflexes.

CuO-ZnO-PANI a lethal p-n-p combination in degradation of 4-chlorophenol under visible light.

Recent interest and responsibility to retain the water resources rose among people. Scientists have been engaged to develop the mechanism that involves the freely available sunlight - a sustainable resource - to remove the pollutants from water to make it again suitable for life. Ample research was reported in the removal of dye pollutants present in water.

Non-noble metal (Ni, Cu)-carbon composite derived from porous organic polymers for high-performance seawater electrolysis.

The hydrothermal preparation of o-dianisidine and triazine interlinked porous organic polymer and its successive derivatisation via metal infusion (Ni, Cu) under hydrothermal and calcination conditions (700 °C) to yield pristine (ANIPOP-700) and Ni/Cu decorated porous carbon are described here (Ni-ANIPOP-700 and Cu-ANIPOP-700). To confirm their chemical and morphological properties, the as-prepared materials were methodically analyzed using solid state C and N NMR, X-ray diffraction, Raman spectroscopy, field emission scanning and high resolution transmission electron microscopic techniques, and x-ray photoelectron spectroscopy. Furthermore, the electrocatalytic activities of these electrocatalysts were thoroughly investigated under standard oxygen evolution (OER) and hydrogen evolution reaction (HER) conditions.