Nanosecond switchable localized surface plasmons through resettable contact angle behavior in silver nanoparticles.

In this article, we show nanosecond switchable localized surface plasmon resonance (LSPR) dipole and quadrupole modes from silver (Ag) nanoparticles on fused quartz substrates. Near-spherical Ag nanoparticles (contact angle of 166± 9 ) were synthesized by Ultra Violet (UV) laser dewetting of Ag thin films under a glycerol fluid environment. Under a single 9 nanosecond laser pulse irradiation of the particles in air, the particles were changed into a near-hemispherical shape (with contact angle of 103± 7 ).

In Situ Contact Angle Tuning of Silver Nanostructures by Laser Heating in Different Fluid Ambient.

It has been theoretically suggested by Yan et al. ( , , 142-148) that the contact angle θ of a liquid droplet on any given surface can be controlled by immersing it in an appropriate surrounding environment. Here, we report the first experimental demonstration of such an in situ contact angle tuning of silver (Ag) nanoparticles on quartz substrates via nanosecond pulsed laser heating under various fluid ambients, like air, water, and glycerol.

Thermal and Plasmonic Stabilization of Silver Nanostructures Using a Bilayer Anchoring Technique.

In this work, we demonstrate how to suppress the shape instability of silver (Ag) nanotriangular pyramids following high-temperature annealing without a coating or encapsulation, thus producing a more stable optical plasmonic system. Nanosphere lithography (NSL) was used to fabricate large-area arrays of nanotriangular pyramids of Ag on glass substrates. By using a combination of morphology and spectroscopic studies it was found that exposure of this system to high temperatures of 473 K and beyond in air led to a rapid change in nanostructure shape, and thus, the surface area, with a substantial change to the original plasmonic character.

Plasmon-Enhanced Photocurrent from Photosystem I Assembled on Ag Nanopyramids.

Plasmonic metal nanostructures have been known to tune optoelectronic properties of fluorophores. Here, we report the first-ever experimental observation of plasmon-induced photocurrent enhancements from Photosystem I (PSI) immobilized on Fischer patterns of silver nanopyramids (Ag-NP). To this end, the plasmonic peaks of Ag-NP were tuned to match the PSI absorption peaks at ∼450 and ∼680 nm wavelengths.

Transformation of irregular shaped silver nanostructures into nanoparticles by under water pulsed laser melting.

The ability to easily manufacture nanostructures with a desirable attribute, such as well-defined size and shape, especially from any given initial shapes or sizes of the material, will be helpful towards accelerating the use of nanomaterials in various applications. In this work we report the transformation of discontinuous irregular nanostructures (DIN) of silver metal by rapid heating under a bulk fluid layer. Ag films were changed into DIN by dewetting in air and subsequently heated by nanosecond laser pulses under water.