Solution aggregation of platinum(ii) triimine methyl complexes.

The NMR chemical shifts of [Pt(tpy)(CH3)](PF6) (1) and [Pt(mbzimpy)(CH3)](PF6) (2), where tpy = 2,2';6'2''-terpyridine and mbzimpy = 2,6-bis(N-methylbenzimidazol-2-yl)pyridine, in room-temperature DMSO-d6 displayed concentration dependence as a result of formation of dimers. Quantification of these dimers, expressed by equilibrium constant (K), shows a greater tendency of 2 to aggregate in solution. Structural conformations of these dimers were confirmed by 2D 1H-1H NOESY; the results explicitly suggest a head-to-tail stacking arrangement of molecules in dimers.

Luminescent Pt(2,6-bis(N-methylbenzimidazol-2-yl)pyridine)X: a comparison with the spectroscopic and electrochemical properties of Pt(tpy)X (X = Cl, CCPh, Ph, or CH).

A series of platinum(ii) pincer complexes of the formula Pt(mbzimpy)X+, 1(a-d), (mbzimpy = 2,6-bis(N-methylbenzimidazol-2-yl)pyridine; X = Cl; (a), CCPh; (b), Ph; (c), or CH3; (d), CCPh = phenylacetylide, and Ph = Phenyl) have been synthesized and characterized. Electronic absorption and emission, as well as electrochemical properties of these compounds, have been investigated. Pt(tpy)X+ analogs (tpy = 2,2';6'2''-terpyridine), 2(a-d), have also been investigated and compared.

Spectroscopic Characterization of Platinum(IV) Terpyridyl Complexes.

Pt(tpy)X [X = Cl (), Br (); tpy = 2,2':6',2″-terpyridine] salts were prepared by the oxidative addition of Pt(tpy)X with X as originally reported by Morgan and Burstall in 1934. The complexes have been fully characterized by H NMR spectroscopy, elemental analysis, mass spectrometry, and X-ray crystallography. The electronic structures of and were investigated using absorption and emission spectroscopy, and the accumulated data are consistent with stabilization of the singlet ligand-centered and potentially singlet ligand field/singlet ligand-to-metal charge-transfer states for and compared to those for Pt(tpy)Cl () and Pt(tpy)Br ().

Results of single-staged rotational osteotomy in a child with congenital proximal radioulnar synostosis: subjective and objective evaluation.

Background: For congenital proximal radioulnar synostosis, both conservative and operative treatments have been described. Most of the studies describing surgical interventions are based on subjective evaluation of the forearm function and have used severe degree of forearm pronation as an indication for surgery. This study describes a single-staged rotational osteotomy of the proximal third ulna and distal third radius.

Comparison of safety, efficacy, and cost effectiveness of benzyl benzoate, permethrin, and ivermectin in patients of scabies.

Objective: To compare three treatment modalities in scabies for safety, efficacy, and economy in a local population of Nagpur.

Materials And Methods: This was a prospective, randomized, comparative clinical trial conducted in 103 participants, randomly allocated to three groups. First group received benzyl benzoate (BB) 25% lotion, second group received permethrin 5% cream, whereas third group received tablet ivermectin 200 mug/kg as a single dose.