Phys Rev E Stat Nonlin Soft Matter Phys
May 2008
It is well known that an activity expansion of the grand canonical partition function works well for attractive interactions, but poorly for repulsive interactions, such as occur between atoms and molecules. The virial expansion of the canonical partition function shows just the opposite behavior. This poses a problem for applications that involve both types of interactions, such as occur in the outer layers of low-mass stars.
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