Adsorption time scales of cluster-forming systems.

A microscopic model of adsorption in cluster forming systems with competing interaction is considered. The adsorption process is described by the master equation and modelled by a kinetic Monte Carlo method. The evolution of the particle concentration and interaction energy during the adsorption of particles on a plane triangular lattice is investigated.

Structural and Thermodynamic Peculiarities of Core-Shell Particles at Fluid Interfaces from Triangular Lattice Models.

A triangular lattice model for pattern formation by core-shell particles at fluid interfaces is introduced and studied for the particle to core diameter ratio equal to 3. Repulsion for overlapping shells and attraction at larger distances due to capillary forces are assumed. Ground states and thermodynamic properties are determined analytically and by Monte Carlo simulations for soft outer- and stiffer inner shells, with different decay rates of the interparticle repulsion.

Triangular lattice models for pattern formation by core-shell particles with different shell thicknesses.

Triangular lattice models for pattern formation by hard-core soft-shell particles at interfaces are introduced and studied in order to determine the effect of the shell thickness and structure. In model I, we consider particles with hard-cores covered by shells of cross-linked polymeric chains. In model II, such inner shell is covered by a much softer outer shell.

Adsorption anomalies in a two-dimensional model of cluster-forming systems.

Adsorption on a boundary line confining a monolayer of particles self-assembling into clusters is studied by Monte Carlo simulations. We focus on a system of particles interacting via competing interaction potential in which effectively short-range attraction is followed by long-range repulsion. For the chemical potential values below the order-disorder phase transition the adsorption isotherms were shown to undergo nonstandard behavior, i.

Self-intermediate scattering function of strongly interacting three-dimensional lattice gases: time- and wave-vector-dependent tracer diffusion coefficient.

We investigate the self-intermediate scattering function (SISF) in a three-dimensional (3D) cubic lattice fluid (interacting lattice gas) with attractive nearest-neighbor interparticle interactions at a temperature slightly above the critical one by means of Monte Carlo simulations. A special representation of SISF as an exponent of the mean tracer diffusion coefficient multiplied by the geometrical factor and time is considered to highlight memory effects that are included in time and wave-vector dependence of the diffusion coefficient. An analytical expression for the diffusion coefficient is suggested to reproduce the simulation data.