Relativistic Exact Two-Component Coupled-Cluster Study of Molecular Sensitivity Factors for Nuclear Schiff Moments.

Relativistic exact two-component coupled-cluster calculations of molecular sensitivity factors for nuclear Schiff moments (NSMs) are reported. We focus on molecules containing heavy nuclei, especially octupole-deformed nuclei. Analytic relativistic coupled-cluster gradient techniques are used and serve as useful tools for identifying candidate molecules that sensitively probe for physics beyond the Standard Model in the hadronic sector.

Opportunities for fundamental physics research with radioactive molecules.

Molecules containing short-lived, radioactive nuclei are uniquely positioned to enable a wide range of scientific discoveries in the areas of fundamental symmetries, astrophysics, nuclear structure, and chemistry. Recent advances in the ability to create, cool, and control complex molecules down to the quantum level, along with recent and upcoming advances in radioactive species production at several facilities around the world, create a compelling opportunity to coordinate and combine these efforts to bring precision measurement and control to molecules containing extreme nuclei. In this manuscript, we review the scientific case for studying radioactive molecules, discuss recent atomic, molecular, nuclear, astrophysical, and chemical advances which provide the foundation for their study, describe the facilities where these species are and will be produced, and provide an outlook for the future of this nascent field.

Effects of Electrons on Nuclear Clock Transition Frequency in ^{229}Th Ions.

We perform calculations of the energy shift of the nuclear clock transition frequency ^{229}Th as a function of the number of electrons in Th ion. We demonstrate that the dependence of the nuclear frequency on electron configuration is significant, for example, removing one electron from the atom leads to relative shift of the nuclear frequency ∼10^{-7}, which is 12 orders of magnitude larger than the expected relative uncertainty of the nuclear clock transition frequency (∼10^{-19}). This leads to the difference of the nuclear clock frequencies in Th IV, Th III, Th II, and Th I.

Variation of the Quadrupole Hyperfine Structure and Nuclear Radius due to an Interaction with Scalar and Axion Dark Matter.

Atomic spectroscopy is used to search for the space-time variation of fundamental constants which may be due to an interaction with scalar and pseudoscalar (axion) dark matter. In this Letter, we study the effects that are produced by the variation of the nuclear radius and electric quadrupole moment. The sensitivity of the electric quadrupole hyperfine structure to both the variation of the quark mass and the effects of dark matter exceeds that of the magnetic hyperfine structure by 1-2 orders of magnitude.

Erratum: Probing Long-Range Neutrino-Mediated Forces with Atomic and Nuclear Spectroscopy [Phys. Rev. Lett. 120, 223202 (2018)].

This corrects the article DOI: 10.1103/PhysRevLett.120.