Balancing the Number of Quantum Wells in HgCdTe/CdHgTe Heterostructures for Mid-Infrared Lasing.

HgCdTe-based heterostructures with quantum wells (QWs) are a promising material for semiconductor lasers in the atmospheric transparency window (3-5 μm) thanks to the possibility of suppressing Auger recombination due to the no-parabolic law of carrier dispersion. In this work, we analyze the thresholds of stimulated emission (SE) under optical pumping from heterostructures with a different number of QWs in the active region of the structure. Total losses in structures are determined from the comparison of thresholds for the different number of QWs in the active region.

Stimulated Emission up to 2.75 µm from HgCdTe/CdHgTe QW Structure at Room Temperature.

Heterostructures with thin Hg(Cd)Te/CdHgTe quantum wells (QWs) are attractive for the development of mid-infrared interband lasers. Of particular interest are room-temperature operating emitters for the short-wavelength infrared range (SWIR, typically defined as 1.7-3 μm).

Terahertz plasmons in doped HgTe quantum well heterostructures: dispersion, losses, and amplification.

We have calculated two-dimensional plasmon energy spectra in HgTe/CdHgTe quantum wells with normal, gapless, and inverted energy spectra with different electron concentrations, taking into account spatial dispersion of electron polarizability and plasmon interaction with the optical phonons. The spectra of the absorption coefficients of two-dimensional plasmons are found. It is shown that an increase of electron concentration in a quantum well leads to a decrease in the plasmon absorption coefficient.

Optical Studies and Transmission Electron Microscopy of HgCdTe Quantum Well Heterostructures for Very Long Wavelength Lasers.

HgTe/CdHgTe quantum well (QW) heterostructures have attracted a lot of interest recently due to insights they provided towards the physics of topological insulators and massless Dirac fermions. Our work focuses on HgCdTe QWs with the energy spectrum close to the graphene-like relativistic dispersion that is supposed to suppress the non-radiative Auger recombination. We combine various methods such as photoconductivity, photoluminescence and magneto-optical measurements as well as transmission electron microscopy to retrofit growth parameters in multi-QW waveguide structures, designed for long wavelengths lasing in the range of 10-22 μm.

Optical properties and lattice dynamics of a novel allotrope of orthorhombic elemental germanium.

Optical and vibrational properties of a novel allotrope of elemental germanium Ge(oP32), which crystallizes in the structure corresponding to the orthorhombic space group Pbcm, are studied experimentally by means of absorption and polarized Raman scattering measurements and theoretically using the first principles density functional theory. Material is found to be a direct band gap semiconductor with E   =  0.33 eV.

Landau level spectroscopy of valence bands in HgTe quantum wells: effects of symmetry lowering.

The Landau level spectroscopy technique has been used to explore the electronic structure of the valence band in a series of p-type HgTe/HgCdTe quantum wells with both normal and inverted ordering of bands. We find that the standard axial-symmetric 4-band Kane model, which is nowadays widely applied in physics of HgTe-based topological materials, does not fully account for the complex magneto-optical response observed in our experiments-notably, for the unexpected avoided crossings of excitations and for the appearance of transitions that are electric-dipole forbidden within this model. Nevertheless, reasonable agreement with experiments is achieved when the standard model is expanded to include effects of bulk and interface inversion asymmetries.

Magnetoconductivity and Terahertz Response of a HgCdTe Epitaxial Layer.

An epitaxial layer of HgCdTe-a THz detector-was studied in magnetotransmission, magnetoconductivity and magnetophotoconductivity experiments at cryogenic temperatures. In the optical measurements, monochromatic excitation with photon frequency ranging from 0.05 THz to 2.

Radiative recombination in narrow gap HgTe/CdHgTe quantum well heterostructures for laser applications.

Radiative recombination is studied in CdHgTe/HgTe QWs with bandgap in the 40-140 meV range using four-band Kane model. Calculated radiative lifetimes agree well with the photoconductivity kinetics measurements. We show that the side maxima in the valence band hinder the radiative recombination at high carrier concentrations and discuss how to overcome this effect for the development of long-wavelength lasers.

Stimulated emission in the 2.8-3.5 μm wavelength range from Peltier cooled HgTe/CdHgTe quantum well heterostructures.

We report stimulated emission in the 2.8-3.5 μm wavelength range from HgTe/CdHgTe quantum well (QW) heterostructures at temperatures available with thermoelectric cooling.

Temperature-driven massless Kane fermions in HgCdTe crystals.

It has recently been shown that electronic states in bulk gapless HgCdTe offer another realization of pseudo-relativistic three-dimensional particles in condensed matter systems. These single valley relativistic states, massless Kane fermions, cannot be described by any other relativistic particles. Furthermore, the HgCdTe band structure can be continuously tailored by modifying cadmium content or temperature.

Cyclotron resonance in HgTe/CdTe-based heterostructures in high magnetic fields.

