Materials (Basel)
April 2024
A simple method for the direct transformation of Sr-exchanged titanosilicate with the sitinakite structure (IONSIV) into ceramic material through cold pressing and subsequent sintering at 1100 °C for 4 h is presented. The temperature transformation of Sr-exchanged sitinakite showed the stages of recrystallization of the material with the formation of Sr-Ti phases matsubaraite (SrTi[SiO]O), jeppeite (SrTiO), tausonite (SrTiO), and rutile. Leaching experiments showed the efficiency of fixation of Sr cations in a ceramic matrix; extraction into water does not exceed 0.
View Article and Find Full Text PDFActa Crystallogr B Struct Sci Cryst Eng Mater
April 2024
A series of novel KSrYEr(BO) (x = 0-1) phosphors that emit near-infrared radiation was synthesized using solid-state methods. Pure Y and Er crystals were grown using a KF flux via the top-seeded solution growth technique. In situ high-temperature single crystal X-ray diffraction, Raman spectroscopy and DFT calculations were used for characterization.
View Article and Find Full Text PDFFlexible crystal() structures, which exhibit() single-crystal()-to-single-crystal() (SCSC) transformations(), are attracting attention() in many applied aspects: magnetic() switches, catalysis, ferroelectrics and sorption. Acid treatment() for titanosilicate material() AM-4 and natural() compounds with the same structures led to SCSC transformation() by loss() Na, Li and Zn cations with large structural() changes (20% of the unit()-cell() volume()). The conservation() of crystallinity through complex() transformation() is possible due() to the formation() of a strong hydrogen bonding() system().
View Article and Find Full Text PDFNumerous studies expose the potential of brannerite to become a good matrix, concentrating fission products and actinides. Minerals can complement the data collected from the synthetic materials and offer an advantage of a long-time exposure to radiation. Natural metamict brannerite from Akchatau, Kazakhstan, and its annealed sample were studied by EPMA, Raman spectroscopy, TGA, DSC, XRD and HTXRD.
View Article and Find Full Text PDFBackground: Relatives of patients withaddictive disorders often face significant difficulties in their daily lives. Although the burnout concept is currently considered a significant and promising theoretical framework for studying family members who care for chronically ill patients, its application has encountered considerable difficulties in the area of addiction treatment.
Objective: This article explores the methodology for studying the psychological issues arising in families affected by addictive disorders.