: Cyclotron resonance study of HgTe/CdTe-based quantum wells with both inverted and normal band structures in quantizing magnetic fields was performed. In semimetallic HgTe quantum wells with inverted band structure, a hole cyclotron resonance line was observed for the first time. In the samples with normal band structure, interband transitions were observed with wide line width due to quantum well width fluctuations.

Exchange interaction effects in electron spin resonance: Larmor theorem violation in narrow-gap quantum well heterostructures.

We report a theoretical study of the exchange interaction effects in the electron spin resonance (ESR) in n-type narrow-gap quantum well (QW) heterostructures. Using the Hartree-Fock approximation, based on the eight-band k⋅p Hamiltonian, the many-body correction to the ESR energy is found to be nonzero, providing theoretical evidence of Larmor theorem violation in symmetric narrow-gap QWs. We predict the exchange enhancement of the ESR g-factor and its divergence in low magnetic fields.

Ethanol adsorption on the Si (111) surface: first principles study.

Equilibrium atomic configurations and electron energy structure of ethanol adsorbed on the Si (111) surface are studied by the first principles density functional theory. Geometry optimization is performed by the total energy minimization method. Equilibrium atomic geometries of ethanol, both undissociated and dissociated, on the Si (111) surface are found and analysed.

The effect of exchange interaction on quasiparticle Landau levels in narrow-gap quantum well heterostructures.

Using the 'screened' Hartree-Fock approximation based on the eight-band k·p Hamiltonian, we have extended our previous work (Krishtopenko et al 2011 J. Phys.: Condens.

Theory of g-factor enhancement in narrow-gap quantum well heterostructures.

We report on the study of the exchange enhancement of the g-factor in the two-dimensional (2D) electron gas in n-type narrow-gap semiconductor heterostructures. Our approach is based on the eight-band k⋅p Hamiltonian and takes into account the band nonparabolicity, the lattice deformation, the spin-orbit coupling and the Landau level broadening in the δ-correlated random potential model. Using the 'screened' Hartree-Fock approximation we demonstrate that the exchange g-factor enhancement not only shows maxima at odd values of Landau level filling factors but, due to the conduction band nonparabolicity, persists at even filling factor values as well.

Elongation of surface plasmon polariton propagation length without gain.

We have demonstrated that an addition of highly concentrated rhodamine 6G chloride dye to the PMMA film adjacent to a silver film can cause 30% elongation of the propagation length of surface Plasmon polaritons (SPPs). The possibility to elongate the SPP propagation length without optical gain opens a new technological dimension to low-loss nanoplasmonic and metamaterials.

Sensitized nonlinear emission of gold nanoparticles.

We have studied Stokes and anti-Stokes emission of Au nanoparticles suspended in pure methanol and methanol solution of rhodamine 6G dye. In the presence of dye, excitation of anti-Stokes emission of gold involves two-photon absorption in rhodamine 6G molecules followed by the energy transfer to Au nanoparticles with simultaneous absorption of one pumping photon by Au. The sensitization by dye molecules caused six-fold enhancement of the anti-Stokes emission of gold nanoparticles.

Emission of Au nanoparticles with and without rhodamine 6G dye.

We have observed Stokes and anti-Stokes emission of Au nanoparticles suspended in methanol and rhodamine 6G dye solution. Photoluminescence of Au nanoparticles is a three-step process involving single-photon or three-photon excitation of electron-hole pairs, relaxation of excited electrons and holes, and emission from electron-hole recombination, possibly enhanced by surface plasmons. In the presence of dye, the excitation of anti-Stokes emission of gold involves two-photon absorption in rhodamine 6G molecules followed by the energy transfer to Au nanoparticles with simultaneous absorption of one pumping photon by Au.

Ab initio study of optical properties of rhodamine 6G molecular dimers.

Equilibrium atomic geometries of rhodamine 6G (R6G) dye molecule dimers are studied using density-functional theory. Electron-energy structure and optical properties of R6G H and J dimers are calculated using the generalized gradient approximation method with ab initio pseudopotentials. Our theory predicts substantial redshifts or blueshifts of the optical absorption spectra of R6G dye molecules after aggregation in J or H dimers, respectively.

Optical second harmonic spectroscopy of boron-reconstructed Si(001).

Optical second harmonic generation (SHG) spectroscopy is used to probe Si(001) following thermal decomposition of diborane at the surface. Incorporation of boron (B) at second layer substitutional sites at H-free Si(001) intensifies and redshifts the E1 SHG spectral peak, while subsequent H termination further intensifies and blueshifts E1, in sharp contrast to the effect of bulk B doping or nonsubstitutional B. Ab initio pseudopotential and semiempirical tight binding calculations independently reproduce these unique trends, and attribute them to the surface electric field associated with charge transfer to electrically active B acceptors, and rehybridization of atomic bonds.